Redox behavior and chemical species of arsenic in acidic aqueous system

Arsenic(As)removal from smelting acidic wastewater is an urgent task.The most common method is oxidation of trivalent As(III)to pentavalent As(V)subsequently precipitated by ferric(Fe(III))salts.Foundations of redox behavior and chemical species are of great importance for understanding As removal.In this work,cyclic voltammetry(CV)and UV?Vis spectroscopy were used for laboratory observation;meanwhile HSC and MINTEQ software were employed for theoretical analyses.It is found that As(III)oxidation,a multiple electron transfer reaction,is diffusion-controlled.The oxidation over-potential is very high(about0.9V)in sulfuric acid solutions(pH1.0).In addition,Fe(III)?As(V)complexes are evidenced by UV?Vis spectra and chemical species analyses in series of Fe(III)?As(V)?H2SO4?H2O solutions.Therefore,the Fe(III)and As(V)species distribution against pH values are determined and a newφ?pH diagram with inclusion of Fe?As complexes is consequently compiled based on thermodynamic data predicted by other researchers.

Medical Image Registration Based on Phase Congruency and Regional Mutual Information

In this paper, a new approach of muhi-modality image registration is represented with not only image intensity, but also features describing image structure. There are two novelties in the proposed method. Firstly, instead of standard mutual information （ MI ） based on joint intensity histogram, regional mutual information （ RMI ） is employed, which allows neighborhood information to be taken into account. Secondly, a new feature images obtained by means of phase congruency are invariants to brightness or contrast changes. By incorporating these features and intensity into RMI, we can combine the aspects of both structural and neighborhood information together, which offers a more robust and a high level of registration accuracy.

Offline handover location positioning for map matching of mobile probes

Handover location technology was employed for collecting road traffic information in a number of field projects, and the project results demonstrate that it is a supplementary and promising means of road traffic information collection for further traffic supervision and maintenance. Because handover location technology is one kind of pattern matching based location technologies, offiine handovex location positioning is an essential problem to be studied for successfully matching mobile probes on GIS map. Offline handover location positioning method involves two stages, handover location positioning respectively via two weighted models and an optimized model based on the intermediate results obtained in the first stage. A preliminary field test is conducted on a stretch of freeway in the inner suburban region in Beijing, and performance evaluation results show that the proposed method is superior to standard least square model in location accuracy and location precision, which is an effective method of offline handover location positioning.