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三探金属与盐溶液的反应
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作者 李露露 沈绍伟 +1 位作者 吴溢选 沈艳娜 《化学教与学》 2024年第17期90-92,共3页
对于初中化学中金属与盐溶液反应的问题,探索由浅入深,从一种金属与一种盐溶液的反应到一种金属与多种盐溶液的反应,再到多种金属与一种盐溶液的反应,结合实验现象分析化学本质,进行原理推理与规律总结,最后利用“递变法”对较复杂的金... 对于初中化学中金属与盐溶液反应的问题,探索由浅入深,从一种金属与一种盐溶液的反应到一种金属与多种盐溶液的反应,再到多种金属与一种盐溶液的反应,结合实验现象分析化学本质,进行原理推理与规律总结,最后利用“递变法”对较复杂的金属与盐溶液反应的问题进行分析和应用,从而更好地帮助学生认识原理,理清思路,掌握做题的一般方法,解决实际问题。 展开更多
关键词 金属 盐溶液 递变法
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等摩尔量法测定Fe(Ⅲ)配合物稳定常数的物理化学实验方法探索 被引量:2
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作者 成昭 范涛 +2 位作者 张雪娇 苗延青 杨莉宁 《化工时刊》 CAS 2018年第12期24-27,共4页
等摩尔量递变法可以通过作图快速求算金属配合物的配位数n与配位稳定常数K,相对于常规的实验测定与复杂的后续求算方法,既保证了准确性,又简化了计算。实验方案中设计了吸光度校正,并进行体系pH控制确保定量配位,进一步减小实验测定和... 等摩尔量递变法可以通过作图快速求算金属配合物的配位数n与配位稳定常数K,相对于常规的实验测定与复杂的后续求算方法,既保证了准确性,又简化了计算。实验方案中设计了吸光度校正,并进行体系pH控制确保定量配位,进一步减小实验测定和求算偏差,提高了实验结果的可靠性。 展开更多
关键词 物理化学实验方法 等摩尔量递变法 配合物稳定常数
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微处理机在测定络合物稳定常数时的应用
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作者 濮良忠 李红 《大连医科大学学报》 CAS 1989年第2期64-68,共5页
本文提出了一种计算机程序,结合等摩尔连续递变法,在计算机上能快速、准确地得到络合物的络合比和稳定常数。
关键词 等摩尔连续递变法 PFG程序
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2D and 3D discrete numerical modelling of soil arching 被引量:2
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作者 Ning BAO Jing WEI +1 位作者 Jian-feng CHEN Ping WEI 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2020年第5期350-365,共16页
In this study,2D and 3D soil arching phenomena associated with piled embankments were evaluated by performing a series of discrete numerical analyses using the particle flow code(PFC3D)software.After validating the mi... In this study,2D and 3D soil arching phenomena associated with piled embankments were evaluated by performing a series of discrete numerical analyses using the particle flow code(PFC3D)software.After validating the micro-parameters with experimental results,we compared the stress-displacement distribution,force chain evolution,maximum vertical displacement of particles,and deformation characteristics induced by 2D and 3D arching effects.Additional analyses were carried out to understand the influence of the fill height,pile clear spacing,friction coefficient,and porosity on soil arching with respect to the stress concentration ratio(SCR)and settlement along the elevation at various sections.The numerical results indicated that a plane soil arch in a 2D embankment overestimates the degree of load transfer and underestimates the settlement at the crest and within the embankment along the elevation in a 3D embankment.A lower equal settlement plane can be found in a 2D embankment.Furthermore,an increase of fill height and friction angle,and a decrease of pile clear spacing and porosity can help to improve the degree of reduction in load transfer and settlement in both 2D and 3D embankments.However,for partially mobilized soil arching in the 3D condition,the increase of fill height reduces the settlement of soils mainly in the portion above the square subsoil area,but has less influence over the portion above the rectangular subsoil area. 展开更多
关键词 Piled embankment Soil arching Discrete element method(DEM) Load transfer SETTLEMENT
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ANALYSIS AND COMPUTATIONAL ALGORITHM FOR QUEUES WITH STATE-DEPENDENT VACATIONS Ⅱ: M(n)/G/1/K
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作者 Ayyar RAHMAN 《Journal of Systems Science & Complexity》 SCIE EI CSCD 2006年第2期191-210,共20页
We study a single-server queueing system with state-dependent arrivals and general service distribution, or simply M(n)/G/1/K, where the server follows an N policy and takes multiple vacations when the system is emp... We study a single-server queueing system with state-dependent arrivals and general service distribution, or simply M(n)/G/1/K, where the server follows an N policy and takes multiple vacations when the system is empty. We provide a recursive algorithm using the supplementary variable technique to numerically compute the stationary queue length distribution of the system. The only input requirements are the Laplace-Stieltjes transforms of the service time distribution and the vacation time distribution, and the state-dependent arrival rate. The computational complexity of the algorithm is O(K^3). 展开更多
关键词 M(n)/G/1 queue queue length distribution recursive algorithm removable server state dependent arrival supplementary variable.
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