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搪瓷涂层的耐腐蚀及改良方法研究进展
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作者 洪昊 李文生 +1 位作者 汤上 亚茨申科·伊列娜 《表面技术》 EI CAS CSCD 北大核心 2023年第11期155-170,共16页
搪瓷具有良好的化学稳定性及结合性,且经济性好、制备工艺简单,有望成为优异的防腐涂层材料,已被尝试应用于石油化工、海洋工程、管道运输等领域的防腐工艺中,表现出了相对良好的防护效果。但它在强酸强碱环境下的耐腐蚀性不足且涂层中... 搪瓷具有良好的化学稳定性及结合性,且经济性好、制备工艺简单,有望成为优异的防腐涂层材料,已被尝试应用于石油化工、海洋工程、管道运输等领域的防腐工艺中,表现出了相对良好的防护效果。但它在强酸强碱环境下的耐腐蚀性不足且涂层中的气泡结构对耐腐蚀性有不利影响,同时高温烧结工艺也会影响金属基体的力学性能,这限制了防护性搪瓷涂层的应用。阐述了搪瓷作为防腐涂层的结构特点,在总结相关研究的基础上提出了目前搪瓷涂层的2种改良方法,即改进涂层成分和调控涂层结构。改进涂层成分可通过磨加法添加相关成分,调控搪瓷涂层组织结构,达到提高涂层[—Si—O—]网络及致密度的目的,进而提高涂层的耐腐蚀性;调控涂层结构主要包括制备多层涂层和热处理工艺,可在一定程度上降低涂层孔隙率、控制涂层晶体形核,这有助于提高涂层的有效厚度及可控制生成化学稳定相。在此基础上总结并提炼了这2种工艺的研究现状,讨论了上述2种技术方法对搪瓷涂层在酸、碱、盐腐蚀介质中的改良机理,并阐述了搪瓷涂层在不同服役介质中的耐腐蚀机制。同时,提出了目前技术的难点与可能的新方向,以期为搪瓷涂层的改良研究提供参考。 展开更多
关键词 搪瓷涂层 耐腐蚀性 酸碱盐环境 改良技术 综述
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Environmental Changes Analysis of Hongjiannao Lake During Recent Fifty Years——Based on the Data of Lake Sediments 被引量:6
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作者 李双 陈硕 张家武 《Agricultural Science & Technology》 CAS 2009年第6期178-183,共6页
Particle size, the contents of carbonate and TOC were analyzed on lake sediments from a short core in Hongjiannao Lake to discuss the environmental changes during the past decades. On the basis of the records in lake ... Particle size, the contents of carbonate and TOC were analyzed on lake sediments from a short core in Hongjiannao Lake to discuss the environmental changes during the past decades. On the basis of the records in lake sediments and comparison with the meteorological data of Yulin region, the environmental changes in Hongjiannao Lake were approximately divided into two stages. In stage A (1957 -1996), the lake evolution and the environmental change were mainly influenced by natural factors. It contains three sub-stages: A1 (1957-1969), a period of lake expansion, A2 (1969-1990), a stable period with high lake levels, and A3 (1990 -1996), a period of gradual extraction of the lake. In stage B (1996 -2005), the lake area still keeps diminishing. During this period, organic matter increased rapidly due to the input of nutrient elements in the catchment. The carbonate content, however, decreased. As the precipitation was decreasing and the temperature was increasing, the decrease of carbonate content could not be explained by either temperature or precipitation change. 展开更多
关键词 Hongjiannao Lake Particle size TOC CARBONATE Environmental changes
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