The dynamics of the Cl＋SiH4 reaction has been studied using the universal crossed molecular beam method. Angular resolved time-of-flight spectra have been measured for the channel SiH3Cl＋H. Product angular distribut...The dynamics of the Cl＋SiH4 reaction has been studied using the universal crossed molecular beam method. Angular resolved time-of-flight spectra have been measured for the channel SiH3Cl＋H. Product angular distributions as well as energy distributions in the center-ofmass frame were determined for the channel. Experimental results show that the SiH3Cl product is mainly backward scattered relative to the Cl atom beam direction, suggesting that the channel takes place via a typical SN2 type reaction mechanism.展开更多
We have investigated the dynamics of the F＋C4H6 reaction using the universal crossed molecular beam method. The C4H5F＋H reaction channel was observed in this experiment. Angular resolved time-of-flight spectra have ...We have investigated the dynamics of the F＋C4H6 reaction using the universal crossed molecular beam method. The C4H5F＋H reaction channel was observed in this experiment. Angular resolved time-of-flight spectra have been measured for the C4H5F product. Prod- uct angular distributions as well as kinetic energy distributions were determined for this product channel. Experimental results show that the C4H5F product is largely backward scattered with considerable forward scattering signal, relative to the F atom beam direction. This suggests that the reaction channel mainly proceeds via a long-lived complex formation mechanism, with possible contribution from a direct SN2 type mechanism.展开更多
In 1907, aviation pioneer Santos-Dumont had the idea of building a very light airplane. He designed and built the SD 19, the Demoiselle, an aircraft with a 6 meter wing span and a 24 HP engine of his own design. The D...In 1907, aviation pioneer Santos-Dumont had the idea of building a very light airplane. He designed and built the SD 19, the Demoiselle, an aircraft with a 6 meter wing span and a 24 HP engine of his own design. The Demoiselle was very successful in flying and, became very popular and its development continued as SD20, SD21 and SD22 （his last airplane）. The influence of the Demoiselle on design principles of light aircraft and general aviation were studied in this work, using statistical entropy, The designs number 20 and 22 may be considered dominant and influenced the design principles of light aircraft and general aviation.展开更多
基金This work is supported by the Chinese Academy of Sciences and the National Natural Science Foundation of China and the Ministry of Science and Technology.
文摘The dynamics of the Cl＋SiH4 reaction has been studied using the universal crossed molecular beam method. Angular resolved time-of-flight spectra have been measured for the channel SiH3Cl＋H. Product angular distributions as well as energy distributions in the center-ofmass frame were determined for the channel. Experimental results show that the SiH3Cl product is mainly backward scattered relative to the Cl atom beam direction, suggesting that the channel takes place via a typical SN2 type reaction mechanism.
文摘We have investigated the dynamics of the F＋C4H6 reaction using the universal crossed molecular beam method. The C4H5F＋H reaction channel was observed in this experiment. Angular resolved time-of-flight spectra have been measured for the C4H5F product. Prod- uct angular distributions as well as kinetic energy distributions were determined for this product channel. Experimental results show that the C4H5F product is largely backward scattered with considerable forward scattering signal, relative to the F atom beam direction. This suggests that the reaction channel mainly proceeds via a long-lived complex formation mechanism, with possible contribution from a direct SN2 type mechanism.
文摘In 1907, aviation pioneer Santos-Dumont had the idea of building a very light airplane. He designed and built the SD 19, the Demoiselle, an aircraft with a 6 meter wing span and a 24 HP engine of his own design. The Demoiselle was very successful in flying and, became very popular and its development continued as SD20, SD21 and SD22 （his last airplane）. The influence of the Demoiselle on design principles of light aircraft and general aviation were studied in this work, using statistical entropy, The designs number 20 and 22 may be considered dominant and influenced the design principles of light aircraft and general aviation.
