Density functional theory calculations were carried out to investigate the influence of doping transition metal(TM) ions into the ceria surface on the activation of surface lattice oxygen atoms. For this purpose, the ...Density functional theory calculations were carried out to investigate the influence of doping transition metal(TM) ions into the ceria surface on the activation of surface lattice oxygen atoms. For this purpose, the structure and stability of the most stable(111) surface termination of CeO2 modified by TM ions was determined. Except for Zr and Pt dopants that preserve octahedral oxygen coordination, the TM dopants prefer a square-planar coordination when substituting the surface Ce ions. The surface construction from octahedral to square-planar is facile for all TM dopants, except for Pt(1.14 e V) and Zr(square-planar coordination unstable). Typically, the ionic radius of tetravalent TM cations is much smaller than that of Ce4+, resulting a significant tensile-strained lattice and explaining the lowered oxygen vacancy formation energy. Except for Zr, the square-planar structure is the preferred one when one oxygen vacancy is created. Thermodynamic analysis shows that TM-doped CeO2 surfaces contain oxygen defects under typical conditions of environmental catalysis. A case of practical importance is the facile lattice oxygen activation in Zr-doped CeO2(111), which benefits CO oxidation. The findings emphasize the origin of lattice oxygen activation and the preferred location of TM dopants in TM-ceria solid solution catalysts.展开更多
Multi-converter approach based on the series and parallel connection topology of modular power converters has been proposed to realize higher power density DC-DC converter. The availability of the proposed approach ha...Multi-converter approach based on the series and parallel connection topology of modular power converters has been proposed to realize higher power density DC-DC converter. The availability of the proposed approach has been verified through the design consideration and the experiment. The design consideration for two DC-DC converters has been carried out by utilizing the power converter exact loss simulator, and the design parameters to maximize their power densities have been extracted taking the trade-off between the conversion efficiency and the power density into account. The prototypes of a 2,400 W, 256-384 V boost chopper using SiC-MOSFETs and a 300 W, 32-48 V GaN-FETs boost chopper have been also developed based on the design. The SiC chopper achieved the efficiency of 97.8% and the power density of 12,8 W/cm3, and the GaN chopper accomplished 98.9% and 18.6 W/cm3 in the experiment. These results show the validity of the design and the availability of the proposed approach. The multi-converter approach enables the cost reduction of the modular power converters, and contributes to realizing the widespread use of power electronics converters in the future 380 V DC distribution system.展开更多
基金supported by The Netherlands Organization for Scientific Research(NWO)through a Vici grant and Nuffic fundingfunding from the European Union’s Horizon 2020 research and innovation programme under grant No.686086(Partial-PGMs)。
文摘Density functional theory calculations were carried out to investigate the influence of doping transition metal(TM) ions into the ceria surface on the activation of surface lattice oxygen atoms. For this purpose, the structure and stability of the most stable(111) surface termination of CeO2 modified by TM ions was determined. Except for Zr and Pt dopants that preserve octahedral oxygen coordination, the TM dopants prefer a square-planar coordination when substituting the surface Ce ions. The surface construction from octahedral to square-planar is facile for all TM dopants, except for Pt(1.14 e V) and Zr(square-planar coordination unstable). Typically, the ionic radius of tetravalent TM cations is much smaller than that of Ce4+, resulting a significant tensile-strained lattice and explaining the lowered oxygen vacancy formation energy. Except for Zr, the square-planar structure is the preferred one when one oxygen vacancy is created. Thermodynamic analysis shows that TM-doped CeO2 surfaces contain oxygen defects under typical conditions of environmental catalysis. A case of practical importance is the facile lattice oxygen activation in Zr-doped CeO2(111), which benefits CO oxidation. The findings emphasize the origin of lattice oxygen activation and the preferred location of TM dopants in TM-ceria solid solution catalysts.
文摘Multi-converter approach based on the series and parallel connection topology of modular power converters has been proposed to realize higher power density DC-DC converter. The availability of the proposed approach has been verified through the design consideration and the experiment. The design consideration for two DC-DC converters has been carried out by utilizing the power converter exact loss simulator, and the design parameters to maximize their power densities have been extracted taking the trade-off between the conversion efficiency and the power density into account. The prototypes of a 2,400 W, 256-384 V boost chopper using SiC-MOSFETs and a 300 W, 32-48 V GaN-FETs boost chopper have been also developed based on the design. The SiC chopper achieved the efficiency of 97.8% and the power density of 12,8 W/cm3, and the GaN chopper accomplished 98.9% and 18.6 W/cm3 in the experiment. These results show the validity of the design and the availability of the proposed approach. The multi-converter approach enables the cost reduction of the modular power converters, and contributes to realizing the widespread use of power electronics converters in the future 380 V DC distribution system.
