We derive a formula for double-pulse spectra from closed-orbit theory. We then calculate the double-pulse photodetachment spectra of H<SUP>?</SUP> in the presence of parallel electric and magnetic fields. ...We derive a formula for double-pulse spectra from closed-orbit theory. We then calculate the double-pulse photodetachment spectra of H<SUP>?</SUP> in the presence of parallel electric and magnetic fields. We analyze the spectra in terms of closed-orbits of the system. We suggest a method for the measurement of a phase associated with each closed-orbit.展开更多
The influence of the interaction between surrounding rock and lining on the long-term behaviour of a tunnel in service is significant.In this paper,we proposed a mechanical model of the circular lined tunnel with the ...The influence of the interaction between surrounding rock and lining on the long-term behaviour of a tunnel in service is significant.In this paper,we proposed a mechanical model of the circular lined tunnel with the alterable mechanical property under hydrostatic stress and radially inner surface pressure of the lining.The alterable mechanical properties of the surrounding rock and the lining are embodied by the changing of their elasticity modulus with service time and radial direction of the tunnel,respectively.The proposed mechanical model is successfully validated by comparison with the existing theoretical models and the numerical simulation,respectively.The influences of the main parameters of the proposed mechanical model,such as the radial power-law indexes and the time-varying coefficients of the surrounding rock and the lining,as well as the radially inner surface pressure of the lining,on the interface displacement and pressure between surrounding rock and lining are investigated.The research results can provide some valuable references for timely diagnosis and correct evaluation of the long-term behaviours of a tunnel in service.展开更多
We propose a remote state preparation (RSP) scheme of three-particle Greenberger Horne-Zeilinger (GHZ) class states, where quantum channels are composed of two maximally entangled states. With the aid of forward c...We propose a remote state preparation (RSP) scheme of three-particle Greenberger Horne-Zeilinger (GHZ) class states, where quantum channels are composed of two maximally entangled states. With the aid of forward classical bits, the preparation of the original state can be successfully realized with the probability 1/2, the necessary classical communication cost is 0.5 bit on average. If the state to be prepared belongs to some special states, the success probability of preparation can achieve 1 after consuming one extra bit on average. We then generalize this scheme to the case that the quantum channels consist of two non-maximally entangled states.展开更多
In order to clarify the mechanism of optical transitions for cubic SrHfO_3, we have investigated the electronicstructure and optical properties of cubic SrHfO_3 using the plane-wave ultrasoft pseudopotential technique...In order to clarify the mechanism of optical transitions for cubic SrHfO_3, we have investigated the electronicstructure and optical properties of cubic SrHfO_3 using the plane-wave ultrasoft pseudopotential technique based on thefirst-principles density-functional theory (DFT).The ground-state properties, obtained by minimizing the total energy,are in favorable agreement with the previous work.From the band structure and charge densities as well as the theoryof crystal-field and molecular-orbital bonding, we have systematically studied how the optical transitions are affected bythe electronic structure and molecular orbitals.Our calculated complex dielectric function is in good agreement withthe experimental data and the optical transitions are in accord with the electronic structure.展开更多
We propose a method to implement a kind of non-local operation between spatially separated two systems with high dimensions by using only a low-dimensional qubit quantum channel and 2-bit classical communication. For ...We propose a method to implement a kind of non-local operation between spatially separated two systems with high dimensions by using only a low-dimensional qubit quantum channel and 2-bit classical communication. For qutrit systems, we further show the creation of non-local maximally entangled state and the construction of the non-local quantum XOR gate in terms of the obtained non-local operations as well as some single qutrit local gates.展开更多
Using the photon closed orbit theory, the spontaneous emission rate of a polarized atom in a medium between two parallel mirrors is derived and calculated. It is found that the spontaneous emission rate of a polarized...Using the photon closed orbit theory, the spontaneous emission rate of a polarized atom in a medium between two parallel mirrors is derived and calculated. It is found that the spontaneous emission rate of a polarized atom between the mirrors is related to the atomic position and the polarization direction. The results show that in the vicinity of the mirror, the variation of the spontaneous emission rate depends crucially on the atomic polarization direction. With the increase of the polarization angle, the oscillation in the spontaneous emission rate becomes decreased. For the polarization direction parallel to the mirror plane, the oscillation is the greatest; while for the perpendicular polarization direction, the oscillation is nearly vanished. The agreement between our result and the quantum electrodynamics result suggests the correctness of our calculation. This study further verifies that the atomic spontaneous emission process can be effectively controlled by changing the polarization orientation of the atom.展开更多
Using closed orbit theory, we give a clear physical picture description of the Rydberg hydrogen atom near a metal surface and calculate the Fourier transformed recurrence spectra of this system at different scaled ene...Using closed orbit theory, we give a clear physical picture description of the Rydberg hydrogen atom near a metal surface and calculate the Fourier transformed recurrence spectra of this system at different scaled energies below ionization threshold. The results show that with the increase of the scaled energy, the number of the closed orbit increases greatly. Some of the orbits are created by the bifurcation of the perpendicular orbit. This case is quite similar to the Rydberg atom in an electric field. When the scaled energy increases furthermore, chaotic orbits appear. This study provides a different perspective on the dynamical behavior of the Rydberg atom near a metal surface.展开更多
2,4-diphenylpentane- and 2,4-di-p-tolylpentane-2,4-diols were investigated employing experimental and density functional theory (DFT) method at B3LYP/6-31G (d) level. The structure of syn-2,4-di-p-tolylpentane-2,4...2,4-diphenylpentane- and 2,4-di-p-tolylpentane-2,4-diols were investigated employing experimental and density functional theory (DFT) method at B3LYP/6-31G (d) level. The structure of syn-2,4-di-p-tolylpentane-2,4-diol (2b) was characterized by X-ray diffraction and compared with the crystal structures of anti- and syn-2,4-diphenylpentane-2,4-diols (la and lb). X-ray diffraction indicates that inter and intra-molecular hydrogen bonds are formed in the crystal structures. There is n-n staking interaction in lb and 2b. Good linear correlations and similar results are found between the experimental 1H and 13C NMR chemical shifts (6~exp) and GIAO (Gauge Independent Atomic Orbital) method calculated magnetic isotropic shielding tensors (acalc). HOMO and LUMO molecular orbitals were calculated at the same levels with the different results. UV-vis absorption spectra of the compounds were recorded in EtOH, MeCN, n-BuOH and cyclohexane with different dielectric constants. It is found that the solvent effect is obvious when e is 24.85(EtOH), 35.69(MeCN) and it is weak when e is decreased to 17.33(n-BuOH), 1.18 (cyclohexane).展开更多
Based on the magnetospheric kinetic theory, a model is developed to specify the flux of energetic electrons in the inner and middle magnetosphere. Under the assumption of adiabatic motion and isotropic particle distri...Based on the magnetospheric kinetic theory, a model is developed to specify the flux of energetic electrons in the inner and middle magnetosphere. Under the assumption of adiabatic motion and isotropic particle distribution maintained by pitch-angle scattering, the model calculates the electron flux by following bounce-averaged electric field, gradient, and curvature drift in the time dependent electric and magnetic field, meanwhile it counts the electron loss caused by pitch angle scattering. Using the model, the clectron flux distribution during a magnetic storm was calculated and compared with the observation data from the geosynchronous orbit. It is shown that the model can successfully reproduce most of the major electron flux enhancements observed at the geosynchronous orbit and generally tracks the satellite data well. The rms errors of the modeled logarithm of flux are between 0.5-1.0.展开更多
The Tibetan Plateau is a large-scale tectonic geomorphologic unit formed by the interactions of plates.It has been commonly believed that convective removal of the thickened Tibetan lithosphere,or lateral flow of the ...The Tibetan Plateau is a large-scale tectonic geomorphologic unit formed by the interactions of plates.It has been commonly believed that convective removal of the thickened Tibetan lithosphere,or lateral flow of the lower crust beneath the Tibetan plateau plays a crucial role in the formation of the large-scale tectonic geomorphologic features.Recent geological and geo-physical observations have provided important evidence in support of the lower crustal channel flow model.However,it re-mains unclear as how the geometry of lower crustal channel and the lateral variation of crustal rheology within the lower crust channel may have affected spatio-temporal evolution of the tectonic geomorphologic unit of the Tibetan Plateau.Here,we use numerical methods to explore the mechanical relations between the lower crustal channel flow and the tectonic geomorpho-logic formation around the eastern Tibetan plateau,by deriving a series of governing equations from fluid mechanics theory.From numerous tests,our results show that the viscosity of the channeled lower crust is about(1-5)×1018 to(1-4)×1020 Pa s(Pa.s) beneath the margin of the eastern Tibetan Plateau,and increases to about 1022 Pa s beneath the Sichuan Basin and the southern region of Yunnan Province.Numerical tests also indicate that if channel flows of the lower crust exist,the horizontal propagation and the vertical uplifting rate of the eastern Tibetan Plateau margin could be accelerated with the time.Thus,the present results could be useful to constrain the rheological structure of the crust beneath the eastern Tibetan plateau,and to understand the possible mechanics of rapid uplift of the eastern Tibetan Plateau margin,especially since its occurrence at 8Ma as revealed by numerous geological observations.展开更多
In a meandering fiver, a certain scale of turbulent vortex dominates the development of fiver morphology, making the river bend with s particular curvature. This kind of vortex is denoted as "bend-forming vortex". T...In a meandering fiver, a certain scale of turbulent vortex dominates the development of fiver morphology, making the river bend with s particular curvature. This kind of vortex is denoted as "bend-forming vortex". The coordinated relationship of bend-forming vortex and meandering fiver channel is then known as "self-adaption feature" of rivers. With these two concepts, this paper investigated the stability and self-adaption character of coherent vortex in the U-shape river bend with a constant curvature. On the basis of fluid mechanics theory and in consideration of turbulent coherent vortex as disturbance, the growth rate and the wave number response range of coherent vortex in meandering rivers with different curvatures were calculated in this paper. Moreover, the responses of different scales of coherent turbulence structure to river bend parameters were analyzed to explain the mechanism of fiver bend maintenance. These methods could provide a theoretical basis for further investigation on fiver meandering.展开更多
Ballistic thermal resistance of graphene nano-junctions is investigated using non-equifibrium molecular dynamics simulation. The simulation system is consisted of two symmetrical trapezoidal or rectangular graphene na...Ballistic thermal resistance of graphene nano-junctions is investigated using non-equifibrium molecular dynamics simulation. The simulation system is consisted of two symmetrical trapezoidal or rectangular graphene nano- ribbons (GNRs) and a connecting nanoscale constriction in between. Prom the simulated temperature profile, a big temperature jump resulted from the constriction is found, which is proportionM to the heat current and corresponds to a local ballistic thermal resistance. Fixing the constriction width and the length of GNRs, this ballistic thermal resistance is independent of the width of the GNRs bottom layer, i.e., the convex angle. But interestingly, this thermal resistance has obvious size effect. It is inversely proportional to the constriction width and will disappear with the constriction being wider. Moreover, based on the phonon dynamics theory, a theoretical model of the ballistic thermal resistance in two-dimensional nano-systems is developed, which gives a good explanation on microcosmic level and agrees well with the simulation result quantitatively and qualitatively.展开更多
文摘We derive a formula for double-pulse spectra from closed-orbit theory. We then calculate the double-pulse photodetachment spectra of H<SUP>?</SUP> in the presence of parallel electric and magnetic fields. We analyze the spectra in terms of closed-orbits of the system. We suggest a method for the measurement of a phase associated with each closed-orbit.
基金Project(U1934210) supported by the Key Project of High-speed Rail Joint Fund of National Natural Science Foundation of ChinaProject(8202037) supported by the Natural Science Foundation of Beijing,China。
文摘The influence of the interaction between surrounding rock and lining on the long-term behaviour of a tunnel in service is significant.In this paper,we proposed a mechanical model of the circular lined tunnel with the alterable mechanical property under hydrostatic stress and radially inner surface pressure of the lining.The alterable mechanical properties of the surrounding rock and the lining are embodied by the changing of their elasticity modulus with service time and radial direction of the tunnel,respectively.The proposed mechanical model is successfully validated by comparison with the existing theoretical models and the numerical simulation,respectively.The influences of the main parameters of the proposed mechanical model,such as the radial power-law indexes and the time-varying coefficients of the surrounding rock and the lining,as well as the radially inner surface pressure of the lining,on the interface displacement and pressure between surrounding rock and lining are investigated.The research results can provide some valuable references for timely diagnosis and correct evaluation of the long-term behaviours of a tunnel in service.
基金the Program for New Century Excellent Talents at Universities of China under Grant No.NCET-06-0554the National Natural Science Foundation of China under Grant No.60677001+3 种基金the Science-Technology Fund of Auhui Province for Outstanding Youth uniter Grant No.06042087the Key Fund of the Ministry of Education of China under Grant No.206063the Natural Science Foundation of Guangdong Province under Grant Nos.06300345 and 7007806Natural Science Foundation of Hubei Province under Grant No.2006AB354
文摘We propose a remote state preparation (RSP) scheme of three-particle Greenberger Horne-Zeilinger (GHZ) class states, where quantum channels are composed of two maximally entangled states. With the aid of forward classical bits, the preparation of the original state can be successfully realized with the probability 1/2, the necessary classical communication cost is 0.5 bit on average. If the state to be prepared belongs to some special states, the success probability of preparation can achieve 1 after consuming one extra bit on average. We then generalize this scheme to the case that the quantum channels consist of two non-maximally entangled states.
基金Supported by the National Natural Science Foundation of China under Grant No.50902110the National Aerospace Science Foundation of China under Grant No.2008ZF53058+3 种基金 the Specialized Research Foundation for Doctoral Program of Higher Education of China under Grant No.200806991032 the Doctorate Foundation of Northwestern Polytechnical University under Grant No.cx201005 the Northwestern Polytechnical University (NPU) Foundation for Fundamental Research under Grant No.NPU-FFR-W018108the 111 Project under Grant No.B08040
文摘In order to clarify the mechanism of optical transitions for cubic SrHfO_3, we have investigated the electronicstructure and optical properties of cubic SrHfO_3 using the plane-wave ultrasoft pseudopotential technique based on thefirst-principles density-functional theory (DFT).The ground-state properties, obtained by minimizing the total energy,are in favorable agreement with the previous work.From the band structure and charge densities as well as the theoryof crystal-field and molecular-orbital bonding, we have systematically studied how the optical transitions are affected bythe electronic structure and molecular orbitals.Our calculated complex dielectric function is in good agreement withthe experimental data and the optical transitions are in accord with the electronic structure.
基金The project supported by the Scientific Research Fund of the Education Bureau of Hunan Province under Grant No. 05B041, the Key Project of the Ministry of Education under Grant No. 206103, the China Postdoctoral Science Foundation under Grant No. 2005037695, National Natural Science Foundation of China under Grant Nos. 2001CB309310, 10325523, and 90203018, and the Natural Science Foundation of Hunan Province under Grant Nos. 04JJ3017 and 05JJ30012
文摘We propose a method to implement a kind of non-local operation between spatially separated two systems with high dimensions by using only a low-dimensional qubit quantum channel and 2-bit classical communication. For qutrit systems, we further show the creation of non-local maximally entangled state and the construction of the non-local quantum XOR gate in terms of the obtained non-local operations as well as some single qutrit local gates.
基金Supported by National Natural Science Foundation of China under Grant No. 10604045the University Science & Technology Planning Program of Shandong Province under Grant No. J09LA02the Discipline Construction Fund of Ludong University
文摘Using the photon closed orbit theory, the spontaneous emission rate of a polarized atom in a medium between two parallel mirrors is derived and calculated. It is found that the spontaneous emission rate of a polarized atom between the mirrors is related to the atomic position and the polarization direction. The results show that in the vicinity of the mirror, the variation of the spontaneous emission rate depends crucially on the atomic polarization direction. With the increase of the polarization angle, the oscillation in the spontaneous emission rate becomes decreased. For the polarization direction parallel to the mirror plane, the oscillation is the greatest; while for the perpendicular polarization direction, the oscillation is nearly vanished. The agreement between our result and the quantum electrodynamics result suggests the correctness of our calculation. This study further verifies that the atomic spontaneous emission process can be effectively controlled by changing the polarization orientation of the atom.
基金supported by National Natural Science Foundation of China under Grant No.10604045the Doctoral Scientific Research Startup Foundation of Ludong University under Grant No.202-23000301
文摘Using closed orbit theory, we give a clear physical picture description of the Rydberg hydrogen atom near a metal surface and calculate the Fourier transformed recurrence spectra of this system at different scaled energies below ionization threshold. The results show that with the increase of the scaled energy, the number of the closed orbit increases greatly. Some of the orbits are created by the bifurcation of the perpendicular orbit. This case is quite similar to the Rydberg atom in an electric field. When the scaled energy increases furthermore, chaotic orbits appear. This study provides a different perspective on the dynamical behavior of the Rydberg atom near a metal surface.
基金Projects(21072053,20772028)supported by the National Natural Science Foundation of ChinaProjects(10K025,11C0527)supported by the Scientific Research Fund of Hunan Provincial Education Department,ChinaProject(LKF0901)supported by the Open Foundation of Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education,Hunan University of Science and Technology,China
文摘2,4-diphenylpentane- and 2,4-di-p-tolylpentane-2,4-diols were investigated employing experimental and density functional theory (DFT) method at B3LYP/6-31G (d) level. The structure of syn-2,4-di-p-tolylpentane-2,4-diol (2b) was characterized by X-ray diffraction and compared with the crystal structures of anti- and syn-2,4-diphenylpentane-2,4-diols (la and lb). X-ray diffraction indicates that inter and intra-molecular hydrogen bonds are formed in the crystal structures. There is n-n staking interaction in lb and 2b. Good linear correlations and similar results are found between the experimental 1H and 13C NMR chemical shifts (6~exp) and GIAO (Gauge Independent Atomic Orbital) method calculated magnetic isotropic shielding tensors (acalc). HOMO and LUMO molecular orbitals were calculated at the same levels with the different results. UV-vis absorption spectra of the compounds were recorded in EtOH, MeCN, n-BuOH and cyclohexane with different dielectric constants. It is found that the solvent effect is obvious when e is 24.85(EtOH), 35.69(MeCN) and it is weak when e is decreased to 17.33(n-BuOH), 1.18 (cyclohexane).
基金supported by the National Natural Science Foundation of China(Grant No.40704032)
文摘Based on the magnetospheric kinetic theory, a model is developed to specify the flux of energetic electrons in the inner and middle magnetosphere. Under the assumption of adiabatic motion and isotropic particle distribution maintained by pitch-angle scattering, the model calculates the electron flux by following bounce-averaged electric field, gradient, and curvature drift in the time dependent electric and magnetic field, meanwhile it counts the electron loss caused by pitch angle scattering. Using the model, the clectron flux distribution during a magnetic storm was calculated and compared with the observation data from the geosynchronous orbit. It is shown that the model can successfully reproduce most of the major electron flux enhancements observed at the geosynchronous orbit and generally tracks the satellite data well. The rms errors of the modeled logarithm of flux are between 0.5-1.0.
基金This work was supported by Knowledge Innovation Program of the Chi-nese Academy of Sciences (Grant No.KZCX2-YW-134)National Nat-ural Science Foundation of China (Grant No.41030320)
文摘The Tibetan Plateau is a large-scale tectonic geomorphologic unit formed by the interactions of plates.It has been commonly believed that convective removal of the thickened Tibetan lithosphere,or lateral flow of the lower crust beneath the Tibetan plateau plays a crucial role in the formation of the large-scale tectonic geomorphologic features.Recent geological and geo-physical observations have provided important evidence in support of the lower crustal channel flow model.However,it re-mains unclear as how the geometry of lower crustal channel and the lateral variation of crustal rheology within the lower crust channel may have affected spatio-temporal evolution of the tectonic geomorphologic unit of the Tibetan Plateau.Here,we use numerical methods to explore the mechanical relations between the lower crustal channel flow and the tectonic geomorpho-logic formation around the eastern Tibetan plateau,by deriving a series of governing equations from fluid mechanics theory.From numerous tests,our results show that the viscosity of the channeled lower crust is about(1-5)×1018 to(1-4)×1020 Pa s(Pa.s) beneath the margin of the eastern Tibetan Plateau,and increases to about 1022 Pa s beneath the Sichuan Basin and the southern region of Yunnan Province.Numerical tests also indicate that if channel flows of the lower crust exist,the horizontal propagation and the vertical uplifting rate of the eastern Tibetan Plateau margin could be accelerated with the time.Thus,the present results could be useful to constrain the rheological structure of the crust beneath the eastern Tibetan plateau,and to understand the possible mechanics of rapid uplift of the eastern Tibetan Plateau margin,especially since its occurrence at 8Ma as revealed by numerous geological observations.
基金supported by the National Natural Science Foundation for Innovative Research Groups of China (Grant No.51021004)the National Natural Science Foundation of China (Grant Nos.50979066,50809045)
文摘In a meandering fiver, a certain scale of turbulent vortex dominates the development of fiver morphology, making the river bend with s particular curvature. This kind of vortex is denoted as "bend-forming vortex". The coordinated relationship of bend-forming vortex and meandering fiver channel is then known as "self-adaption feature" of rivers. With these two concepts, this paper investigated the stability and self-adaption character of coherent vortex in the U-shape river bend with a constant curvature. On the basis of fluid mechanics theory and in consideration of turbulent coherent vortex as disturbance, the growth rate and the wave number response range of coherent vortex in meandering rivers with different curvatures were calculated in this paper. Moreover, the responses of different scales of coherent turbulence structure to river bend parameters were analyzed to explain the mechanism of fiver bend maintenance. These methods could provide a theoretical basis for further investigation on fiver meandering.
基金Supported by the National Natural Science Foundation of China under Grant Nos.51322603,51136001,51356001Science Fund for Creative Research Groups(No.51321002)+1 种基金the Program for New Century Excellent Talents in University,Tsinghua University Initiative Scientific Research Programthe Tsinghua National Laboratory for Information Science and Technology of China
文摘Ballistic thermal resistance of graphene nano-junctions is investigated using non-equifibrium molecular dynamics simulation. The simulation system is consisted of two symmetrical trapezoidal or rectangular graphene nano- ribbons (GNRs) and a connecting nanoscale constriction in between. Prom the simulated temperature profile, a big temperature jump resulted from the constriction is found, which is proportionM to the heat current and corresponds to a local ballistic thermal resistance. Fixing the constriction width and the length of GNRs, this ballistic thermal resistance is independent of the width of the GNRs bottom layer, i.e., the convex angle. But interestingly, this thermal resistance has obvious size effect. It is inversely proportional to the constriction width and will disappear with the constriction being wider. Moreover, based on the phonon dynamics theory, a theoretical model of the ballistic thermal resistance in two-dimensional nano-systems is developed, which gives a good explanation on microcosmic level and agrees well with the simulation result quantitatively and qualitatively.