沉积物记录着水体环境变化的丰富信息,其中重金属的含量是评价水体环境的重要指标。文章应用酸溶–电感耦合等离子体质谱法建立了沉积物中常见金属元素钴、铜和铅的检测方法,以内标法定量,计算出3种元素的方法检出限分别为0.01 mg∙kg−1...沉积物记录着水体环境变化的丰富信息,其中重金属的含量是评价水体环境的重要指标。文章应用酸溶–电感耦合等离子体质谱法建立了沉积物中常见金属元素钴、铜和铅的检测方法,以内标法定量,计算出3种元素的方法检出限分别为0.01 mg∙kg−1、0.19 mg∙kg−1和0.27 mg∙kg−1,线性方程相关系数分别是0.9997、1和1,利用该方法分析了3种沉积物有证标准物质GBW07308a (GSD-8a)、GBW07365 (GSD-22)和GBW 07362 (GSD-19),测定值与参考值吻合较好,均在相应标准物质不确定度范围内。精密度实验中钴、铜、铅的相对标准偏差分别为3.93%~6.45%、2.22%~5.34%和2.58%~5.18%,正确度范围为 0.35%~3.69%,方法的精密度和准确性良好、检出限低。用建立的方法测定了某区域内50个沉积物样品,结果表明,本方法符合沉积物中3种重金属元素含量的测试要求,能满足实际环境中水系沉积物中3种重金属元素含量快速、准确测试的需要。方法高效、快速、可行。Sediments record plentiful information about changes in the water environment. The content of heavy metals in the sediment is an important index to evaluate the water environment. The article developed a detection method for common metal elements Co, Cu, and Pb in sediments using acid dissolution-inductively coupled plasma mass spectrometry (ICP-MS), quantifying the elements with the internal standard method. The detection limits for these three elements were calculated to be 0.01 mg∙kg−1 for Co, 0.19 mg∙kg−1 for Cu, and 0.27 mg∙kg−1 for Pb, with correlation coefficients for the linear equations being 0.9997, 1, and 1, respectively. The method was applied to analyze three sediment certified reference materials, GBW07308a (GSD-8a), GBW07365 (GSD-22), and GBW07362 (GSD-19), yielding values that were in good agreement with the reference values and within the uncertainty range of the corresponding standard materials. In the precision experiment, the relative standard deviations for Co, Cu, and Pb were 3.93%~6.45%, 2.22%~5.34%, and 2.58%~5.18%, respectively, with accuracy ranging from 0.35% to 3.69%. The method demonstrated good precision and accuracy with low detection limits. It was used to test 50 sediment samples from a certain area, indicating that the method meets the testing requirements for the content of these three heavy metals in sediments and fulfilling the need for rapid and accurate testing of these heavy metal contents in aquatic sediments in real environmental situations. The method is efficient, rapid, and feasible.展开更多
目的:建立微量酸消解-电感耦合等离子体质谱法检测潮汕凉茶中15种元素(Al、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、As、Se、Sr、Cd、Ba和Pb)的方法。方法:凉茶样品(200μL)经真空冷冻干燥,80℃水浴下使用65%硝酸(200μL)及30%过氧化氢(100μL...目的:建立微量酸消解-电感耦合等离子体质谱法检测潮汕凉茶中15种元素(Al、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、As、Se、Sr、Cd、Ba和Pb)的方法。方法:凉茶样品(200μL)经真空冷冻干燥,80℃水浴下使用65%硝酸(200μL)及30%过氧化氢(100μL)分别消解1 h及10 min,消解后用3%硝酸稀释至5 m L,再利用电感耦合等离子体质谱法测定Al、V、Cr等15种元素的含量。结果:15种元素的线性关系良好(r>0.999),检测限为0.009~14.788μg/L,精密度为0.7%~2.4%,加标回收率为84.0%~125.2%。9种凉茶中Al、V、Cr、Mn、Fe、Ni、As、Sr、Ba等9种元素含量存在差异(P<0.05)。结论:建立了微量酸消解-电感耦合等离子体质谱法检测潮汕凉茶中元素的方法,该方法简便、快速、准确。展开更多
文摘沉积物记录着水体环境变化的丰富信息,其中重金属的含量是评价水体环境的重要指标。文章应用酸溶–电感耦合等离子体质谱法建立了沉积物中常见金属元素钴、铜和铅的检测方法,以内标法定量,计算出3种元素的方法检出限分别为0.01 mg∙kg−1、0.19 mg∙kg−1和0.27 mg∙kg−1,线性方程相关系数分别是0.9997、1和1,利用该方法分析了3种沉积物有证标准物质GBW07308a (GSD-8a)、GBW07365 (GSD-22)和GBW 07362 (GSD-19),测定值与参考值吻合较好,均在相应标准物质不确定度范围内。精密度实验中钴、铜、铅的相对标准偏差分别为3.93%~6.45%、2.22%~5.34%和2.58%~5.18%,正确度范围为 0.35%~3.69%,方法的精密度和准确性良好、检出限低。用建立的方法测定了某区域内50个沉积物样品,结果表明,本方法符合沉积物中3种重金属元素含量的测试要求,能满足实际环境中水系沉积物中3种重金属元素含量快速、准确测试的需要。方法高效、快速、可行。Sediments record plentiful information about changes in the water environment. The content of heavy metals in the sediment is an important index to evaluate the water environment. The article developed a detection method for common metal elements Co, Cu, and Pb in sediments using acid dissolution-inductively coupled plasma mass spectrometry (ICP-MS), quantifying the elements with the internal standard method. The detection limits for these three elements were calculated to be 0.01 mg∙kg−1 for Co, 0.19 mg∙kg−1 for Cu, and 0.27 mg∙kg−1 for Pb, with correlation coefficients for the linear equations being 0.9997, 1, and 1, respectively. The method was applied to analyze three sediment certified reference materials, GBW07308a (GSD-8a), GBW07365 (GSD-22), and GBW07362 (GSD-19), yielding values that were in good agreement with the reference values and within the uncertainty range of the corresponding standard materials. In the precision experiment, the relative standard deviations for Co, Cu, and Pb were 3.93%~6.45%, 2.22%~5.34%, and 2.58%~5.18%, respectively, with accuracy ranging from 0.35% to 3.69%. The method demonstrated good precision and accuracy with low detection limits. It was used to test 50 sediment samples from a certain area, indicating that the method meets the testing requirements for the content of these three heavy metals in sediments and fulfilling the need for rapid and accurate testing of these heavy metal contents in aquatic sediments in real environmental situations. The method is efficient, rapid, and feasible.
文摘目的:建立微量酸消解-电感耦合等离子体质谱法检测潮汕凉茶中15种元素(Al、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、As、Se、Sr、Cd、Ba和Pb)的方法。方法:凉茶样品(200μL)经真空冷冻干燥,80℃水浴下使用65%硝酸(200μL)及30%过氧化氢(100μL)分别消解1 h及10 min,消解后用3%硝酸稀释至5 m L,再利用电感耦合等离子体质谱法测定Al、V、Cr等15种元素的含量。结果:15种元素的线性关系良好(r>0.999),检测限为0.009~14.788μg/L,精密度为0.7%~2.4%,加标回收率为84.0%~125.2%。9种凉茶中Al、V、Cr、Mn、Fe、Ni、As、Sr、Ba等9种元素含量存在差异(P<0.05)。结论:建立了微量酸消解-电感耦合等离子体质谱法检测潮汕凉茶中元素的方法,该方法简便、快速、准确。
