速聚型壳法用热塑性酚醛树脂的合成

先用1#弱酸性物质作催化剂,再用强酸(2#催化剂)进一步催化,通过对合成工艺因素优化制备了聚合速度20～30s,软化点80～90℃适用于壳法工艺的速聚型热塑性酚醛树脂。

速聚剂在环保刨花板生产中的应用

采用较高物质量比脲醛树脂和添加速聚剂的制备工艺,能稳定生产物理力学性能满足GB/T 4897-2015《刨花板》中干燥状态下使用的家具型刨花板的要求和甲醛释放量≤5 mg/100 g的环保刨花板,与传统低物质量比脲醛树脂技术相比,可以提高生产速度,降低生产成本。

高邻位热塑性酚醛树脂的合成

以甲醛、苯酚为原料，盐酸为强酸催化剂、醋酸锌为弱酸盐催化剂，采用分段聚合方式，合成了聚合速度30-40s、软化点85～95℃的速聚型热塑性酚醛树脂。树脂的热塑性质和邻位、对位结构通过DSC、FT—IR确证。树脂的热稳定性通过TG测定。

L波段强流单束团注入器的束流动力学计算

自由电子激光器要求高亮度、低能散度的电子束注入波荡器(Undulator)。本文叙述提供高亮度电子束的高频电子直线加速器中的注入器部分的设计计算。注入器由L波段(1300MHz)的十二分频和三分频两个谐振腔预聚束器和一个基波频率的变相速聚束器组成。粒子运动方程中考虑了空间电荷效应和束流负载效应。电子枪的注入参数:脉冲宽度T=4ns;电流I=5A;电子的初始动能E_0=100keV;电子束分布为高斯型。参数优化设计结果:单束团宽度小于25ps,峰值电流达400A以上,电子的平均归一化能量>4,束团内的能量差小于200keV。

Investigating Jet Appearance in Different Background Lights with High-Speed Frame Photography

Shaped charge jet formation process is studied under the conditions of different background lights by means of high speed frame photography. In order to shoot true jet appearance, the glass tube in which jet moves is vacuumized. The experiment results show that observing jet appearance with the double reflecting mirrors system is feasible as long as the vacuum of the glass tube can meet the requirement of experiment.

An accelerated method to evaluate thymopentin release from microspheres in vitro

To design an accelerated method to evaluate thymopentin release from PLGA microspheres in vitro. Microspheres were prepared by double emulsion technique, using poly（lactide-co-glycolide） （PLGA） as carrier. At higher medium temperature （45℃, 50℃ and 55℃）, an accelerated release testing in short time was studied and correlated with the conventional release （37℃） in vitro. The release in vitro of thymopentin from PLGA microspheres at 45 ℃, 50℃ and 55℃ was significantly accelerated （P 〈 0.05）. In particular, at 50℃, an accelerated release （30 h） of the hydrophilic peptide from the PLGA matrix was achieved and correlated well with the conventional release （30 d）. An accelerated release testing in vitro at higher temperature could be used to monitor thymopentin release from PLGA microspheres.

Segregation of niobium in laser cladding Inconel 718 superalloy

Inconel 718 superalloy is widely used in the aerospace and turbine industry. Segregation of niobium appears in the laser cladding Inconel 718 superalloy and consequently influences the phase transformation during the rapid solidification. In order to control the microstructure and improve the mechanical properties of the deposited coating, the the influence of solidification conditions on the segregation of niobium and the resultant formation of Nb-rich Laves phase was studied using the microstructure observation and EDS analysis. The results show that the cooling rate has considerable influence on the microstructure of the deposited coating. High cooling rate is beneficial for suppressing the segregation of Nb and reducing the formation of Laves phase, which is believed to be detrimental to the performance of the Inconel 718 alloy.

Thermosensitive Poly(N-isopropylacrylamide-co-acrylonitrile) Hydrogels with Rapid Response

Acrylonitrile (AN) was copolymerized with N-isopropylacrylamide (NIPA) to synthesize thermosensitive hy-drogels, and the on-off switch behavior of poly(NIPA-co-AN) hydrogels with different fraction of hydrophobic compo-nent (AN) was investigated. It is found that the lower critical solution temperature (LCST), the swelling ratio at certain temperature and the reswelling rate of poly(NIPA-co-AN) hydrogels decreased as AN unit fraction in copolymers in-creased. In order to improve the responsive rate of poly(NIPA-co-AN) hydrogels, they were further treated by surface crosslinking using N, N′-methylene bisacrylamide (BIS) as a crosslinking agent. The swelling and deswelling behaviors of these copolymers were compared with those of the untreated hydrogels. The results indicated that the responsive rate of poly(NIPA-co-AN) hydrogel was improved by surface crosslinking. The resulting hydrogels bearing cyano groups with fast response have potential applications in the field of drug-controlled release and immobilization of biomolecules.

Characteristic of Drop Coalescence Resting on Liquid-Liquid Interface

The trajectory model of dispersed phase drops and the model of basic flow for drop motion between two inclined parallel plates are derived with the optimized calculation. The analytical results of direct numerical simulation indicate that the basic flow plays an important role in the drop coalescence on liquid-liquid interface. In the stratified two-phase flow field, the smaller droplets are difficult to drain the thin continuous film between the approaching droplets and bulk interfaces and eventually immerse into the trickling film to yield coalescence. They almost attain the velocity of their local surroundings. Moreover, the basic flow exerts a dominant influence on the motion of smaller droplet. The smaller droplets are easily entrained by the basic flow. On the contrary, the larger drop presents advantageous characteristics of coalescence due to its high velocity. The range of 0.3 mm < δR≤ 0.75 mm is the advantageous drop coalescence condition since the rapidly varied velocity and its first derivative theoretically cause the forces acting on a drop to become imbalanced. On the other hand, the thin layer of the continuous phase drained from the interval between the drops and trickling film should not be neglected in the calculation of shearing force since it is important for drop rotation. The drop rotation is an indispensable factor in coalescence.

Simulation of Rate Retardation in RAFT Polymerization of Styrene with Low RAFT-Initiator Ratio

Bulk polymerizations of styrene (St) were carried out in the presence of three reversible addition fragmentation chain transfer (RAFT) agents benzyl dithiobenzoate (BDB), cumyl dithiobenzoate(CDB), and 1-phenylethyl dithiobenzoate (PEDB) under low ratio of RAFT agent to initiator. The kinetic model was developed to predict polymerization rate, which indicates that the RAFT polymerization of St is a first-order reaction. In the range of experimental conversions, the plots of -ln(1-x) against time t are approximately linear (x is monomer conversion). The kinetic study reveals the existence of strong rate retardation in RAFT polymerization of styrene. A coefficient K_r is defined to estimate the rate retardation in the RAFT system considering the assumption that the retardation in polymerization rate is mainly attributed to slow fragmentation of the intermediate radicals. K_r relates to the structure of RAFT agents as well as the concentrations of RAFT agent and azobis isobutyronitrile (AIBN). For a certain RAFT agent, the value of K_r is enhanced by the increase in the initial concentration of RAFT agent and the higher ratio of RAFT to AIBN. With the same recipe for different RAFT agents, the increasing trend for the values of K_r is BDB<PEDB<CDB.

Influence of Wind Speed on Heat Flow through Polypropylene Insulating Material

The heat transfer properties of polypropylene insulation at different ambient temperature against wind were analysed. A theoretical model of the combined conductive, convective and radiative heat flow through fibrous insulating material was presented. Detail study was carried out by using the finite element method. The theoretical results are in accordance to the experimental results which were accomplished in an artificial climate chamber.

RECENT ADVANCES IN THE PREPARATION OF MOLECULARLY IMPRINTED POLYMERS VIA CONTROLLED RADICAL POLYMERIZATION TECHNIQUES

Molecular imprinting technique is a simple and efficient method for the preparation of polymer materials (i.e., molecularly imprinted polymers, MIPs) with tailor-made recognition sites for certain target molecules. The resulting MIPs have proven to be versatile synthetic receptors due to their high specific recognition ability, favorable mechanical, thermal and chemical stability, and ease of preparation. Recent years have witnessed significant progress in the synthesis and applications of MIPs. This review focus on the recent developments and advances in the preparation of MIPs via various controlled radical polymerization techniques.

Numerical simulatim of rainwater accumulation and flow characteristics over windshield of high-speed trains

In this paper, a Euler-Lagrangian particle/fluid film/VOF coupled multiphase flow model is presented. Numerical simulations are conducted, and the rainwater accumulation and flow characteristics over two types of windshields are studied based on the presented model. The results show that an uneven water film is formed over the windshield, with rain water accumulation occurring for the concave windshield but not for the convex windshield. At low speeds, the average fluid-film thickness for a concave windshield is larger than that of a convex windshield;however, a minor difference occurs between these two values at high speeds, and a critical velocity is observed for the two types of windshields. When the train velocity is less than the critical velocity, the fluid film at the lower part of the windshield and the train nose flows downward, and beyond the critical velocity, the fluid film over the entire windshield and train nose flows upward.

Nonlinear Characteristics of an Intense Laser Pulse Propagating in Partially Stripped Plasmas

The nonlinear optic characteristics of an intense laser pulse propagating in partially stripped plasmas are investigated analytically. The phase and group velocity of the laser pulse propagation as well as the three general expressions governing the nonlinear optic behavior, based on the photon number conservation, are obtained by considering the partially stripped plasma as a nonlinear optic medium. The numerical result shows that the presence of the bound electrons in partially stripped plasma can significantly change the propagating property of the intense laser pulse.

Ring-Polymer Molecular Dynamics Studies of Thermal Rate Coefficients for Reaction F+H2O→HF+OH

The prototype tetra-atomic reaction F+H2O→HF+OH plays a significant role in both atmospheric and astronomical chemistry.In this work,thermal rate coefficients of this reaction are determined with the ring polymer molecular dynamics(RPMD)method on a full-dimensional potential energy surface(PES).This PES is the most accurate one for the title reaction,as demonstrated by the correct barrier height and reaction energy,compared to the benchmark calculations by the focal point analysis and the high accuracy extrapolated ab initio thermochemistry methods.The RPMD rate coefficients are in excellent agreement with those calculated by the semiclassical transition state theory and a two-dimensional master equation technique,and some experimental measurements.As has been found in many RPMD applications,quantum effects,including tunneling and zero-point energy effects,can be efficiently and effectively captured by the RPMD method.In addition,the convergence of the results with respect to the number of beads is rapid,which is also consistent with previous RPMD applications.

A rapid method for determination of acid value in transformer oil by PPy modified electrode

A polypyrrole-modified glassy carbon electrode （PPy/GC electrode） was prepared and its electrocatalytic behavior towards naphthoquinone in the presence of acid was characterized by linear sweep voltammetry （LSV）. A well-defined new reduction peak appeared at a more positive potential than the original reduction peak. The new reduction peak current was linearly related to the acid value （AV） of oil. Based on it, a rapid electrochemical method for determining AV of transformer oil was developed using PPy/GC electrode. A working curve was obtained in the AV range of 0.01 to 0.40 mg（KOH）.g^-1, with a sensitivity of 39.42 μA0.5/（mg（KOH）.g-l） and the detection limit of 0.0014 mg（KOH）.g^-1 （signal-to-noise ratio is 3, standard deviation is 2.247%）. Moreover, the proposed method has been successfully applied to AV determination of several transformer oil samples with advantages of rapidness, high sensitivity and accuracy compared to the conventional method.

Gender and tachycardia： independent modulation of platelet reactivity in patients with atrial fibrillation

Background Female patients with atrial fibrillation （AF） experience increased risk of thromboembolism compared to males, an observation that is reflected by its inclusion in the CHA2DS2VASc score. New onset AF （often associated with tachycardia） also confers upon patients increased thromboembolic risk. The mechanisms underlying this risk are uncertain, but new onset AF is associated with profound impairment of platelet nitric oxide （NO） signalling. Given that cardiovascular responses to catecholamines are gender-dependent, and that the presence of tachycardia in new onset AF may represent a response to catecholaminergic stimulation, we explored the potential impact of gender and tachycardia on platelet aggregation and NO signalling. Methods Interactions were sought in 87 AF patients between the extent of adenosine diphosphate （ADP）-induced platelet aggregation, the anti-aggregatory effects of the NO donor, sodium nitroprusside, gender, and admission heart rate. The potential impact of platelet expression of thioredoxin-interacting protein （Txnip） was also evaluated. Results Analysis ofcovariance confLrmed the presence of physiological antagonism between platelet ADP and NO responses [F （1, 74） = 12.212, P 〈 0.01 ], while female sex correlated with impaired NO responses independent of platelet aggregability [F （2, 74） = 8.313, P 〈 0.01]. Admission heart rate correlated directly with platelet aggregation （r = 0.235, P 〈 0.05）, and inversely with NO response （r = -0.331, P 〈 0.01）. Txnip expression varied neither with gender nor with heart rate. Conclusions These results indicate, that gender and heart rate are independent determinants of platelet fimction. Prospective studies of the putative benefit of reversal of tachycardia on restoration of normal platelet function are therefore a priority.

Design and Simulation of Solenoid for Buncher of a Linear Accelerator

One of the most important components of a linac is bunchcr. Throughout most of the buncher, the electrons are well forward of the crest and have velocities considerably less than light velocity, thus they arc in a region of radial dcfocusing and a considerable fraction of the beam will be lost unless defocusing action is counteracted by some other applied forces. The simplest way to do this is to sct up a longitudinal magnetic field which intcmcts with the radial motion of the electrons and causes them to follow helical orbits through the space occupied by the field. In this paper, five solenoids were designed to provide necessary magnetic field inside the bunchcr. Magnetic field was analytically calculated and compared with simulation results of Computer Simulation Technology （CST）. Because of resistance in wires, some amount of energy appears in form of heat, so heat power was calculated analytically and cooling system was designed for these solenoids by Analysis System （ANSYS）.

ADSORPTION OF PHENOL AND NITROPHENOLS ON A HYPERCROSSLINKED POLYMERIC ADSORBENT

The adsorption of phenol and nitrophenols on hypercrosslinked polymeric adsorbent was studied as a function of the solution concentration and temperature. Adsorption isotherms of phenol and nitrophenols on hypercrosslinked resin were determined. These isotherms were modeled according to the Freundlich adsorption isotherm. The isotherms for phenol and nitrophenols on hypercrosslinked resin were assigned as L curves. Thermodynamic parameters were calculated for all phenol and nitrophenols. The kinetics experiment results showed that the adsorption rates were of the first-order kinetics. The rate constants at 303K were calculated.

Research on Image Segmentation Algorithm based on Fuzzy C-mean Clustering

This paper presents a fuzzy C- means clustering image segmentation algorithm based on particle swarm optimization, the method utilizes the strong search ability of particle swarm clustering search center. Because the search clustering center has small amount of calculation according to density, so it can greatly improve the calculation speed of fuzzy C- means algorithm. The experimental results show that, this method can make the fuzzy clustering to obviously improve the speed, so it can achieve fast image segmentation.