Electronic structures of complex mineral jamesonite were studied using density functional theory method together with their flotation behavior. The flotation behavior ofjamesonite is similar to that of stibnite, indic...Electronic structures of complex mineral jamesonite were studied using density functional theory method together with their flotation behavior. The flotation behavior ofjamesonite is similar to that of stibnite, indicating good floatability at pH below 6 and easy depression with NaOH, especially with lime. In weak alkaline condition, the flotation behavior ofjamesonite is close to that of galena. The coordination structure of Pb for jamesonite is more complex than that for galena. Sb in jamesonite possesses two coordinated modes, whereas Sb of stibnite is only 3-coordinated. Pb in galena is more active than that in jamesonite. Sb （3-coordination） in jamesonite is inactive, in contrast with that in stibnite. However, 4-coordination Sb in jamesonite is more active than 3-coordination Sb. HOMO orbitals of jamesonite and stibnite contain metal atoms, which contribute to the formation of adsorption configuration of CaOH^＋ when there is lime; therefore, jamesonite and stibnite are easily depressed by lime.展开更多
Research about the auto commuter＇s pre-trip route choice behavior ignores the combined influence of the real-time information and all respondents＇ historical information in the existing documents.To overcome this sh...Research about the auto commuter＇s pre-trip route choice behavior ignores the combined influence of the real-time information and all respondents＇ historical information in the existing documents.To overcome this shortcoming,an approach to describing the pre-trip route choice behavior with the incorporation of the real-time and historical information is proposed.Two types of real-time information are investigated,which are quantitative information and prescriptive information.By using the bounded rationality theory,the influence of historical information on the real-time information reference process is examined first.Estimation results show that the historical information has a significant influence on the quantitative information reference process,but not on the prescriptive information reference process.Then the route choice behavior is modeled.A comparison is also made among three route choice models,one of which does not incorporate the real-time information reference process,while the others do.Estimation results show that the route choice behavior is better described with the consideration of the reference process of both quantitative and prescriptive information.展开更多
In order to effectively separate galena and jamesonite and improve the recovery during the mixing flotation, the interaction mechanisms between the minerals and the collector of diethyl dithiocarbamate （DDTC） were i...In order to effectively separate galena and jamesonite and improve the recovery during the mixing flotation, the interaction mechanisms between the minerals and the collector of diethyl dithiocarbamate （DDTC） were investigated. Single mineral flotation test was organized to research the effect of pulp pH value on the flotation behavior of galena and jamesonite. Electrochemistry property of the interaction of these two minerals with DDTC was investigated by cyclic voltammetry and Tafel tests. Flotation test shows that the recovery of jamesonite in high alkaline pulp is strongly depressed by lime （Ca（OH）2）. The cyclic voltammetry and Tafel tests results show that the interaction between galena and DDTC is an electrochemical process. High pH value has little influence on the interaction between galena and DDTC, while it has great effect on jamesonite due to self-oxidation and specific adsorption of OH^- and CaOH^＋ on jamesonite surface. Non-electroactive hydroxyl compound and low-electroconductive calcium compounds cover the surface of jamesonite, which impedes electron transfer and DDTC adsorption, thus leads to very low floatability of jamesonite.展开更多
This paper analyzes the characteristics of the destination distribution of trips and proposes a stratified sampling strategy for travel mode choice.The stratified sampling strategy can reduce the size of the alternati...This paper analyzes the characteristics of the destination distribution of trips and proposes a stratified sampling strategy for travel mode choice.The stratified sampling strategy can reduce the size of the alternative set;thus,the computation burden of simulation is decreased.Using the stratified sampling strategy,a combined choice model of the trip mode and destination is developed based on the Bayesian theory.Simulations are carried out to verify the proposed model.The results show that the combined choice model of the trip mode and destination can efficiently simulate travelers＇ choice behaviors.Furthermore,the forecasting accuracy of the combined choice model is higher than the one of the gravity model.Therefore,the proposed model is a powerful tool with which to analyze travelers＇ behaviors in selecting the trip mode.展开更多
基金Project(NCET-11-0925)supported by the New Century Excellent Talents in University,ChinaProject(51164001)supported by the National Natural Science Foundation of ChinaProject supported by Open Foundation of Guangxi Key Laboratory for Advanced Materials and Manufacturing Technology,China
文摘Electronic structures of complex mineral jamesonite were studied using density functional theory method together with their flotation behavior. The flotation behavior ofjamesonite is similar to that of stibnite, indicating good floatability at pH below 6 and easy depression with NaOH, especially with lime. In weak alkaline condition, the flotation behavior ofjamesonite is close to that of galena. The coordination structure of Pb for jamesonite is more complex than that for galena. Sb in jamesonite possesses two coordinated modes, whereas Sb of stibnite is only 3-coordinated. Pb in galena is more active than that in jamesonite. Sb （3-coordination） in jamesonite is inactive, in contrast with that in stibnite. However, 4-coordination Sb in jamesonite is more active than 3-coordination Sb. HOMO orbitals of jamesonite and stibnite contain metal atoms, which contribute to the formation of adsorption configuration of CaOH^＋ when there is lime; therefore, jamesonite and stibnite are easily depressed by lime.
基金The Scientific Research Innovation Project for College Graduates in Jiangsu Province(No.CX10B_071Z)the National High Technology Research and Development Program of China(863 Program)(No.2011AA110304)
文摘Research about the auto commuter＇s pre-trip route choice behavior ignores the combined influence of the real-time information and all respondents＇ historical information in the existing documents.To overcome this shortcoming,an approach to describing the pre-trip route choice behavior with the incorporation of the real-time and historical information is proposed.Two types of real-time information are investigated,which are quantitative information and prescriptive information.By using the bounded rationality theory,the influence of historical information on the real-time information reference process is examined first.Estimation results show that the historical information has a significant influence on the quantitative information reference process,but not on the prescriptive information reference process.Then the route choice behavior is modeled.A comparison is also made among three route choice models,one of which does not incorporate the real-time information reference process,while the others do.Estimation results show that the route choice behavior is better described with the consideration of the reference process of both quantitative and prescriptive information.
基金Projects(5110417951374247)supported by the National Natural Science Foundation of China
文摘In order to effectively separate galena and jamesonite and improve the recovery during the mixing flotation, the interaction mechanisms between the minerals and the collector of diethyl dithiocarbamate （DDTC） were investigated. Single mineral flotation test was organized to research the effect of pulp pH value on the flotation behavior of galena and jamesonite. Electrochemistry property of the interaction of these two minerals with DDTC was investigated by cyclic voltammetry and Tafel tests. Flotation test shows that the recovery of jamesonite in high alkaline pulp is strongly depressed by lime （Ca（OH）2）. The cyclic voltammetry and Tafel tests results show that the interaction between galena and DDTC is an electrochemical process. High pH value has little influence on the interaction between galena and DDTC, while it has great effect on jamesonite due to self-oxidation and specific adsorption of OH^- and CaOH^＋ on jamesonite surface. Non-electroactive hydroxyl compound and low-electroconductive calcium compounds cover the surface of jamesonite, which impedes electron transfer and DDTC adsorption, thus leads to very low floatability of jamesonite.
文摘This paper analyzes the characteristics of the destination distribution of trips and proposes a stratified sampling strategy for travel mode choice.The stratified sampling strategy can reduce the size of the alternative set;thus,the computation burden of simulation is decreased.Using the stratified sampling strategy,a combined choice model of the trip mode and destination is developed based on the Bayesian theory.Simulations are carried out to verify the proposed model.The results show that the combined choice model of the trip mode and destination can efficiently simulate travelers＇ choice behaviors.Furthermore,the forecasting accuracy of the combined choice model is higher than the one of the gravity model.Therefore,the proposed model is a powerful tool with which to analyze travelers＇ behaviors in selecting the trip mode.
