The controlling step and the extraction reaction rate equation of zinc extraction from Zn（II）-NH3 solution by using a newly synthesized organic compound, 2-acetyl-3-oxo-dithiobutyric acid-myristyl ester as the zinc ...The controlling step and the extraction reaction rate equation of zinc extraction from Zn（II）-NH3 solution by using a newly synthesized organic compound, 2-acetyl-3-oxo-dithiobutyric acid-myristyl ester as the zinc extractant, were clarified. The effects of agitation speed, specific interfacial area, temperature, extractant concentration and Zn ion concentration on the extraction rate are studied in constant interfacial area cell. The results show that the extraction rate depends on interfacial chemical reaction and diffusion by using this new extraetant to extract zinc, and the apparent activation energy of this extraction reaction is measured as 28.2 kJ/mol, which demonstrates that the extraction reaction is controlled by the mixed-controlled reaction rate. The apparent reaction orders a and b are measured as 1 and 0.38, and the constant k0 is 138.70. So, when extraction conditions are controlled as [HR]=20%-50%, T=0-30℃, N=120-177 r/min and S=72.6-127.5 m-1, the solvent extraction reaction rate can be depicted as v/（mol . m-2 . s-1 ） = 138.7. exp（ - 28 206/8.314T ）. [Zn 2＋ ]r ·[HR ]o0.38.展开更多
In this paper we analyze the influence of free convection on nonlinear peristaltic transport of a Jeffrey fluid in a finite vertical porous stratum using the Brinkman model. Heat is generated within the fluid by both ...In this paper we analyze the influence of free convection on nonlinear peristaltic transport of a Jeffrey fluid in a finite vertical porous stratum using the Brinkman model. Heat is generated within the fluid by both viscous and Darcy dissipations. The coupled nonlinear governing equations are solved analytically. The expressions for the temperature, the axial velocity, the local wall shear stress and the pressure gradient are obtained. The effects of various physical parameters such as the Jeffrey parameter λ1, the permeability parameter σ and the heat source/sink parameter β are analyzed through graphs, and the results are discussed in detail. It is observed that the velocity field increases with increasing values of the Jeffrey parameter but it decreases with increasing values of the permeability parameter. It is found that the pressure rise increases with decreasing Jeffrey parameter and increasing permeability parameter. We notice that the effect of the permeability parameter a is the strongest on the bolus trapping phenomenon. For λ1 = 0, N =0, the results of the present study reduce to the results of Tripathi [Math. Comput.Modelling 57 （2013） 1270-1283]. Further the effect of viscous and Darcy dissipations is to reduce the rate of heat transfer in the finite vertical porous channel under peristalsis.展开更多
基金Foundation item： Project（51174240） supported by the National Natural Science Foundation of China Project（2006BA02B04-4-2） supported by the National Eleventh Five-Year Research Program of China Project（20100908） supported by Scientific and Industrial Research Organisation of Guangdong Province, China
文摘The controlling step and the extraction reaction rate equation of zinc extraction from Zn（II）-NH3 solution by using a newly synthesized organic compound, 2-acetyl-3-oxo-dithiobutyric acid-myristyl ester as the zinc extractant, were clarified. The effects of agitation speed, specific interfacial area, temperature, extractant concentration and Zn ion concentration on the extraction rate are studied in constant interfacial area cell. The results show that the extraction rate depends on interfacial chemical reaction and diffusion by using this new extraetant to extract zinc, and the apparent activation energy of this extraction reaction is measured as 28.2 kJ/mol, which demonstrates that the extraction reaction is controlled by the mixed-controlled reaction rate. The apparent reaction orders a and b are measured as 1 and 0.38, and the constant k0 is 138.70. So, when extraction conditions are controlled as [HR]=20%-50%, T=0-30℃, N=120-177 r/min and S=72.6-127.5 m-1, the solvent extraction reaction rate can be depicted as v/（mol . m-2 . s-1 ） = 138.7. exp（ - 28 206/8.314T ）. [Zn 2＋ ]r ·[HR ]o0.38.
文摘In this paper we analyze the influence of free convection on nonlinear peristaltic transport of a Jeffrey fluid in a finite vertical porous stratum using the Brinkman model. Heat is generated within the fluid by both viscous and Darcy dissipations. The coupled nonlinear governing equations are solved analytically. The expressions for the temperature, the axial velocity, the local wall shear stress and the pressure gradient are obtained. The effects of various physical parameters such as the Jeffrey parameter λ1, the permeability parameter σ and the heat source/sink parameter β are analyzed through graphs, and the results are discussed in detail. It is observed that the velocity field increases with increasing values of the Jeffrey parameter but it decreases with increasing values of the permeability parameter. It is found that the pressure rise increases with decreasing Jeffrey parameter and increasing permeability parameter. We notice that the effect of the permeability parameter a is the strongest on the bolus trapping phenomenon. For λ1 = 0, N =0, the results of the present study reduce to the results of Tripathi [Math. Comput.Modelling 57 （2013） 1270-1283]. Further the effect of viscous and Darcy dissipations is to reduce the rate of heat transfer in the finite vertical porous channel under peristalsis.
