Combination of Tunable Diode Laser Absorption Spectroscopy(TDLAS)technique and multipass cell is an attractive approach for ultrahigh sensitive detection of trace gases.Theoretically,based on Beer-Lambert law,the long...Combination of Tunable Diode Laser Absorption Spectroscopy(TDLAS)technique and multipass cell is an attractive approach for ultrahigh sensitive detection of trace gases.Theoretically,based on Beer-Lambert law,the longer optical path length and the larger gas absorption,the lower concentration gas could be detected.However,lower radiation intensity and inevitable etalon fringe resulted from multiple reflections would greatly weaken the Signal-to-Noise Ratio(SNR)and thus an expected ultrahigh sensitive detection system is difficult to achieve.In order to fully make use of the advantages of TDLAS and multipass cell,the base length and the total optical path length of the multipass cell are needed to be carefully balanced.Furthermore,the harmonic signals contaminated by various noises are processed with wavelet transform method.As a demonstration of this method,few low concentrations of gas CO in N2 are measured employing TDLAS technique and a novel sealed multipass cell with total optical length of 114 m.The detection limit is about 5×10-6(volume ratio),which is one order of magnitude better than earlier noise reduction.展开更多
文摘Combination of Tunable Diode Laser Absorption Spectroscopy(TDLAS)technique and multipass cell is an attractive approach for ultrahigh sensitive detection of trace gases.Theoretically,based on Beer-Lambert law,the longer optical path length and the larger gas absorption,the lower concentration gas could be detected.However,lower radiation intensity and inevitable etalon fringe resulted from multiple reflections would greatly weaken the Signal-to-Noise Ratio(SNR)and thus an expected ultrahigh sensitive detection system is difficult to achieve.In order to fully make use of the advantages of TDLAS and multipass cell,the base length and the total optical path length of the multipass cell are needed to be carefully balanced.Furthermore,the harmonic signals contaminated by various noises are processed with wavelet transform method.As a demonstration of this method,few low concentrations of gas CO in N2 are measured employing TDLAS technique and a novel sealed multipass cell with total optical length of 114 m.The detection limit is about 5×10-6(volume ratio),which is one order of magnitude better than earlier noise reduction.
