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碘代烷紫外光解通道机理 被引量:1
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作者 曹建如 黄玉惠 +4 位作者 杨达林 高振 方万全 武小军 朱起鹤 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 1990年第4期235-245,共11页
通过对CH_3I,C_2H_5I,n-C_3H_7I,iso-C_3H_7I,n-C_4H_9I,t-C_4H_9I以及CH_2ClI在248nm的激光裂解实验研究,进一步论证光解通道比I/I主要受解离动力学过程中~3Q_0和~1Q_1态的位能曲线交叉机理控制,同时讨论不同Taft极化因子的烷基取代基... 通过对CH_3I,C_2H_5I,n-C_3H_7I,iso-C_3H_7I,n-C_4H_9I,t-C_4H_9I以及CH_2ClI在248nm的激光裂解实验研究,进一步论证光解通道比I/I主要受解离动力学过程中~3Q_0和~1Q_1态的位能曲线交叉机理控制,同时讨论不同Taft极化因子的烷基取代基对n→σ跃迁的影响。利用Landau-Zener关系式和Hammett方程,建立了光解通道比与光解碎片能量分配以及Taft因子之间的关系表达式,能合理地解释实验观察的结果。 展开更多
关键词 碘化烷 紫外光解 通道机理
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1,2-环氧丙烷的光电离解离通道与机理 被引量:1
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作者 刘付轶 盛六四 +4 位作者 齐飞 武国华 高辉 周卫东 张允武 《物理化学学报》 SCIE CAS CSCD 北大核心 1999年第9期845-849,共5页
Photoionization/dissociation of 1,2 propylene oxide are performed by using a time of flight mass spectrometer(TOF MS) with vacuum ultraviolet photons from Hefei synchrotron radiation source. The photoionization TOF ma... Photoionization/dissociation of 1,2 propylene oxide are performed by using a time of flight mass spectrometer(TOF MS) with vacuum ultraviolet photons from Hefei synchrotron radiation source. The photoionization TOF mass spectrum and photoionization efficiency(PIE) curves of fragment ions are measured.The appearance potentials(AP) of these ions are obtained from their PIE curves. From these data, the formation enthalpies of the observed ions have been evaluated, and their possible channels have been analyzed. The mechanism of dissociative photoionization of 1,2 propylene oxide has been discussed. 展开更多
关键词 1 2-环氧丙烷 光电离 出现势 解离通道机理
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钛合金的应力腐蚀 被引量:9
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作者 褚洪 《北京科技大学学报》 EI CAS CSCD 北大核心 2002年第1期47-48,共2页
分析了环境、应力、材料对钛合金应力腐蚀的影响,介绍了钛合金应力腐蚀的3种机制(即活性通道机理、氢脆机理、氯脆机理).
关键词 钛合金 应力腐蚀 活性通道机理 氢脆机理 氯脆机理 腐蚀机理
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五羰基乙酰基锰的深度氢硅烷化
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作者 王颖 薛冰 +2 位作者 李艺林 李司楠 徐崇福 《无机化学学报》 SCIE CAS CSCD 北大核心 2015年第7期1393-1401,共9页
采用两步法合成(CO)5MnCOCH3(1),然后对1与Me2PhSiH的深度氢硅烷化反应做9 h的1H NMR连续监控,通过将反应物和衍生物的特征峰与内标物C6H5(CH2)2C6H5的特征峰对照直接积分定量,得到适时含量(mmol)随反应时间改变(h)的变化规律。期间共... 采用两步法合成(CO)5MnCOCH3(1),然后对1与Me2PhSiH的深度氢硅烷化反应做9 h的1H NMR连续监控,通过将反应物和衍生物的特征峰与内标物C6H5(CH2)2C6H5的特征峰对照直接积分定量,得到适时含量(mmol)随反应时间改变(h)的变化规律。期间共得到了9种中间体或最终产物,通过核磁波谱对比,确定了这些化合物的分子结构。除了对其中6种化合物的特征峰积分直接定量外,对另外3个化合物采用化学计量结合特征峰积分间接定量,并对其反应机理做出了合理的解释。最后提出了深度氢硅烷化的多步反应与双通道机理,并且对反应原料1和Me2PhSiH中Mn和Si进行了全程跟踪,结果发现,在9 h时,Mn总含量高达90.7%,而Si总含量高达91.4%。 展开更多
关键词 氢硅烷化 积分定量 多步反应 通道机理
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Formation Mechanism and Size Prediction of Bubble in Opposite-Flowing T-Shaped Microchannel 被引量:3
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作者 马友光 付涛涛 +2 位作者 朱春英 季喜燕 LI Huaizhi 《Transactions of Tianjin University》 EI CAS 2010年第4期251-255,共5页
Bubble formation in an opposite-flowing T-shaped microchannel with 40 μm in depth and 120 μm in width was real-time visualized and investigated experimentally by means of a high speed camera. N2 bubbles were generat... Bubble formation in an opposite-flowing T-shaped microchannel with 40 μm in depth and 120 μm in width was real-time visualized and investigated experimentally by means of a high speed camera. N2 bubbles were generated in glycerol-water mixtures with different concentrations of surfactant sodium dodecyl sulfate (SDS). And the images were captured by the high speed camera linked to a computer. Results indicated that the bubble formation process can be distinguished into three consecutive stages, i.e., expansion, collapse and pinching off. The bubble size decreases with the increase of liquid flow rate and viscosity of liquid phase as well as the decrease of gas flow rate. The surface tension of the liquid phase has no measurable influence on the bubble size. Moreover, a new approach to predicting the size of bubbles formed in the T-shaped microchannel is proposed. And the predicted values agree well with the experimental data. 展开更多
关键词 MICROCHANNEL bubble formation high speed camera opposite-flowing
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Processing of 8-Channel Synchronous Electro-Cardiograph
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作者 赵捷 韩月秋 《Journal of Beijing Institute of Technology》 EI CAS 2002年第1期66-70,共5页
A real time algorithm is presented here to recognize and analyze 8 channel simultaneous electro cardiograph(ECG). The algorithm transforms 8 channel simultaneous ECG into three orthogonal vectors and spatial veloc... A real time algorithm is presented here to recognize and analyze 8 channel simultaneous electro cardiograph(ECG). The algorithm transforms 8 channel simultaneous ECG into three orthogonal vectors and spatial velocity first, then forms the spatial velocity sample, and uses this spatial velocity sample to recognize each beat. The algorithm computes the averaged parameters by using averaged spatial velocity and the averaged ECG and the current parameters by using the current beat period and current width of QRS. The algorithm can recognize P, QRS and T onsets and ends of simultaneous 12 lead ECG precisely, and some arrhythmias such as premature ventricular beat, ventricular escape beat, R on T, bigeminy, trigeminy. The algorithm software works well on a real 8 channel ECG system and meets the demands of designing. 展开更多
关键词 multi lead electro cardiograph embedded system real time computer processing
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Microscopic phase-field study for oriented diffusion channel effect of nickel-based alloy and phases' effect mechanism 被引量:1
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作者 YANG Kun CHEN Zheng +2 位作者 DONG WeiPing WANG YongXin ZHANG MingYi 《Science China(Technological Sciences)》 SCIE EI CAS 2011年第4期835-840,共6页
In this paper,a microscopic phase-field model was used to investigate the effect of the oriented diffusion channel and the phases' effect mechanism for the Ni75Al6.0V19.0 alloy during a phase transformation proces... In this paper,a microscopic phase-field model was used to investigate the effect of the oriented diffusion channel and the phases' effect mechanism for the Ni75Al6.0V19.0 alloy during a phase transformation process.A diffusion channel of V was formed in the [100] direction.The oriented growth of DO22 in this direction,when an elastic misfit stress field existed,forced Al to form a diffusion channel next to DO22,resulting in L12-oriented growth.With an increase in stress,the oriented growth increased initially and then decreased.At a higher stress,the average values of the occupation probability for V atoms became constant later while Al atoms earlier. 展开更多
关键词 diffusion channel effect stresses-induced diffusion diffusion-induced stresses microscopic phase-field
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otassium channels in airway smooth muscle and airway hyperreactivity in asthma 被引量:3
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作者 LIUXian-sheng XUYong-jian 《Chinese Medical Journal》 SCIE CAS CSCD 2005年第7期574-580,共7页
Our knowledge of the physiology of ion channels has increased tremendously during the past 20 years because of the advances of the single-channel recording and molecular cloning techniques. More than 50 different iden... Our knowledge of the physiology of ion channels has increased tremendously during the past 20 years because of the advances of the single-channel recording and molecular cloning techniques. More than 50 different identified potassium channels have already been found.1,2 They are distributed ubiquitously in wide variety of cells including airway smooth muscle (ASM) cells and inflammatory cells in airway such as eosinophils, basophils, macrophages and so on.3 Several types of K+ channels have been identified in ASM cells, e.g., a large-conductance, voltgage-dependent Ca2+-activated K+ channel(BKCa), a voltage-dependent delayed-rectifier K+ channel(Kv), and an ATP-sensitve K+ channel(KATP).1 In such excitable cells, 展开更多
关键词 delayed rectifier K^+ channel . large conductance Ca^(2+)-activated K^+ channel . ATP-sensitive K^+ channel . airway smooth muscle cell . asthma
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