随着环保意识的增强和环保法规的日益严格,煤矿洗选废水的处理与回用问题受到了广泛关注。本研究主要针对煤矿洗选废水处理难题,深入探讨了废水特性及其环境影响,系统研究了零排放处理技术,特别是高级氧化与膜分离等新技术。通过工程案...随着环保意识的增强和环保法规的日益严格,煤矿洗选废水的处理与回用问题受到了广泛关注。本研究主要针对煤矿洗选废水处理难题,深入探讨了废水特性及其环境影响,系统研究了零排放处理技术,特别是高级氧化与膜分离等新技术。通过工程案例分析,验证了这些技术在提升废水处理效率、实现零排放目标方面的有效性。研究结果表明,综合运用多种先进技术,能够有效实现煤矿洗选废水的零排放目标,不仅降低了企业的环保风险和经济成本,还促进了水资源的循环利用和生态环境的保护。本文的研究为煤矿行业废水处理提供了科学依据和实践参考,对于推动煤炭行业的绿色转型和可持续发展具有重要意义。With the enhancement of environmental awareness and increasingly stringent environmental regulations, the treatment and reuse of coal mine washing wastewater has received widespread attention. This study mainly focuses on the treatment of coal mine washing wastewater, deeply explores the characteristics of wastewater and its environmental impact, and systematically studies zero-discharge treatment technology, especially new technologies such as advanced oxidation and membrane separation. Through engineering case analysis, the effectiveness of these technologies in improving wastewater treatment efficiency and achieving zero-discharge goals has been verified. The research results show that the comprehensive use of a variety of advanced technologies can effectively achieve the zero-discharge goal of coal mine washing wastewater, which not only reduces the environmental risks and economic costs of enterprises, but also promotes the recycling of water resources and the protection of the ecological environment. The research in this paper provides a scientific basis and practical reference for wastewater treatment in the coal mining industry, which is of great significance for promoting the green transformation and sustainable development of the coal industry.展开更多
A new process for vanadium recovery from stone coal by roasting-flotation was investigated based on the mineralogy. The process comprised four key steps: decarburization, preferential grinding, desliming and flotatio...A new process for vanadium recovery from stone coal by roasting-flotation was investigated based on the mineralogy. The process comprised four key steps: decarburization, preferential grinding, desliming and flotation. In the decarburization stage, roasting at 550 ℃ effectively avoided the negative effect of the carbonaceous materials in raw ore and generation of free CaO from calcite decomposition during roasting. Through preferential grinding, the high acid-consuming minerals were enriched in the middle fractions, while mica was enriched in the fine and coarse fractions. Through flotation, the final concentrate can be obtained with V2O5 grade of 1.07% and recovery of 83.30%. Moreover, the vanadium leaching rate of the final concentrate increased 13.53% compared to that of the feed. The results reveal that the decarburization by roasting at 550 ℃ is feasible and has little negative impact on mica flotation, and vanadium recovery from stone coal is conducive to reducing handling quantity, acid consumption and production cost.展开更多
The reduction behaviors of FeO·V2O3 and FeO·Cr2O3 during coal-based direct reduction have a decisive impact on the efficient utilization of high-chromium vanadium-bearing titanomagnetite concentrates. The ef...The reduction behaviors of FeO·V2O3 and FeO·Cr2O3 during coal-based direct reduction have a decisive impact on the efficient utilization of high-chromium vanadium-bearing titanomagnetite concentrates. The effects of molar ratio of C to Fe n(C)/n(Fe) and temperature on the behaviors of vanadium and chromium during direct reduction and magnetic separation were investigated. The reduced samples were characterized by X-ray diffraction(XRD), scanning election microscopy(SEM) and energy dispersive spectrometry(EDS) techniques. Experimental results indicate that the recoveries of vanadium and chromium rapidly increase from 10.0% and 9.6% to 45.3% and 74.3%, respectively, as the n(C)/n(Fe) increases from 0.8 to 1.4. At n(C)/n(Fe) of 0.8, the recoveries of vanadium and chromium are always lower than 10.0% in the whole temperature range of 1100-1250 °C. However, at n(C)/n(Fe) of 1.2, the recoveries of vanadium and chromium considerably increase from 17.8% and 33.8% to 42.4% and 76.0%, respectively, as the temperature increases from 1100 °C to 1250 °C. At n(C)/n(Fe) lower than 0.8, most of the FeO·V2O3 and FeO·Cr2O3 are not reduced to carbides because of the lack of carbonaceous reductants, and the temperature has little effect on the reduction behaviors of FeO·V2O3 and FeO·Cr2O3, resulting in very low recoveries of vanadium and chromium during magnetic separation. However, at higher n(C)/n(Fe), the reduction rates of FeO·V2O3 and FeO·Cr2O3 increase significatly because of the excess amount of carbonaceous reductants. Moreover, higher temperatures largely induce the reduction of FeO·V2O3 and FeO·Cr2O3 to carbides. The newly formed carbides are then dissolved in the γ(FCC) phase, and recovered accompanied with the metallic iron during magnetic separation.展开更多
A desulphurization experimental study under the effects of compounding physical force fields has been described for 〈 0.5 mm fine particles of high sulfur coal. A statistical test using the Box-Behnken Design of expe...A desulphurization experimental study under the effects of compounding physical force fields has been described for 〈 0.5 mm fine particles of high sulfur coal. A statistical test using the Box-Behnken Design of experiments was conducted to evaluate the effects of individual operating variables and their interactions on desulfurization of fine coal using an enhanced centrifugal gravity separator. A model describing the relation between desulphurization efficiency of pyrite sulfur and different operating variables has been designed. The interactions between different factors on the pyrite sulfur desulphurization efficiency have been analysed. The optimal test conditions for desulfarization are extracted from the Design-Expert 6.0 software. Finally, the pointed out. advantage of centrifugal gravity separation for fine coal is pointed out.展开更多
The feasibility of using ultrasound to enhance the performance of de-sulphurization and de-ashing during slime flotation was investigated. The Setararn C80 calorimeter, the contact angle gauge DCAT21 and an electropho...The feasibility of using ultrasound to enhance the performance of de-sulphurization and de-ashing during slime flotation was investigated. The Setararn C80 calorimeter, the contact angle gauge DCAT21 and an electrophoresis apparatus were used to study the surface nature of coal, pyrite and refuse before and after ultrasonic conditioning. The yield, ash and sulfur contents of equally sized coal slimes were also measured before and after ultrasonic conditioning. The results show that ultrasonic conditioning can drive the separation of pyrite and refuse from coal. After ultrasonic conditioning the hydrophobicity of coal and hydrophilicity of pyrite and refuse increase. The perfect index of flotation, the perfect index of de-sulphurization and the percentage of de-sulphurization increase by 22.51%, 25.36% and 2.49%, respectively. This study shows that ultrasonic conditioning can enhance the performance of de-sulphurization and de-ashing of coal flotation methods.展开更多
A 40-60 t/h modularized dry coal beneficiation process with a novel method to control the bed was designed around a gas-solid fluidized bed separator. Furthermore, the hydrodynamics of medium-solids consisting of wide...A 40-60 t/h modularized dry coal beneficiation process with a novel method to control the bed was designed around a gas-solid fluidized bed separator. Furthermore, the hydrodynamics of medium-solids consisting of wide-size-range magnetite powder (0.3-0.06 ram) and 〈1 mm fine coal were numerically studied. The simulation results show that the fluidization performance of the wide-size-range medium-solid bed is good. The separation performance of the modularized system was then investigated in detail using a mixture of 〈0.3 mm magnetite powder (mass fraction of 0.3-0.06 mm particles is 91.38 %) and 〈1 mm fine coal as solid media. The experimental results show that at separation densities of 1.33 g/cm^3 or 1.61 g/cm^3, 50-6 mm coal can be separated effectively with probable error, E, values of 0.05 g/cm^3 and 0.06 g/cm^3, respectively. This technique is beneficial for saving water resources and for the clean utilization of coal.展开更多
For the production of low ash content clean coal, separation at low density is required for some raw coals.Based on analyzing the fluidizing characteristics of magnetic-pearls with a specific size clistribution and fo...For the production of low ash content clean coal, separation at low density is required for some raw coals.Based on analyzing the fluidizing characteristics of magnetic-pearls with a specific size clistribution and formation mechanism of a microbubble fluidized bed, optimal technological and operating parameters suitable for low density coal separation were determined. The experimental results show that an air dense medium fluidized bed with low den-sity can be formed using magnetic pearls as medium solids, which can efficiently beneficiate coal of 6-50 mm size with a probable error Ep value of 0.05 at a separating density of 1.44 g/cm^3.展开更多
Beneficiation of non-coking coal is gaining ground in India. It not only reduces the volume of inert content to be transported to the power plant and also lowers the wear in the boiler houses. For special applications...Beneficiation of non-coking coal is gaining ground in India. It not only reduces the volume of inert content to be transported to the power plant and also lowers the wear in the boiler houses. For special applications such as the fuel for integrated gasification combined cycle plant (IGCC), the ash content in the coal should preferably be below 15 %. Indian coals are characterized by high inter-grown ash content mainly due to 'drift origin' of Gondwana formation in Permian age. This warrants fine grinding of non-coking coal in order to liberate the ash forming minerals from coal macerals. A non- coking coal sample of vitrinite type from India was ground to 44 ~tm (dso) and subjected to column flotation to improve its quality. The non-coking coal analyzing 34.6 % ash, 26.2 % volatile matter, 1.3 % moisture and 37.9 % fixed carbon could be upgraded to a concentrate/froth of 14.83 % ash at 72.18 % yield by optimizing collector and frother dosages and flotation column operating parameters, namely, froth depth, superficial feed velocity and superficial air velocity. The concentrate produced by this process is suitable as fuel for IGCC in coal-to-electricity route.展开更多
The cyclonic static micro-bubble column flotation (FCSMC) is an effective separation device for fine particle treatment. The high mineralization rate and short flotation time of this equipment can be attributed to its...The cyclonic static micro-bubble column flotation (FCSMC) is an effective separation device for fine particle treatment. The high mineralization rate and short flotation time of this equipment can be attributed to its unique cyclonic force field. It also has been observed that the presence of a cyclonic force field leads to a lower bottom separation size limit and a reduction of unselective entrainment. The collection zone of the column is considered to consist of two parts,a column separation zone and a cyclonic zone. Total recovery of the collection zone was developed. For our study,we analyzed the particle movement in the cyclonic zone. Particle residence time equations for the cyclonic zone were de-rived by force analysis. Results obtained in this study provide a theoretical foundation for the design and scale-up of the FCSMC.展开更多
The settling behavior of coarse particles in a gas-solid fluidized bed was experimentally studied by using magnetic tracer. It is well known that the calculation of terminal velocity is of interest in dense medium sep...The settling behavior of coarse particles in a gas-solid fluidized bed was experimentally studied by using magnetic tracer. It is well known that the calculation of terminal velocity is of interest in dense medium separation. However, this problem has not been completely solved up to now. In this work, the terminal velocity of an object mov-ing in a gas-solid fluidized bed was experimentally measured and theoretically calculated. The experimental results in-dicated that the plastic viscosity and yield stress of the bed increase as the size of fluidized particles increases, but it varies little when some coarser particles are mixed with the fluidized particles. The resistance to a rising object was an order magnitude greater than that to a settling object. The efficient buoyancy on a flaky object, which lies flatly on the gas distributor, was much less than that calculated by the Archimedes principle. The object does not always rise or set-tle with minimal projective area owing to radial motion of the fluidized particles. But in the lower part of the bed, the bar-shaped objects were likely with minimal projective area rising or settling.展开更多
文摘随着环保意识的增强和环保法规的日益严格,煤矿洗选废水的处理与回用问题受到了广泛关注。本研究主要针对煤矿洗选废水处理难题,深入探讨了废水特性及其环境影响,系统研究了零排放处理技术,特别是高级氧化与膜分离等新技术。通过工程案例分析,验证了这些技术在提升废水处理效率、实现零排放目标方面的有效性。研究结果表明,综合运用多种先进技术,能够有效实现煤矿洗选废水的零排放目标,不仅降低了企业的环保风险和经济成本,还促进了水资源的循环利用和生态环境的保护。本文的研究为煤矿行业废水处理提供了科学依据和实践参考,对于推动煤炭行业的绿色转型和可持续发展具有重要意义。With the enhancement of environmental awareness and increasingly stringent environmental regulations, the treatment and reuse of coal mine washing wastewater has received widespread attention. This study mainly focuses on the treatment of coal mine washing wastewater, deeply explores the characteristics of wastewater and its environmental impact, and systematically studies zero-discharge treatment technology, especially new technologies such as advanced oxidation and membrane separation. Through engineering case analysis, the effectiveness of these technologies in improving wastewater treatment efficiency and achieving zero-discharge goals has been verified. The research results show that the comprehensive use of a variety of advanced technologies can effectively achieve the zero-discharge goal of coal mine washing wastewater, which not only reduces the environmental risks and economic costs of enterprises, but also promotes the recycling of water resources and the protection of the ecological environment. The research in this paper provides a scientific basis and practical reference for wastewater treatment in the coal mining industry, which is of great significance for promoting the green transformation and sustainable development of the coal industry.
基金Project(2015BAB03B05)supported by the National Key Technology R&D Program during the"12th Five-year Plan"Period,ChinaProject(51404177)supported by the National Natural Science Foundation of China
文摘A new process for vanadium recovery from stone coal by roasting-flotation was investigated based on the mineralogy. The process comprised four key steps: decarburization, preferential grinding, desliming and flotation. In the decarburization stage, roasting at 550 ℃ effectively avoided the negative effect of the carbonaceous materials in raw ore and generation of free CaO from calcite decomposition during roasting. Through preferential grinding, the high acid-consuming minerals were enriched in the middle fractions, while mica was enriched in the fine and coarse fractions. Through flotation, the final concentrate can be obtained with V2O5 grade of 1.07% and recovery of 83.30%. Moreover, the vanadium leaching rate of the final concentrate increased 13.53% compared to that of the feed. The results reveal that the decarburization by roasting at 550 ℃ is feasible and has little negative impact on mica flotation, and vanadium recovery from stone coal is conducive to reducing handling quantity, acid consumption and production cost.
基金Projects(2013CB632601,2013CB632604)supported by the National Basic Research Program of ChinaProject(51125018)supported by the National Science Foundation for Distinguished Young Scholars of China+1 种基金Project(KGZD-EW-201-2)supported by the Key Research Program of the Chinese Academy of SciencesProjects(51374191,21106167,51104139)supported by the National Natural Science Foundation of China
文摘The reduction behaviors of FeO·V2O3 and FeO·Cr2O3 during coal-based direct reduction have a decisive impact on the efficient utilization of high-chromium vanadium-bearing titanomagnetite concentrates. The effects of molar ratio of C to Fe n(C)/n(Fe) and temperature on the behaviors of vanadium and chromium during direct reduction and magnetic separation were investigated. The reduced samples were characterized by X-ray diffraction(XRD), scanning election microscopy(SEM) and energy dispersive spectrometry(EDS) techniques. Experimental results indicate that the recoveries of vanadium and chromium rapidly increase from 10.0% and 9.6% to 45.3% and 74.3%, respectively, as the n(C)/n(Fe) increases from 0.8 to 1.4. At n(C)/n(Fe) of 0.8, the recoveries of vanadium and chromium are always lower than 10.0% in the whole temperature range of 1100-1250 °C. However, at n(C)/n(Fe) of 1.2, the recoveries of vanadium and chromium considerably increase from 17.8% and 33.8% to 42.4% and 76.0%, respectively, as the temperature increases from 1100 °C to 1250 °C. At n(C)/n(Fe) lower than 0.8, most of the FeO·V2O3 and FeO·Cr2O3 are not reduced to carbides because of the lack of carbonaceous reductants, and the temperature has little effect on the reduction behaviors of FeO·V2O3 and FeO·Cr2O3, resulting in very low recoveries of vanadium and chromium during magnetic separation. However, at higher n(C)/n(Fe), the reduction rates of FeO·V2O3 and FeO·Cr2O3 increase significatly because of the excess amount of carbonaceous reductants. Moreover, higher temperatures largely induce the reduction of FeO·V2O3 and FeO·Cr2O3 to carbides. The newly formed carbides are then dissolved in the γ(FCC) phase, and recovered accompanied with the metallic iron during magnetic separation.
文摘A desulphurization experimental study under the effects of compounding physical force fields has been described for 〈 0.5 mm fine particles of high sulfur coal. A statistical test using the Box-Behnken Design of experiments was conducted to evaluate the effects of individual operating variables and their interactions on desulfurization of fine coal using an enhanced centrifugal gravity separator. A model describing the relation between desulphurization efficiency of pyrite sulfur and different operating variables has been designed. The interactions between different factors on the pyrite sulfur desulphurization efficiency have been analysed. The optimal test conditions for desulfarization are extracted from the Design-Expert 6.0 software. Finally, the pointed out. advantage of centrifugal gravity separation for fine coal is pointed out.
基金Projects 50274036 supported by the National Natural Science Foundation of China1055G039 by the Mainstay Teacher Originality Innovation Plan Foundation of the Education Department of Heilongjiang Province.
文摘The feasibility of using ultrasound to enhance the performance of de-sulphurization and de-ashing during slime flotation was investigated. The Setararn C80 calorimeter, the contact angle gauge DCAT21 and an electrophoresis apparatus were used to study the surface nature of coal, pyrite and refuse before and after ultrasonic conditioning. The yield, ash and sulfur contents of equally sized coal slimes were also measured before and after ultrasonic conditioning. The results show that ultrasonic conditioning can drive the separation of pyrite and refuse from coal. After ultrasonic conditioning the hydrophobicity of coal and hydrophilicity of pyrite and refuse increase. The perfect index of flotation, the perfect index of de-sulphurization and the percentage of de-sulphurization increase by 22.51%, 25.36% and 2.49%, respectively. This study shows that ultrasonic conditioning can enhance the performance of de-sulphurization and de-ashing of coal flotation methods.
基金Projects(50921002, 50774084) supported by the National Natural Science Foundation of ChinaProject(2007AA05Z318) supported by the National High-tech Research and Development Program of China+1 种基金Project(BK2010002) supported by the Natural Science Foundation of Jiangsu Province of ChinaProject(20100480473) supported by the China Postdoctoral Science Foundation
文摘A 40-60 t/h modularized dry coal beneficiation process with a novel method to control the bed was designed around a gas-solid fluidized bed separator. Furthermore, the hydrodynamics of medium-solids consisting of wide-size-range magnetite powder (0.3-0.06 ram) and 〈1 mm fine coal were numerically studied. The simulation results show that the fluidization performance of the wide-size-range medium-solid bed is good. The separation performance of the modularized system was then investigated in detail using a mixture of 〈0.3 mm magnetite powder (mass fraction of 0.3-0.06 mm particles is 91.38 %) and 〈1 mm fine coal as solid media. The experimental results show that at separation densities of 1.33 g/cm^3 or 1.61 g/cm^3, 50-6 mm coal can be separated effectively with probable error, E, values of 0.05 g/cm^3 and 0.06 g/cm^3, respectively. This technique is beneficial for saving water resources and for the clean utilization of coal.
基金Projects 90510002, 90210035 supported by the National Natural Science Foundation of China306008 by the Science and Technology Research of Ministry of Education of China
文摘For the production of low ash content clean coal, separation at low density is required for some raw coals.Based on analyzing the fluidizing characteristics of magnetic-pearls with a specific size clistribution and formation mechanism of a microbubble fluidized bed, optimal technological and operating parameters suitable for low density coal separation were determined. The experimental results show that an air dense medium fluidized bed with low den-sity can be formed using magnetic pearls as medium solids, which can efficiently beneficiate coal of 6-50 mm size with a probable error Ep value of 0.05 at a separating density of 1.44 g/cm^3.
文摘Beneficiation of non-coking coal is gaining ground in India. It not only reduces the volume of inert content to be transported to the power plant and also lowers the wear in the boiler houses. For special applications such as the fuel for integrated gasification combined cycle plant (IGCC), the ash content in the coal should preferably be below 15 %. Indian coals are characterized by high inter-grown ash content mainly due to 'drift origin' of Gondwana formation in Permian age. This warrants fine grinding of non-coking coal in order to liberate the ash forming minerals from coal macerals. A non- coking coal sample of vitrinite type from India was ground to 44 ~tm (dso) and subjected to column flotation to improve its quality. The non-coking coal analyzing 34.6 % ash, 26.2 % volatile matter, 1.3 % moisture and 37.9 % fixed carbon could be upgraded to a concentrate/froth of 14.83 % ash at 72.18 % yield by optimizing collector and frother dosages and flotation column operating parameters, namely, froth depth, superficial feed velocity and superficial air velocity. The concentrate produced by this process is suitable as fuel for IGCC in coal-to-electricity route.
基金Project 50425414 supported by the National Outstanding Youth Science Foundation of China
文摘The cyclonic static micro-bubble column flotation (FCSMC) is an effective separation device for fine particle treatment. The high mineralization rate and short flotation time of this equipment can be attributed to its unique cyclonic force field. It also has been observed that the presence of a cyclonic force field leads to a lower bottom separation size limit and a reduction of unselective entrainment. The collection zone of the column is considered to consist of two parts,a column separation zone and a cyclonic zone. Total recovery of the collection zone was developed. For our study,we analyzed the particle movement in the cyclonic zone. Particle residence time equations for the cyclonic zone were de-rived by force analysis. Results obtained in this study provide a theoretical foundation for the design and scale-up of the FCSMC.
基金Projects (504740309021003550025411) supported by National Natural Science Foundation of China
文摘The settling behavior of coarse particles in a gas-solid fluidized bed was experimentally studied by using magnetic tracer. It is well known that the calculation of terminal velocity is of interest in dense medium separation. However, this problem has not been completely solved up to now. In this work, the terminal velocity of an object mov-ing in a gas-solid fluidized bed was experimentally measured and theoretically calculated. The experimental results in-dicated that the plastic viscosity and yield stress of the bed increase as the size of fluidized particles increases, but it varies little when some coarser particles are mixed with the fluidized particles. The resistance to a rising object was an order magnitude greater than that to a settling object. The efficient buoyancy on a flaky object, which lies flatly on the gas distributor, was much less than that calculated by the Archimedes principle. The object does not always rise or set-tle with minimal projective area owing to radial motion of the fluidized particles. But in the lower part of the bed, the bar-shaped objects were likely with minimal projective area rising or settling.