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配体对CdTe量子点与BSA的选择性相互作用的影响 被引量:3
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作者 王珊珊 王雪婷 +1 位作者 郭明明 于俊生 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2012年第6期1195-1204,共10页
以巯基乙酸(TGA)、巯基丙酸(MPA)、巯基甘油(TG)、L-半胱氨酸(L-cys)和谷胱甘肽(GSH)等5种巯基分子为稳定剂,水相合成了5种CdTe量子点.以牛血清白蛋白(BSA)作为靶分子,通过吸收光谱、荧光光谱和时间分辨荧光动力学等手段研究了各种配体... 以巯基乙酸(TGA)、巯基丙酸(MPA)、巯基甘油(TG)、L-半胱氨酸(L-cys)和谷胱甘肽(GSH)等5种巯基分子为稳定剂,水相合成了5种CdTe量子点.以牛血清白蛋白(BSA)作为靶分子,通过吸收光谱、荧光光谱和时间分辨荧光动力学等手段研究了各种配体分子稳定的CdTe量子点与BSA的直接相互作用.结果表明,5种量子点均能有效猝灭BSA的荧光,其猝灭程度按配体次序为GSH>L-cys>TGA>TG>MPA;而BSA对不同配体稳定的CdTe量子点的荧光光谱的影响则具有明显的选择性.BSA对TGA-CdTe和MPA-CdTe量子点的荧光先敏化增强而后猝灭下降;L-cys分子由于同时具有氨基和羧基而与BSA的相互作用较强,因此BSA能显著猝灭L-cys-CdTe量子点的荧光;而BSA对TG-CdTe量子点的荧光猝灭程度较小;GSH分子的空间效应使GSH-CdTe量子点的荧光被BSA猝灭的程度最小.吸收光谱和时间分辨荧光动力学研究表明,5种量子点与BSA之间的相互作用均为静态过程.探讨了量子点的配体分子结构与蛋白质的相互作用机理. 展开更多
关键词 CDTE量子点 配体影响 牛血清白蛋白 选择性相互作用 光致发光
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Evaluation of the individual allocation scheme and its impacts in a dynamic global vegetation model 被引量:1
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作者 SONG Xiang ZENG Xiao-Dong LI Fang 《Atmospheric and Oceanic Science Letters》 CSCD 2016年第1期38-44,共7页
The strategies of plant growth play an important role not only in ecosystem structure,but also in global carbon and water cycles.In this work,the individual carbon allocation scheme of tree PFTs and its impacts were e... The strategies of plant growth play an important role not only in ecosystem structure,but also in global carbon and water cycles.In this work,the individual carbon allocation scheme of tree PFTs and its impacts were evaluated in China with Institute of Atmospheric Physics-Dynamic Global Vegetation Model,version 1.0(IAP-DGVM1.0)as a test-bed.The results showed that,as individual growth,the current scheme tended to allocate an increasing proportion of annual net primary productivity(NPP)to sapwood and decreasing proportions to leaf and root accordingly,which led to underestimated individual leaf biomass and overestimated individual stem biomass.Such biases resulted in an overestimation of total ecosystem biomass and recovery time of mature forests,and an underestimation of ecosystem NPP and tree leaf area index in China. 展开更多
关键词 IAP-DGVM 1.0 individual allocation scheme BIOMASS carbon residence time China
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