酸激发磷石膏地聚合物胶凝材料基本物理性能研究

以原状磷石膏、水泥、偏高岭土等为主要原料,磷酸或乙酸为激发剂,制备了酸激发磷石膏胶凝材料并探究其基本物理力学性能,研究了酸激发剂的种类及掺量对胶凝材料抗压性能和抗折性能的影响。研究结果表明:磷石膏、偏高岭土、水泥的质量比为45∶15∶40,掺加量为1-5%的磷酸或乙酸,制备的胶凝材料具有较好的抗压抗折性能;掺加量为4%的磷酸制备的胶凝材料28天龄期的抗压强度达到了30.97MPa,抗折强度3.64 MPa;掺加量为4%的乙酸制备的胶凝材料28天龄期的抗压强度19.03MPa,抗折强度达到了4.08 MPa;在自然养护条件下,磷酸激发的磷石膏胶凝材料的激发效果优于乙酸。

用造纸黑液和高掺量粉煤灰研制烧结砖

介绍大掺量粉煤灰烧结砖的试制过程 ,对烧结反应机理进行了初步探讨 ,论证了一种“资源优用”

高掺量造纸黑液粉煤灰烧结砖的研制

利用造纸工业废液和工业废渣粉煤灰研制成粉煤灰掺量高达70 %～85 % ,产品性能符合国家标准要求的烧结砖 ,生产成本比实心粘土砖降低1/2左右 ,具有明显的经济、社会效益。介绍了试制过程 ,并对酸激发机理、造纸黑液的活化增塑机理进行了分析。

高掺量粉煤灰烧结砖的试验研究

用改性黑液活化粉煤灰 ,并用其浓缩液做粘合剂 ,配以微量酸性激发材料试制高掺量粉煤灰烧结砖 ,并对烧结反应机理进行了初步探讨。

Synthesis and Luminescence Properties of Tb^3＋-Activated Silicate Oxyapatite Phosphor

A green-emitting phosphor Ca（Tb1-xLax）4（SiO4）3O （CTLS） was synthesized by a solid state reaction. X-ray diffraction, photoluminescence （PL） spectroscopy, reflectance spectra and chromaticity coordinates were carried out in this study. The CaTb4（SiO4）3O host has been known to crystallize in a hexagonal structure with disordering found in the Ca2＋ and Tb3＋ cation sites. The phosphors exhibited highly green-emitting band centered at 541 nm under ultraviolet excitation, which corresponds to the 5D4→7F5 transition. The optimal doping concentration of Tb3＋ was observed to be at 20 mol%, and the PL intensity was found to decline dramatically when the content of Tb3＋ exceeds 20m01% due to concentration quenching. Based on the results, we are currently evaluating the potential application of Ca（Tb,La）4（SiO4）30 as a new green-emitting near-UV LED convertible phosphor.