The coal with low moisture during carbonization could not only increase the yield of coke,but also promote the coke quality and reduce the energy consumption.In this paper,the influence of the moisture in the blend co...The coal with low moisture during carbonization could not only increase the yield of coke,but also promote the coke quality and reduce the energy consumption.In this paper,the influence of the moisture in the blend coal(1.8%10.13%)on the product yields and coke quality during coal carbonization were investigated.The results show that the coke yield is increased from 75.90%to 77.16%,and the coke qualities such as coke strength after reaction with CO2(CSR),coke reactivity index(CRI),fragmentation index(M25)and abrasion index(M10))are also improved when the moisture of the blend coal decreases from 10.13%to 1.80%in a bench scale reactor.Due to the secondary reaction,tar become lighter when the moisture is decreased.In order to further prove the above results,the blend coal with 1.8%and 9%10%(common moisture used in coke plant)moisture is carbonized in a coke oven with 6 m height,the results show that CRI are 23.4%and 27.3%,CRS are 67.1%and 62.2%under 1.8%and 9%10%moisture of blend coal.Moreover,the variation of the moisture in blend coal has a limited influence on dust emission at the ascension pipe and the charging car.展开更多
The properties and blending recipe of petroleum cokes used to make high quality carbon anodes for aluminium electrolysis were studied. Three kinds of green cokes were selected for bench scale study to illustrate the e...The properties and blending recipe of petroleum cokes used to make high quality carbon anodes for aluminium electrolysis were studied. Three kinds of green cokes were selected for bench scale study to illustrate the effects of cokes properties and its blending recipe on anode performances. The results show that impurities derived mainly fi'om cokes remarkably affect the CO2 reactivity and air reactivity of carbon anodes. Ca, Na and V can increase CO2 reactivity of calcined cokes but S has the contrary effect, and the cokes of high V level generally present high air reactivity. The anodes with good quality can be made by properly selecting and scientifically blending of cokes, some poor quality cokes can also be used to produce high quality anodes with a reasonable blending recipe. Na contaminated anodes have high CO2 reactivity and air reactivity, so the recycled anode butts should be well cleaned to reduce Na content before being introduced into anode production, which is especially important to the low S cokes.展开更多
The thermal upgrading of two residual oils tory-scale continuous delayed coking unit. The goal with different characteristics was studied in a labora- was to investigate the influence of the process vari- ables such a...The thermal upgrading of two residual oils tory-scale continuous delayed coking unit. The goal with different characteristics was studied in a labora- was to investigate the influence of the process vari- ables such as temperature, reaction time and additive on liquid yield and products distribution. A maximum liquid yield of 73% was achieved compared to 69% with the commercial unit. This yield was even increased to 75% under the effect of an additive. The fractionation of liquid oil by simulated vacuum distillation showed a high yield of diesel (46.9%), compared to 28% for the commercial unit.展开更多
基金Project(51706160)supported by the National Natural Science Foundation of ChinaProject(T201906)supported by the Foundation for Outstanding Youth Innovative Research Groups of Higher Education Institution in Hubei Province,China
文摘The coal with low moisture during carbonization could not only increase the yield of coke,but also promote the coke quality and reduce the energy consumption.In this paper,the influence of the moisture in the blend coal(1.8%10.13%)on the product yields and coke quality during coal carbonization were investigated.The results show that the coke yield is increased from 75.90%to 77.16%,and the coke qualities such as coke strength after reaction with CO2(CSR),coke reactivity index(CRI),fragmentation index(M25)and abrasion index(M10))are also improved when the moisture of the blend coal decreases from 10.13%to 1.80%in a bench scale reactor.Due to the secondary reaction,tar become lighter when the moisture is decreased.In order to further prove the above results,the blend coal with 1.8%and 9%10%(common moisture used in coke plant)moisture is carbonized in a coke oven with 6 m height,the results show that CRI are 23.4%and 27.3%,CRS are 67.1%and 62.2%under 1.8%and 9%10%moisture of blend coal.Moreover,the variation of the moisture in blend coal has a limited influence on dust emission at the ascension pipe and the charging car.
文摘The properties and blending recipe of petroleum cokes used to make high quality carbon anodes for aluminium electrolysis were studied. Three kinds of green cokes were selected for bench scale study to illustrate the effects of cokes properties and its blending recipe on anode performances. The results show that impurities derived mainly fi'om cokes remarkably affect the CO2 reactivity and air reactivity of carbon anodes. Ca, Na and V can increase CO2 reactivity of calcined cokes but S has the contrary effect, and the cokes of high V level generally present high air reactivity. The anodes with good quality can be made by properly selecting and scientifically blending of cokes, some poor quality cokes can also be used to produce high quality anodes with a reasonable blending recipe. Na contaminated anodes have high CO2 reactivity and air reactivity, so the recycled anode butts should be well cleaned to reduce Na content before being introduced into anode production, which is especially important to the low S cokes.
文摘The thermal upgrading of two residual oils tory-scale continuous delayed coking unit. The goal with different characteristics was studied in a labora- was to investigate the influence of the process vari- ables such as temperature, reaction time and additive on liquid yield and products distribution. A maximum liquid yield of 73% was achieved compared to 69% with the commercial unit. This yield was even increased to 75% under the effect of an additive. The fractionation of liquid oil by simulated vacuum distillation showed a high yield of diesel (46.9%), compared to 28% for the commercial unit.