期刊文献+
共找到19篇文章
< 1 >
每页显示 20 50 100
Zn(Ⅱ)-NH3-Cl^--CO3^2-H2O体系中Zn(Ⅱ)配合平衡 被引量:6
1
作者 王瑞祥 唐谟堂 +4 位作者 杨建广 杨声海 张文海 唐朝波 何静 《中国有色金属学报》 EI CAS CSCD 北大核心 2008年第E01期192-198,共7页
用双平衡法研究Zn(Ⅱ)-NH3-Cl^--CO3^2-H2O体系中Zn(Ⅱ)配合平衡热力学,求出氨水浓度和氯离子浓度在0~10mol/L范围内变化时,体系中各物种的平衡浓度,绘制热力学平衡图,并对热力学计算结果进行实验验证和差异分析。结果表明:... 用双平衡法研究Zn(Ⅱ)-NH3-Cl^--CO3^2-H2O体系中Zn(Ⅱ)配合平衡热力学,求出氨水浓度和氯离子浓度在0~10mol/L范围内变化时,体系中各物种的平衡浓度,绘制热力学平衡图,并对热力学计算结果进行实验验证和差异分析。结果表明:锌离子浓度理论计算值与实验值之间的平均相对误差为7.47%,这说明该热力学模型是正确的,所选数据的准确性较好。 展开更多
关键词 热力学 Zn(Ⅱ)配合平衡 平衡
下载PDF
Ni(Ⅱ)-NH_3-Cl^--H_2O体系中Ni(Ⅱ)配合平衡热力学 被引量:6
2
作者 王瑞祥 唐谟堂 +5 位作者 巨少华 杨声海 张文海 唐朝波 何静 杨建广 《中南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2008年第5期891-896,共6页
根据质量平衡和电荷平衡的双平衡法,研究Ni(Ⅱ)-NH3-Cl--H2O体系中Ni(Ⅱ)配合平衡热力学;求出氨水浓度和氯离子浓度在0~5 mol/L范围内变化时,体系的pH值、体系中总镍、游离氯离子、游离氨以及各种镍-氨配合物等的平衡浓度,绘制热力学... 根据质量平衡和电荷平衡的双平衡法,研究Ni(Ⅱ)-NH3-Cl--H2O体系中Ni(Ⅱ)配合平衡热力学;求出氨水浓度和氯离子浓度在0~5 mol/L范围内变化时,体系的pH值、体系中总镍、游离氯离子、游离氨以及各种镍-氨配合物等的平衡浓度,绘制热力学平衡图,并对热力学计算结果进行试验验证和差异分析。研究结果表明:镍离子浓度理论计算值与试验值之间的相对误差绝对平均值为6.91%,这说明该热力学模型是正确的,所选数据的准确性较好。 展开更多
关键词 NH3-CI^--H2O体系 Ni(Ⅱ)配合平衡 平衡
下载PDF
配合平衡离子分布的尝试迭代法求解 被引量:2
3
作者 王清成 何文猛 尹光福 《四川大学学报(自然科学版)》 CAS CSCD 北大核心 2000年第6期906-910,共5页
用经典迭代法求解配位体不过量的配合平衡系统的离子分布十分困难 ,而用作者提出的尝试迭代法却能顺利求解 .尝试迭代法的作法是 :从千千万万组离子浓度的取值中 ,用尝试法筛选出若干组满足尝试公式的离子浓度 。
关键词 尝试迭代法 配合平衡 离子分布 配位体不过量 求解 离子浓度 配位效应
下载PDF
Mg(Ⅱ)-NH_3-NH_4Cl-H_2O体系中Mg(Ⅱ)配合平衡热力学 被引量:3
4
作者 王瑞祥 唐谟堂 曾婕 《中国有色冶金》 北大核心 2010年第1期69-73,共5页
用双平衡法研究了Mg(Ⅱ)-NH_3-NH_4Cl-H_2O体系中Mg(Ⅱ)配合平衡热力学,得出氨水浓度和氯化铵浓度在0~5 mol/L范围内变化时体系中各物种的平衡浓度,绘制了热力学平衡图,揭示了镁在该体系中的溶解规律。该体系存在着镁的高溶解度区域,... 用双平衡法研究了Mg(Ⅱ)-NH_3-NH_4Cl-H_2O体系中Mg(Ⅱ)配合平衡热力学,得出氨水浓度和氯化铵浓度在0~5 mol/L范围内变化时体系中各物种的平衡浓度,绘制了热力学平衡图,揭示了镁在该体系中的溶解规律。该体系存在着镁的高溶解度区域,镁的溶解度随着氯化铵浓度增加而增加,最高可达1.07mol/L;而在纯氨水中,镁离子浓度不随氨水浓度变化,始终接近0;向体系中添加氯化铵并保持其浓度不变,镁离子浓度随着氨水浓度的升高先略有降低而后逐渐升高,呈现一个浅碟型,在氨水浓度为2.5mol/L附近出现最低点。 展开更多
关键词 NH3-NH4Cl-H2O体系 热力学 Mg(Ⅱ)配合平衡 平衡
下载PDF
Cd(Ⅱ)-NH_3-Cl^--H_2O体系配合平衡 被引量:1
5
作者 王瑞祥 武岩鹏 唐谟堂 《有色金属(冶炼部分)》 CAS 北大核心 2010年第4期2-5,共4页
用双平衡法,研究了Cd(Ⅱ)-NH3-Cl--H2O体系中Cd(Ⅱ)配合平衡热力学,求出了氨水浓度和氯离子浓度在0~5 mol/L变化时,体系中各物种的平衡浓度,绘制了热力学平衡图,并对热力学计算结果进行了试验验证和差异分析。结果表明:镉离子浓度理论... 用双平衡法,研究了Cd(Ⅱ)-NH3-Cl--H2O体系中Cd(Ⅱ)配合平衡热力学,求出了氨水浓度和氯离子浓度在0~5 mol/L变化时,体系中各物种的平衡浓度,绘制了热力学平衡图,并对热力学计算结果进行了试验验证和差异分析。结果表明:镉离子浓度理论计算值与试验值之间的绝对平均误差为12.04%,说明该热力学模型是正确的,所选数据的准确性较好。 展开更多
关键词 热力学 镉(Ⅱ)配合平衡 平衡
下载PDF
Cd(Ⅱ)与某些α-氨基酸在溶液中的配合平衡研究
6
作者 蒋毅民 陈小兰 《广西师范大学学报(自然科学版)》 CAS 1992年第2期40-43,共4页
采用离子选择电极法研究了Cd(Ⅱ)与5种α-氨基酸在溶液中的配合平衡,测定了Cd(Ⅱ):α-氨基酸为1:1和1:2配合物的稳定常数。
关键词 Α-氨基酸 溶液 配合平衡
下载PDF
试探法求解配合平衡
7
作者 李可群 《高等函授学报(自然科学版)》 2009年第4期30-32,共3页
针对配合物溶液配体起始浓度大于或小于等于金属离子起始浓度两种情形,分别提出两种精确求解配合平衡的简便试探方法,它们不存在一般迭代法的"迭代振荡"现象,一般仅需试探几次即可得到满意结果。
关键词 配合平衡 精确求解 试探法
下载PDF
配合离解平衡问题的研究
8
作者 胡昊 《安徽水利水电职业技术学院学报》 2008年第1期70-71,共2页
文章介绍了化学反应中的配合离解平衡与沉淀溶解和氧化还原平衡的关系及其应用。
关键词 配合离解平衡 沉淀溶解平衡 氧化还原平衡
下载PDF
四大化学平衡统一计算公式在数学中的应用 被引量:3
9
作者 贺克强 徐瑛 《设计艺术研究》 1997年第2期71-72,83,共3页
运用酸碱质子理论的共轭概念,常见化学反应中,酸碱平衡、氧化还原平衡、配合平衡,沉淀-溶解平衡可用一个统一公式计算平衡常数。
关键词 四大化学 平衡统一 计算公式 氧化还原平衡 平衡常数 配合平衡 酸碱质子理论 负离子 溶解平衡 四大平衡
下载PDF
Co(Ⅱ)在NH_3-NH_4Cl-H_2O体系中的平衡规律 被引量:3
10
作者 廖元杭 《有色金属(冶炼部分)》 CAS 北大核心 2012年第11期1-4,9,共5页
利用双平衡法,研究了Co(Ⅱ)-NH3-Cl--H2O体系中Co?的溶解规律,通过计算绘制了热力学平衡图,揭示了体系中各物质的平衡浓度与氨水浓度和氯离子浓度之间的关系。结果表明,在该体系中唯一存在的固相物质为Co(OH)2(S),试验验证了热力学计算... 利用双平衡法,研究了Co(Ⅱ)-NH3-Cl--H2O体系中Co?的溶解规律,通过计算绘制了热力学平衡图,揭示了体系中各物质的平衡浓度与氨水浓度和氯离子浓度之间的关系。结果表明,在该体系中唯一存在的固相物质为Co(OH)2(S),试验验证了热力学计算结果,两者之间的偏差仅为10.13%。 展开更多
关键词 热力学 钴(Ⅱ) 配合平衡 平衡
下载PDF
一种掺再生剂和RAP的沥青混合料配合比设计新方法 被引量:4
11
作者 冯新军 张喆 +3 位作者 赵梦龙 Soohyok Im Pravat Karki Fujie Zhou 《中外公路》 北大核心 2018年第2期242-247,共6页
由于回收沥青路面材料(RAP)和回收沥青油毡瓦(RAS)等具有环保、节能、省税等优点,现已广泛应用于沥青路面工程中,并且发展规模日益壮大。然而这些回收材料已经高度老化,应用在实际工程中将会对沥青混合料的耐久性带来潜在的危害。再生... 由于回收沥青路面材料(RAP)和回收沥青油毡瓦(RAS)等具有环保、节能、省税等优点,现已广泛应用于沥青路面工程中,并且发展规模日益壮大。然而这些回收材料已经高度老化,应用在实际工程中将会对沥青混合料的耐久性带来潜在的危害。再生剂能改善高含量RAP混合料的工程性质,因此受到道路界的广泛关注。该文提出了一种掺再生剂和RAP的沥青混合料配合比设计新方法,并且已经铺筑了试验路段。研究人员首先通过一系列的室内试验逐步选定沥青用量和再生剂掺量范围,然后采用沥青混合料配合比平衡设计法确定最佳沥青用量和最佳再生剂用量。试验结果表明:再生剂的掺量是平衡再生沥青混合料抗车辙性能和抗开裂性能的关键因素。 展开更多
关键词 再生剂 沥青混合料 平衡配合比设计法 再生沥青路面
下载PDF
Functional Equilibrium Between Photosynthetic and Above-ground Nonphotosynthetic Structures of Plants: Evidence from a Pruning Experiment with Three Subtropical Tree Species 被引量:4
12
作者 曾波 《Acta Botanica Sinica》 CSCD 2003年第2期152-157,共6页
It is well known that plants have functional equilibrium between their above-ground parts (shoots) and below-ground parts (roots), but whether the above-ground parts of plants have functional equilibrium between their... It is well known that plants have functional equilibrium between their above-ground parts (shoots) and below-ground parts (roots), but whether the above-ground parts of plants have functional equilibrium between their photosynthetic structures (leaves) and non-photosynthetic structures (branches and stem) is unknown. The purpose of this study is to test the hypotheses that: (1) the above-ground parts of plants have functional equilibriums between their photosynthetic structures and non-photosynthetic structures; (2) the maintenance of the equilibriums is guaranteed by the alteration of biomass partitioning to photosynthetic and non-photosynthetic structures. To test these hypotheses, a pruning experiment with four pruning intensities (0%, 20%, 50%, and 70%) were carried out with three subtropical Chinese tree species ( Ficus microcarpa, Ficus virens, Cinnamomum camphora). Pruning treatments were conducted in two successive years. The results were in conformity with the hypothesis, i.e. above-ground parts of trees had functional equilibriums between photosynthetic and non-photosynthetic structures. Pruning decreased instantaneously the mass ratios of photosynthetic structures to non-photosynthetic structures (P/NP) of all three tree species, the reduction in P/NP was strengthened with pruning intensity. However, one year after pruning, the P/NP of all pruned trees increased and were not smaller than those of unpruned trees. In agreement with the expectation, the biomass partitioning of pruned trees was altered, more newly produced above-ground biomass was partitioned to leaf growth and less to branch and stem growth, thus enabled the damaged trees to restore their functional equilibrium between photosynthetic and non-photosynthetic structures. It is clear that the maintenance of functional equilibrium between photosynthetic and non-photosynthetic structures guaranteed by the alteration of biomass partitioning provides plants a good strategy to resist external disturbance and damage. 展开更多
关键词 biomass partitioning functional equilibrium non-photosynthetic structures photosynthetic structures tree
下载PDF
Elimination Mechanism and Equilibrium Model about Complete Linkage of Panmixis Based on Fitness 被引量:2
13
作者 覃俊达 陈奇 李大林 《Agricultural Science & Technology》 CAS 2011年第6期801-804,共4页
[Objective]The aim was to discuss elimination mechanism and equilibrium model about complete linkage gene of panmixis based on fitness.[Method]A mathematical model that gsgenerational evalution of frequency of panmixi... [Objective]The aim was to discuss elimination mechanism and equilibrium model about complete linkage gene of panmixis based on fitness.[Method]A mathematical model that gsgenerational evalution of frequency of panmixis two pairs of complete linkage gene under difference fitness was built by using difference equations to study elimination mechanism and genetic equilibrium state of panncticcoinplete linkage gene.[Result]The panmixis is different from Hardy-Weinberg Equilibrium which reached the equilibrium just by one generation.A method that by using linear equation to calculate the frequency of four gametes and the fitnessed of panmixis was established after detormining is the fitness of 10 genotypes the necessary and sufficient condition of the panmixis to reach balance.[Conclusion]The method is valuable for reference on linkage disequilibrium and hitchhiking effect study. 展开更多
关键词 Random match Complete linkage Gene frequency FITNESS EQUILIBRIUM
下载PDF
Alloy gene Gibbs energy partition function and equilibrium holographic network phase diagrams of Au_3Cu-type sublattice system 被引量:3
14
作者 谢佑卿 聂耀庄 +2 位作者 李小波 彭红建 刘心笔 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第1期211-240,共30页
Taking Au3Cu-type sublattice system as an example, three discoveries have been presented. First, the fourth barrier to hinder the progress of metal materials science is that today’s researchers do not understand that... Taking Au3Cu-type sublattice system as an example, three discoveries have been presented. First, the fourth barrier to hinder the progress of metal materials science is that today’s researchers do not understand that the Gibbs energy function of an alloy phase should be derived from Gibbs energy partition function constructed of alloy gene sequence and their Gibbs energy sequence. Second, the six rules for establishing alloy gene Gibbs energy partition function have been discovered, and it has been specially proved that the probabilities of structure units occupied at the Gibbs energy levels in the degeneracy factor for calculating configuration entropy should be degenerated as ones of component atoms occupied at the lattice points. Third, the main characteristics unexpected by today’s researchers are as follows. There exists a single-phase boundary curve without two-phase region coexisting by the ordered and disordered phases. The composition and temperature of the top point on the phase-boundary curve are far away from those of the critical point of the Au3Cu compound; At 0 K, the composition of the lowest point on the composition-dependent Gibbs energy curve is notably deviated from that of the Au3Cu compounds. The theoretical limit composition range of long range ordered Au3Cu-type alloys is determined by the first jumping order degree. 展开更多
关键词 Au3Cu compound Au3Cu-type sublattice system alloy gene Gibbs energy partition function equilibrium holographic network phase diagrams systematic metal materials science
下载PDF
Alloy gene Gibbs energy partition function and equilibrium holographic network phase diagrams of AuCu_3-type sublattice system 被引量:3
15
作者 谢佑卿 李小波 +2 位作者 刘心笔 聂耀庄 彭红建 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第11期3585-3610,共26页
Taking AuCu3-type sublattice system as an example, three discoveries have been presented: First, the third barrier hindering the progress in metal materials science is that researchers have got used to recognizing exp... Taking AuCu3-type sublattice system as an example, three discoveries have been presented: First, the third barrier hindering the progress in metal materials science is that researchers have got used to recognizing experimental phenomena of alloy phase transitions during extremely slow variation in temperature by equilibrium thinking mode and then taking erroneous knowledge of experimental phenomena as selected information for establishing Gibbs energy function and so-called equilibrium phase diagram. Second, the equilibrium holographic network phase diagrams of AuCu3-type sublattice system may be used to describe systematic correlativity of the composition?temperature-dependent alloy gene arranging structures and complete thermodynamic properties, and to be a standard for studying experimental subequilibrium order-disorder transition. Third, the equilibrium transition of each alloy is a homogeneous single-phase rather than a heterogeneous two-phase, and there exists a single-phase boundary curve without two-phase region of the ordered and disordered phases; the composition and temperature of the top point on the phase-boundary curve are far away from the ones of the critical point of the AuCu3 compound. 展开更多
关键词 AuCu3 compound AuCu3-type sublattice system alloy gene Gibbs energy partition function equilibrium holographic network phase diagram systematic metal materials science
下载PDF
徐工新一代高空作业平台GTBZ24A下线
16
《工程机械与维修》 2018年第1期8-8,共1页
近日,徐工消防全新研发的新一代曲臂式高空作业平台GTBZ24A完成调试下线。作为徐工新一代高空作业平台技术与产品的“领军人物”,GTBZ24A全新采用四轮四驱配合平衡车桥技术,而内外轮独立驱动的应用,能够自动控制轮胎转速,让您行进... 近日,徐工消防全新研发的新一代曲臂式高空作业平台GTBZ24A完成调试下线。作为徐工新一代高空作业平台技术与产品的“领军人物”,GTBZ24A全新采用四轮四驱配合平衡车桥技术,而内外轮独立驱动的应用,能够自动控制轮胎转速,让您行进转向也能舒适操作,强大的越野能力让车辆在复杂地形自如行进,爬坡度同行业领先。作为新一代技术研发平台的硕果,GTBZ24A采用定制化阔控系统,能够实现各动作精准控制,极大提升产品操作的动作平顺性, 展开更多
关键词 高空作业平台 下线 平台技术 自动控制 研发平台 配合平衡 独立驱动 复杂地形
下载PDF
A Study on Stoichiometry of Complexes of Tributyl Phosphate and Methyl Isobutyl Ketone with Lithium in the Presence of FeCl_3 被引量:4
17
作者 周智勇 秦炜 +1 位作者 费维扬 李以圭 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2012年第1期36-39,共4页
To study the characteristic of liquid-liquid extraction equilibrium of lithium from brine sources, the complexes formed from tributyl phosphate (TBP) and methyl isobutyl ketone (MIBK) with lithium were investi- ga... To study the characteristic of liquid-liquid extraction equilibrium of lithium from brine sources, the complexes formed from tributyl phosphate (TBP) and methyl isobutyl ketone (MIBK) with lithium were investi- gated using FeCl3 as coextracting agent. Liquid-liquid extraction reaction mechanisms were proposed and the stoichiometry of tetrachloroferrate(III) complex with lithium was obtained by regressing the experimental data. It is found that the stoichiometry of tetrachloroferrate(III) to lithium in the complex is 1 : 1 with either TBP or MIBK as extractant in kerosene. The stoichiometry of the complex of TBP with Li was 1 : 1 and that of MIBK with Li was 2 : 1. The formed complexes of TBP and MIBK with lithium are determined to be LiFeCla-TBP and LiFeC14.2MIBK, respectively, according to the rule of neutralization. 展开更多
关键词 LITHIUM extraction reaction equations formation tributyl phosphate methyl isobutyl ketone KEROSENE
下载PDF
Quantum-Chemical Interpretation of the Spectroscopy of Highly Luminescent 1,3,5-Triazapentadiene Complexes of Platinum(Ⅱ)
18
作者 Maslov Vladimir G. G.N. Lyalin 《Journal of Chemistry and Chemical Engineering》 2012年第12期1142-1149,共8页
The quantum-chemical calculations were performed to determine the nature of the equilibrium geometry of the ground and excited states of the 1,3,5-triazapentadiene complexes of platinum(Ⅱ) and theirs nature and str... The quantum-chemical calculations were performed to determine the nature of the equilibrium geometry of the ground and excited states of the 1,3,5-triazapentadiene complexes of platinum(Ⅱ) and theirs nature and structure of molecular orbitals. 展开更多
关键词 Complexes of platinum(II) quantum-chemical calculations equilibrium geometries excitation energies oscillatorstrengths.
下载PDF
Zn(Ⅱ)-Ag(Ⅰ)-组氨酸-H_2O系配位平衡研究 被引量:2
19
作者 方福荣 张祥麟 郭学益 《化学通报》 CAS CSCD 北大核心 1997年第12期40-43,共4页
Zn(Ⅱ)┐Ag(Ⅰ)┐组氨酸┐H2O系配位平衡研究方福荣张祥麟郭学益(深圳蛇口商检局518067)(中南工业大学化学系长沙410083)(中南工业大学冶金系长沙410083)金属离子在水溶液中一般都不能以简单离子独... Zn(Ⅱ)┐Ag(Ⅰ)┐组氨酸┐H2O系配位平衡研究方福荣张祥麟郭学益(深圳蛇口商检局518067)(中南工业大学化学系长沙410083)(中南工业大学冶金系长沙410083)金属离子在水溶液中一般都不能以简单离子独立存在,而是与其它分子或离子(如H... 展开更多
关键词 锌离子 银离子 组氨酸 配位平衡 配合平衡
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部