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酸碱盐改性对活性炭吸附油气特征的影响 被引量:1
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作者 宫徵羽 王春雨 +3 位作者 赵飞 许丹芸 罗清月 朱玲 《环境工程学报》 CAS CSCD 北大核心 2020年第5期1276-1285,共10页
采用酸碱盐溶液浸渍方法对活性炭进行改性,探究了其吸附油气的特征,考察了改性后的活性炭对油气吸附量和穿透时间的影响,采用BET、SEM、XRD及FT-IR等方法对活性炭进行了表征。结果表明:改性后的活性炭孔结构和表面化学性质发生了明显的... 采用酸碱盐溶液浸渍方法对活性炭进行改性,探究了其吸附油气的特征,考察了改性后的活性炭对油气吸附量和穿透时间的影响,采用BET、SEM、XRD及FT-IR等方法对活性炭进行了表征。结果表明:改性后的活性炭孔结构和表面化学性质发生了明显的变化,2#样品(醋酸改性)比表面积最大为1264.33 m2·g-1,碱改性活性炭对油气的吸附性能优于其他改性方法,3#样品(氨水改性)吸附容量最高为0.279 g·g-1,拟合动力学速率常数k′值是0.0963,5#样品(氢氧化钾改性)穿透时间最长为130 min;改性处理后,增加了活性炭表面的-OH与C=C含量,正丁烷主要以-CH2基团吸附在吸附剂表面。在综合酸碱盐溶液改性的基础上,利用Yoon-Nelson动力学方程对吸附曲线进行拟合,评价改性活性炭对油气的吸附性能。以上研究结果可为活性炭吸附油气的工业应用提供参考。 展开更多
关键词 油气 活性炭吸附 酸碱盐改性 动力学拟合
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Salt-free reactive dyeing of betaine-modified cationic cotton fabrics with enhanced dye fixation 被引量:6
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作者 Wei Ma Mei Meng +1 位作者 Shumin Yan Shufen Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2016年第1期175-179,共5页
Novel cationic cotton fabrics were prepared by an efficient and simple one-step pad–dry–bake pretreatment process with betaine as cationic reagent. Ester bonds formed between cotton fibers and betaine hydrochloride ... Novel cationic cotton fabrics were prepared by an efficient and simple one-step pad–dry–bake pretreatment process with betaine as cationic reagent. Ester bonds formed between cotton fibers and betaine hydrochloride were proved by Fourier transformed infrared attenuated total reflection(FTIR-ATR) spectra. Moreover, the properties of the cationic fabrics, including X-ray Diffraction(XRD), tensile strength and whiteness and yellowness index,were investigated in comparison with that of the untreated ones. The cationic fabrics were applied in salt-free dyeing of C.I. Reactive Red 195, C.I. Reactive Yellow 145 and C.I. Reactive Blue 19. Different dye fixation processes were applied and compared for untreated and cationic cotton. Dye fixation and color fastness properties of the dyes were tested, and the results presented that dye fixation on the cationic fabrics in the absence of salt was improved with satisfactory light fastness property and applicable wash and rub fastnesses. 展开更多
关键词 Salt-free dyeing Betaine Cationic cotton Reactive dyes
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