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非平衡吸附对核素迁移的影响及平衡速率参数的确定 被引量:7
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作者 陈家军 王金生 李合莲 《中国环境科学》 EI CAS CSSCI CSCD 北大核心 2000年第1期73-76,共4页
放射性核素以水为载体在多孔介质中迁移时,吸附和解吸作用不容忽视吸附和解吸是一非平衡过程.非平衡状态下吸附和解吸达到平衡的快慢程度可以用平衡速率参数a来表征本文首次定量分析了非平衡吸附对核素迁移的影响,提出基于室内分配... 放射性核素以水为载体在多孔介质中迁移时,吸附和解吸作用不容忽视吸附和解吸是一非平衡过程.非平衡状态下吸附和解吸达到平衡的快慢程度可以用平衡速率参数a来表征本文首次定量分析了非平衡吸附对核素迁移的影响,提出基于室内分配系数实验求取a值的方法,并将室内实验得出的a值同原位核素迁移试验拟合值进行比较;结果表明用此方法求出的a值可作为非平衡吸附核素迁移数学模型的主要参数依据。 展开更多
关键词 放射性核素迁移 吸附 非平衡吸附 平衡速率参数
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基于Z′参数的高强铝合金稳态蠕变速率可靠性研究 被引量:3
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作者 李昂 高蔚 +1 位作者 吴福 张毅 《原子能科学技术》 EI CAS CSCD 北大核心 2020年第4期709-714,共6页
建立了基于速率温度参数模型的新型高强铝合金Z′参数表达式及稳态蠕变速率-可靠度预测方法,Z′参数表征稳态蠕变速率数据偏离速率温度参数模型主曲线的程度。结合实测数据,研究了Z′参数的统计分布规律。基于Z′参数,分别得出新型高强... 建立了基于速率温度参数模型的新型高强铝合金Z′参数表达式及稳态蠕变速率-可靠度预测方法,Z′参数表征稳态蠕变速率数据偏离速率温度参数模型主曲线的程度。结合实测数据,研究了Z′参数的统计分布规律。基于Z′参数,分别得出新型高强铝合金实验应力-速率温度参数-可靠度曲线和温度-许用应力-可靠度曲线。结果显示,新型高强铝合金Z′参数满足正态分布规律。稳态蠕变速率预测上限随可靠度的增加而升高。外推至稳态蠕变速率上限10-7 h-1时,新型高强铝合金在50、80℃下的许用应力(可靠度99.7%)分别为470.0、294.5 MPa。与传统安全系数法相比,基于Z′参数的预测结果更合理。 展开更多
关键词 高强铝合金 速率温度参数 Z′参数 可靠度 稳态蠕变速率预测
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基于速率温度参数计算7075铝合金蠕变本构方程 被引量:3
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作者 李昂 《中国有色金属学报》 EI CAS CSCD 北大核心 2020年第2期308-315,共8页
针对高强铝合金蠕变数据存在幂律失效而难于拟合的问题,采用Monkman-Grant关系式,在经典时间温度参数模型的基础上,推导4种不同形式的速率温度参数模型。根据高强铝合金7075在34.4~148.9℃下的蠕变数据,利用多元线性回归方法,计算得出... 针对高强铝合金蠕变数据存在幂律失效而难于拟合的问题,采用Monkman-Grant关系式,在经典时间温度参数模型的基础上,推导4种不同形式的速率温度参数模型。根据高强铝合金7075在34.4~148.9℃下的蠕变数据,利用多元线性回归方法,计算得出基于不同形式速率温度参数的材料稳态蠕变方程。结合统计检验方法,评价不同模型下蠕变方程的拟合效果。结果表明:在显著性水平5%的条件下,OSD’模型下稳态蠕变速率实测数据与拟合结果的对数差值不满足正态分布。OSD’、LM’模型下拟合数据的对数值无法完全落入理想拟合线双侧96.5%的置信区间内。RMB’、MH’模型下实测与拟合对数值之间的线性相关系数均大于0.994,对应的残差平方和分别为0.2797、0.2800。基于RMB’、MH’模型的蠕变本构方程可以较好地描述7075铝合金在实验条件范围内的稳态蠕变行为。 展开更多
关键词 速率温度参数 高强铝合金 幂律失效 蠕变本构方程 统计检验
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有理参数曲线的最优参数化 被引量:3
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作者 厉玉蓉 李丹 《计算机辅助设计与图形学学报》 EI CSCD 北大核心 2015年第10期1988-1992,共5页
为了利用有理参数曲线的自由度求解其最优参数化,提出一种能够快速准确地确定有理参数曲线最优参数化方程的算法.首先给出了有理参数曲线最优参数化方程的充分条件,即两端点参数速率相等且为最值;然后对一般情形的有理参数曲线方程提出... 为了利用有理参数曲线的自由度求解其最优参数化,提出一种能够快速准确地确定有理参数曲线最优参数化方程的算法.首先给出了有理参数曲线最优参数化方程的充分条件,即两端点参数速率相等且为最值;然后对一般情形的有理参数曲线方程提出求最优参数化方程的算法.与其他算法进行实验的参数化结果表明,该算法具有简单可靠、计算量小、效果好、适用范围广的优点. 展开更多
关键词 有理参数曲线 最优参数 参数速率
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拟薄水铝石的胶溶能力 被引量:14
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作者 潘红年 朱玉霞 +1 位作者 林伟 李凤珍 《石油学报(石油加工)》 EI CAS CSCD 北大核心 2010年第2期195-200,共6页
为区别使用效果不同的拟薄水铝石,研究了其胶溶能力。对不同的拟薄水铝石进行差热和表面羟基分析,并测定了其在胶溶过程中pH值和黏度的变化。结果表明,在同样的胶溶条件下,使用效果较差的拟薄水铝石溶胶的黏度值较低,其可能含有其他杂... 为区别使用效果不同的拟薄水铝石,研究了其胶溶能力。对不同的拟薄水铝石进行差热和表面羟基分析,并测定了其在胶溶过程中pH值和黏度的变化。结果表明,在同样的胶溶条件下,使用效果较差的拟薄水铝石溶胶的黏度值较低,其可能含有其他杂晶。表面羟基强度较弱是使用效果较差拟薄水铝石胶溶性能差的原因。根据胶溶过程中的黏度情况定义胶溶速率参数,可用来区分胶溶能力不同的拟薄水铝石。 展开更多
关键词 胶溶速率参数 黏度 表面羟基
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基于高压天然气装置的CO2吸收动态模型与控制方法 被引量:1
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作者 汪秋婷 王德前 《科技通报》 2020年第5期136-141,共6页
二氧化碳污染物和井口高压力对富CO2型天然气资源的开发提出了重大挑战。必须深入研究瞬态条件下的高二氧化碳分压数据,设计出一种任何干扰条件下处理CO2的控制策略。本文利用高压天然气处理的实验装置,对CO2吸收过程进行稳态和动态建... 二氧化碳污染物和井口高压力对富CO2型天然气资源的开发提出了重大挑战。必须深入研究瞬态条件下的高二氧化碳分压数据,设计出一种任何干扰条件下处理CO2的控制策略。本文利用高压天然气处理的实验装置,对CO2吸收过程进行稳态和动态建模、数据获取和实验验证。利用单乙醇胺水溶液(MEA)脱除二氧化碳,基于平衡法和速率参数法进行动态模拟,改进CO2吸收过程的稳态平衡模型,并在动态系统中设计最优控制策略。 展开更多
关键词 高压天然气 CO2 MEA 平衡法 速率参数 动态模拟
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等间距冲激脉冲调制信号的相位循环特性分析及应用 被引量:1
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作者 石荣 贺岷珏 易翔 《中国电子科学研究院学报》 2009年第6期615-619,共5页
从理论上分析了等间距冲激脉冲调制信号所具有的相位循环特性,介绍了此特性在符号速率参数估计方面的应用,并通过仿真验证了其有效性,这对于信号特征分析与提取具有重要意义。
关键词 等间距冲激脉冲调制信号 相位循环特性 符号速率参数估计
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应用遗传算法优化氢气/空气燃烧反应系数 被引量:2
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作者 牛宝柱 蒋勇 邱榕 《火灾科学》 CAS CSCD 2009年第2期45-50,共6页
研究目的是优化氢气/空气简化反应机理的系数,使得简化机理在一定的误差范围内,能代替详细机理。通过计算氢气/空气详细反应机理得到的组分浓度作为遗传算法的适应度目标,对简化机理进行优化。结果显示,优化后的简化机理不仅在在计算组... 研究目的是优化氢气/空气简化反应机理的系数,使得简化机理在一定的误差范围内,能代替详细机理。通过计算氢气/空气详细反应机理得到的组分浓度作为遗传算法的适应度目标,对简化机理进行优化。结果显示,优化后的简化机理不仅在在计算组分浓度,而且在层流预混火焰速度和组分时空分布方面,更加接近详细机理所能达到的计算结果,比优化之前的简化反应机理计算结果更加准确。 展开更多
关键词 氢气/空气燃烧 遗传算法 简化机理优化 反应速率参数
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端到端路径性能的检测 被引量:1
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作者 范霖 范超 《通信世界》 2002年第30期60-61,共2页
近年来VoP、VoD等实时应用在网络应用中比例大大增加,实时应用需要网络对其提供服务保证或区分服务,网络路径的延时特性和传输速率越来越受到人们的重视。网络延时和有效带宽直接反映了路径的性能和对端主机提供的服务等级水平,但它... 近年来VoP、VoD等实时应用在网络应用中比例大大增加,实时应用需要网络对其提供服务保证或区分服务,网络路径的延时特性和传输速率越来越受到人们的重视。网络延时和有效带宽直接反映了路径的性能和对端主机提供的服务等级水平,但它们都是随时间随机变化的变量,跟踪这些路径特征参数的动态变化可以获得资源的使用状况和性能趋势,并作为网络路径性能评价和实时的端到端性能管理的依据。 展开更多
关键词 路径性能 网络路径 传输速率 性能指标 路径速率参数
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酒石酸唑吡坦在模拟失重状态下SD大鼠体内十二指肠吸收特性
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作者 张旸 井娟 +4 位作者 赵军 张瑞涛 徐媛 刘雪英 王庆伟 《医药导报》 CAS 北大核心 2021年第4期450-454,共5页
目的研究酒石酸唑吡坦在模拟失重与正常SD大鼠体内十二指肠的吸收特性,并比较酒石酸唑吡坦在正常和模拟失重大鼠中十二指肠吸收变化。方法采用大鼠在体单向肠灌流模型,利用高效液相色谱(HPLC)法测定肠灌流液中酒石酸唑吡坦的含量,计算... 目的研究酒石酸唑吡坦在模拟失重与正常SD大鼠体内十二指肠的吸收特性,并比较酒石酸唑吡坦在正常和模拟失重大鼠中十二指肠吸收变化。方法采用大鼠在体单向肠灌流模型,利用高效液相色谱(HPLC)法测定肠灌流液中酒石酸唑吡坦的含量,计算有效渗透系数(P_(eff))和吸收速率参数(K_(a))。结果酒石酸唑吡坦在模拟失重SD大鼠体内十二指肠段的吸收参数与正常SD大鼠吸收参数的差异有统计学意义(P<0.05),其中模拟失重状态下大鼠十二指肠P_(eff)和K_(a)均减小。结论酒石酸唑吡坦在模拟失重状态下SD大鼠体内十二指肠P_(eff)和K_(a)均小于正常组SD大鼠,因此模拟失重状态会减少酒石酸唑吡坦在SD大鼠十二指肠段吸收程度和吸收速度。提示机体进入失重环境后需要调整酒石酸唑吡坦服用剂量。 展开更多
关键词 唑吡坦 酒石酸 模拟失重 在体单向肠灌流 色谱法 高效液相 十二指肠吸收 有效渗透系数 吸收速率参数
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Effect of Heat Stress on Photosynthetic Characteristics of Different Green Organs of Winter Wheat During Grain-filling Stage 被引量:28
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作者 徐晓玲 王志敏 张俊平 《Acta Botanica Sinica》 CSCD 2001年第6期571-577,共7页
Four winter wheat (Triticum aestivum L.) varieties ('JD 8', 'Jing 411','Centurk' and 'Tam 202') were used to study the effect of heat stress on photosynthetic characteristics of flag le... Four winter wheat (Triticum aestivum L.) varieties ('JD 8', 'Jing 411','Centurk' and 'Tam 202') were used to study the effect of heat stress on photosynthetic characteristics of flag leaf blade, nag leaf sheath, peduncle, glume, lemma and awn during grain-filling stage. The results showed that heat acclimation during grain-filling stage increased thermotolerance of wheat with significant differences among different green organs. During heat stress, the decreases of the efficiency of primary light energy conversion (F-v/F-m) of PS II and pigment (chlorophyll and carotenoid) content were much slower in peduncle, flag leaf sheath and glume than in nag leaf blade, lemma and ann; and the percentage of decrease in net photosynthetic rate (P-n) of ear was lower than that of the nag leaf blade. The measured photosynthetic parameters (F-v/F-m, P-n and pigment content) of 'JD 8', a relatively heat tolerant variety, declined more slowly than those of the other three varieties during the whole heat stress period. 展开更多
关键词 winter wheat net photosynthetic rate chlorophyll fluorescence kinetics parameters heat tolerance
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叶酸在模拟失重状态下SD大鼠体内十二指肠吸收特性分析研究
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作者 张旸 崔敏萱 +5 位作者 赵军 张瑞涛 周雪娇 于娇妍 井娟 王庆伟 《中国药师》 CAS 2020年第1期78-81,共4页
目的:研究叶酸在模拟失重与正常SD大鼠体内十二指肠的吸收特征,探索模拟失重1,2,3,4周时叶酸在SD大鼠体内十二指肠较正常组SD大鼠发生的改变。方法:采用大鼠在体单向肠灌流模型,用HPLC法测定灌流液中叶酸的含量,计算有效渗透系数(Peff)... 目的:研究叶酸在模拟失重与正常SD大鼠体内十二指肠的吸收特征,探索模拟失重1,2,3,4周时叶酸在SD大鼠体内十二指肠较正常组SD大鼠发生的改变。方法:采用大鼠在体单向肠灌流模型,用HPLC法测定灌流液中叶酸的含量,计算有效渗透系数(Peff)和吸收速率参数(Ka)。结果:叶酸在模拟失重SD大鼠体内十二指肠段的吸收参数与正常SD大鼠吸收参数的差异有统计学意义(P<0.05),其中模拟失重状态前3周随着时间增加十二指肠Peff和Ka增加,模拟失重状态第4周时肠吸收参数较前3周下降。结论:叶酸在模拟失重状态下SD大鼠体内十二指肠Peff和Ka均大于正常组SD大鼠,因此模拟失重状态对叶酸在SD大鼠十二指肠段的吸收有很大影响。 展开更多
关键词 叶酸 模拟失重 在体单向肠灌流 高效液相色谱法 十二指肠吸收 有效渗透系数 吸收速率参数
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微量热法研究黄嘌呤氧化酶反应
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作者 梁毅 汪存信 +2 位作者 屈松生 吴元欣 李定或 《化学世界》 CAS CSCD 1996年第S1期164-166,共3页
微量热法研究黄嘌呤氧化酶反应梁毅,汪存信,屈松生吴元欣,李定或(武汉大学化学系武汉430072)(武汉化工学院化工系武汉430072)我们已经用微量热法并结合单参数初始速率法的热动力学模型研究了过氧化氢酶反应[1]。... 微量热法研究黄嘌呤氧化酶反应梁毅,汪存信,屈松生吴元欣,李定或(武汉大学化学系武汉430072)(武汉化工学院化工系武汉430072)我们已经用微量热法并结合单参数初始速率法的热动力学模型研究了过氧化氢酶反应[1]。在此基础上,本文结合热导式热量计的... 展开更多
关键词 微量热法 黄嘌呤 较快酶促反应 参数初始速率 氧化酶反应 参数模型 热动力学模型 热动力学研究 感温滞后 米氏常数
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Effect of surface dissolution on kinetic parameters in flotation of ilmenite from different gangue minerals 被引量:10
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作者 Omid SALMANI NURI Mehdi IRANNAJAD Akbar MEHDILO 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2019年第12期2615-2626,共12页
The effects of acid surface dissolution on the flotation kinetics of ilmenite(IL)and its common accompanied gangue minerals including olivine-pyroxene(Ol-Px),tremolite-clinochlore(Tr-Cch)and quartz were investigated.T... The effects of acid surface dissolution on the flotation kinetics of ilmenite(IL)and its common accompanied gangue minerals including olivine-pyroxene(Ol-Px),tremolite-clinochlore(Tr-Cch)and quartz were investigated.The results show that through the surface dissolution the adsorption rate constant for ilmenite increases from 5.272 to 8.441 mol/(g·min)while it decreases for Ol-Px,Tr-Cch and quartz from 6.332,7.309 and 7.774 mol/(g·min)to 5.034,6.223 and 7.371 mol/(g·min),respectively.Also,the flotation experiments on a binary mixture of minerals indicate that after surface dissolution the values of modified rate constant for ilmenite flotation from Ol-Px,Tr-Cch and quartz are enhanced from 36.15,36.52 and 47.86 min-1 to 41.72,45.78 and 56.24 min-1,respectively.This results in the improvement of kinetic selectivity index(SI)in the separation of treated ilmenite from gangue minerals.As evidenced by ICP-MS analysis,the decrease of kinetic parameters for gangue minerals can be due to the removal of Fe^2+,Ca^2+and Mg^2+ions from their surfaces,which results in the lack of enough active sites to interact with collector species.As confirmed by contact angle measurements,this prevents the formation of a stable hydrophobic layer on the minerals surfaces for creating stable attachments between minerals and bubbles.Generally,the improvement of ilmenite flotation kinetics has a negative correlation with the iron content in its accompanied gangue minerals. 展开更多
关键词 surface dissolution FLOTATION kinetic parameters modified rate constant selectivity index collector adsorption
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Influence of the operating parameters over the current efficiency and corrosion rate in the Hall–Heroult aluminum cell with tin oxide anode substrate material 被引量:2
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作者 Virgil Constantin 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2015年第4期722-726,共5页
A systematic laboratory study was conducted on current efficiency and corrosion obtained in cryolite-alumina melts with SnO2-Sb203-CuO ceramic inert anodes. The current efficiency (CE) was determined by measuring th... A systematic laboratory study was conducted on current efficiency and corrosion obtained in cryolite-alumina melts with SnO2-Sb203-CuO ceramic inert anodes. The current efficiency (CE) was determined by measuring the total amount of oxygen evolved at the anode and was found to be ~ 95%. The influence of operating parameters (inter-elec- trode distance, temperature and current density) was evaluated. The quantitative interdependencies as well as the ranges of CE optima[ values were established (2-3 cm, 940-960 ℃ and 0.7-0.8 A.cm 2). The corrosion process of these anodes was evaluated by the mass loss method. The evaluation also took care of the corrosion data, as the prob- lem of the anode corrosion appeared to be the main obstacle for the use of those anodes in the commercial cells.Low-ering of the ACD up to 2 cm did not aggravate anode corrosion. 展开更多
关键词 Aluminum electrolysisCurrent efficiencyCorrosionInert anodes
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RATE ADAPTIVE PROTOCOL FOR MULTIRATE IEEE 802.11 NETWORKS 被引量:1
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作者 Xi Yong Huang Qingyan +1 位作者 Wei Jibo Zhao Haitao 《Journal of Electronics(China)》 2007年第3期289-295,共7页
In this paper, a rate adaptive protocol AMARF (Adaptive Multirate Auto Rate Fallback) for multirate IEEE 802.11 networks is proposed. In AMARF, each data rate is assigned a unique success threshold, which is a criteri... In this paper, a rate adaptive protocol AMARF (Adaptive Multirate Auto Rate Fallback) for multirate IEEE 802.11 networks is proposed. In AMARF, each data rate is assigned a unique success threshold, which is a criterion to judge when to switch a rate to the next higher one, and the success thresholds can be adjusted dynamically in an adaptive manner according to the running conditions, such as packet length and channel parameters. Moreover, the proposed protocol can be implemented by software without any change to the current IEEE 802.11 standards. Simulation result shows that AMARF yields significantly higher throughput than other existing schemes including ARF and its variants, in various running conditions. 展开更多
关键词 IEEE 802.11 Rate adaptive MULTIRATE
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Kinetics of celestite conversion to acidic strontium oxalate hydrate in aqueous solution of oxalic acid 被引量:1
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作者 Mert ZORAGA Cem KAHRUMAN Ibrahim YUSUFOGLU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2019年第6期1332-1345,共14页
Conversion of SrSO4 to acidic strontium oxalate hydrate(H[Sr(C2O4)1.5(H2O)]) in aqueous H2C2O4 solutions proceeds as a consecutive reaction. In the first step of the consecutive reaction, SrSO4 reacts with H2C2O4 and ... Conversion of SrSO4 to acidic strontium oxalate hydrate(H[Sr(C2O4)1.5(H2O)]) in aqueous H2C2O4 solutions proceeds as a consecutive reaction. In the first step of the consecutive reaction, SrSO4 reacts with H2C2O4 and pseudomorphic conversion to SrC2 O4·H2O occurs. In the second step, SrC2 O4·H2O reacts with H2C2O4 to form H[Sr(C2 O4)1.5(H2O)]. Sr(HC2 O4)(C2 O4)0.5·H2 O crystallizes during cooling of the reaction mixture to room temperature if the solution reaches the saturation concentration of (H[Sr(C2O4)1.5(H2O)]. The aims of this study are the derivation of reaction rate equations and the determination of the kinetic parameters such as pre-exponential factor, apparent activation energy and order of H2C2O4 concentration for each reaction step.Fractional conversions of SrSO4 were calculated using the quantitative amounts of dissolved S and Sr. It was determined that the reaction rate increased at the initial time of reaction by increasing the temperature using solutions with approximately same H2C2O4 concentrations. The reaction extends very slowly after a certain time in solutions with low H2C2O4 concentration and ends by the formation of a protective layer of SrC2O4-H2O around the surfaces of solid particles. Fractional conversion of SrSO4 is increased by increasing concentration of H2C2O4 at constant temperature. Kinetic model equations were derived using shrinking core model for each step. 展开更多
关键词 celestite concentrate pseudomorphic conversion rate equations kinetic parameters conversion reaction
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Combustion characteristics of Daqing oil shale and oil shale semi-cokes 被引量:8
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作者 MIAO Zhen-yong WU Ouo-guang LI Ping ZHAO Na WANG Pan-cheng MENG Xian-liang 《Mining Science and Technology》 EI CAS 2009年第3期380-384,共5页
Thermo-gravimetric-analysis(TGA) was used to analyze the combustion characteristics of an oil shale and semi-cokes prepared from it.The effect of prior pyrolysis and TGA heating rate on the combustion process was stud... Thermo-gravimetric-analysis(TGA) was used to analyze the combustion characteristics of an oil shale and semi-cokes prepared from it.The effect of prior pyrolysis and TGA heating rate on the combustion process was studied.Prior pyrolysis affects the initial temperature of mass loss and the ignition temperature.The ignition temperature increases as the volatile content of the sample decreases.TG/DTG curves obtained at different heating rates show that heating rate has little effect on ignition temperature.But the peak of combustion shifts to higher temperatures as the heating rate is increased.The Coats-Redfern integration method was employed to find the combustion-reaction kinetic parameters for the burning of oil shale and oil shale semi-coke. 展开更多
关键词 oil shale SEMI-COKE combustion characteristics pyrolysis degree h-eating rate
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THE THEORETICAL MODEL FOR PREDICTING CIRCULATION VELOCITY OF HYDRAULIC BRAKE
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作者 刘英林 侯春生 《Journal of Coal Science & Engineering(China)》 1997年第1期54-59,共6页
By rational hypothesis of fluid flow pattern, applied the law of conservation of energy and integrated the laboratory test results, finished the prediction by the theoretical model of cir-culation velocity of hydrauli... By rational hypothesis of fluid flow pattern, applied the law of conservation of energy and integrated the laboratory test results, finished the prediction by the theoretical model of cir-culation velocity of hydraulic brake which is important parameter. Thus provide the theoritical basis for hydraulic brake of bblt conveyor whose research has just been started. 展开更多
关键词 FLUID BRAKE THEORY
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A Velocity Map Ion-imaging Study on Ketene Photodissociation at 218 nm 被引量:1
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作者 Jie Liu Feng-yan Wang +2 位作者 Hua Wang Bo Jiang Xue-ming Yang 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2006年第1期1-5,共5页
Photodissociation dynamics of ketene at 218 nm has been investigated using the velocity map ion-imaging method. Both angular and translational energy distributions for the CO products at different rotational and vibra... Photodissociation dynamics of ketene at 218 nm has been investigated using the velocity map ion-imaging method. Both angular and translational energy distributions for the CO products at different rotational and vibrational states have been obtained. The 2+1 REMPI spectrum of CO products is also obtained. The results are as bellow: (i) CO products in the first two vibrational states ( v"=0 and v"=1 ) exhibit significant rotational excitation. Furthermore the rotational excitation of CO at the v"=0 level is noticeably higher than that at the v"=1 level. (ii) It was found that the major photodissociation pathway of ketene at 218 nm is the CH2(ǎ^1A1)+CO(X^1∑^+) channel, while the CH2(b^1B1)+CO(X^1∑^+) channel and the CH2(X^3B1)+CO(X^1E^+) channel are also likely present, (iii) The anisotropy parameters β of CO different rovibronic states all appear to be larger than zero. No significant difference is observed at the two vibrational states, 展开更多
关键词 Velocity map ion-imaging PHOTODISSOCIATION Anisotropy parameter Translational energy distribution
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