Gas chromatography-mass spectrometry(GC-MS) and the chemometric resolution method(alternative moving window factor analysis,AMWFA) were used for comparative analysis of volatile constituents in herbal pair(HP) flos lo...Gas chromatography-mass spectrometry(GC-MS) and the chemometric resolution method(alternative moving window factor analysis,AMWFA) were used for comparative analysis of volatile constituents in herbal pair(HP) flos lonicerae-caulis lonicerae(FL-CL) and its single herbs.The temperature-programmed retention index(PTRI) was also employed for the identification of compounds.In total,44,39,and 50 volatile chemical components in volatile oil of FL,CL and HP FL-CL were separately determined qualitatively and quantitatively,accounting for 87.22%,94.54% and 90.08% total contents of volatile oil of FL,CL and HP FL-CL,respectively.The results show that there are 32 common volatile constituents between HP FL-CL and single herb FL,33 common volatile constituents between HP FL-CL and single herb CL,and 10 new constituents in the volatile oil of HP FL-CL.展开更多
A novel halogen-free phosphorus–nitrogen–silicon flame retardant monomer with reactive siloxy groups,N-(diphenylphosphino)-1,1-diphenyl-N-(3-(triethoxysilyl)propyl) phosphinamine(DPTA) has been synthesized and was a...A novel halogen-free phosphorus–nitrogen–silicon flame retardant monomer with reactive siloxy groups,N-(diphenylphosphino)-1,1-diphenyl-N-(3-(triethoxysilyl)propyl) phosphinamine(DPTA) has been synthesized and was applied to the fire-resistant finishing of cotton fabrics. The molecular structure of DPTA has been well characterized by elemental analysis, FTIR,1H NMR, and ^(31)P NMR spectroscopies. The chemically-grafted cotton fabrics, which were treated with 25 wt% DPTA, were obtained and confirmed by attenuated total reflectance Fourier infrared spectroscopy(ATR-FTIR). The flame retardancy and thermal property of the treated samples were investigated by limited oxygen index(LOI), vertical flammability test(VFT), thermogravimetric analysis(TGA) and microscale combustion calorimeter(MCC). It is noted that in vertical flammability test, the treated samples extinguished immediately upon removing the ignition source, whereas the untreated one was completely burned out. Furthermore, TGA and MCC tests revealed that the treated samples produced a high char formation and a low heated release during combustion. The surface morphology of the untreated and treated samples and the char residues after LOI tests were observed by scanning electron microscopy(SEM). Therefore, all the results showed that the treated cotton fabrics with 25 wt% DPTA apparently improved the fireresistant and thermal performances.展开更多
Strain rate effects on the stress-strain behavior of sand were investigated by performing special plane strain and triaxial compression tests on saturated and air-dried sand specimens. In these tests, the loading stra...Strain rate effects on the stress-strain behavior of sand were investigated by performing special plane strain and triaxial compression tests on saturated and air-dried sand specimens. In these tests, the loading strain rate was changed many times by a factor of up to 1 000 during otherwise monotonous loading at a constant axial strain rate. Test results show that the stress jump upon a stepwise change in the strain rate decays with an increase in the irreversible strain when monotonous loading continues at the changed strain rate and the amount of stress jump is essentially proportional to the instantaneous stress. Based on the amount of these stress jumps, a parameter fl called the rate-sensitivity coefficient is introduced to represent the quantity of the observed viscous properties of sand, which equals 0.021 3 and 0.024 2 respectively for Hostun and Toyoura sands. Further analyses on the results indicate that the effect of the presence of pore water is deemed to be negligible with sand and the fl value is rather independent of loading method, wet condition and confining pressure.展开更多
Let TΩ be the singular integral operator with kernel Ω(x)/|x|n where is homogeneous of degree zero, integrable and has mean value zero on the unit sphere Sn-1. In this paper, by Fourier transform estimates, L...Let TΩ be the singular integral operator with kernel Ω(x)/|x|n where is homogeneous of degree zero, integrable and has mean value zero on the unit sphere Sn-1. In this paper, by Fourier transform estimates, Littlewood-Paley theory and approximation, the authors prove that if Ω∈(lnL)2 (Sn- 1), then the commutator generated by TΩ and CMO(Rn) function, and the corresponding discrete maximal operator, are compact on LP(Rn, |s|γp) for p∈ (1, ∞) and γp ∈ (-1, p-l)展开更多
Tm^(3+) doped Na_5Lu_9F_(32) single crystal with high optical quality was grown by an improved Bridgman method. The Judd-Ofelt intensity parameters ?_t(t=2, 4, 6) were calculated according to the measured absorption s...Tm^(3+) doped Na_5Lu_9F_(32) single crystal with high optical quality was grown by an improved Bridgman method. The Judd-Ofelt intensity parameters ?_t(t=2, 4, 6) were calculated according to the measured absorption spectra and physical-chemical properties of the obtained Na_5Lu_9F_(32) single crystal. The stimulated emission cross-section of the ~3F_4→~3H_6 transition(~1.8 μm) is 0.35×10^(-20) cm^2 for Tm^(3+) doped Na_5Lu_9F_(32) single crystal. The emission spectra under the excitation of 790 nm laser diode(LD) and fluorescence lifetime at 1.8 μm were measured to reveal the fluorescence properties of Tm^(3+) doped Na_5Lu_9F_(32) single crystal. The research results show that the Tm^(3+) doped Na_5Lu_9F_(32) single crystal has larger stimulated emission cross-section compared with other crystals. All these spectral properties suggest that this kind of Tm^(3+)doped Na_5Lu_9F_(32) crystal with high physical-chemical stability and high-efficiency emission at 1.8 μm may be used as potential laser materials for optical devices.展开更多
A three node C^0 continuous isoparametric beam element is formulated to model the curved pipe conveying fluid in three dimensional configuration.The equations of motion for the combined structure and fluid domain incl...A three node C^0 continuous isoparametric beam element is formulated to model the curved pipe conveying fluid in three dimensional configuration.The equations of motion for the combined structure and fluid domain including added mass effect,Coriolis effect,centrifugal effect and the effect of pressure on the walls of pipe have been developed by Paidoussis.This equation is converted to finite element formulation using Galerkin technique and is validated with the results available from literature.展开更多
Under dynamic conditions, the signals of power system have time-varying magnitude and frequency, which might lead to considerable errors for synchrophasor measurement. The traditional discrete Fourier transform (DFT) ...Under dynamic conditions, the signals of power system have time-varying magnitude and frequency, which might lead to considerable errors for synchrophasor measurement. The traditional discrete Fourier transform (DFT) based algorithms used in Phasor Measurement Unit (PMU) are hard to meet the requirements of measurement accuracy because of the existence of spectral leakage. A dynamic phasor measurement algorithm is proposed in this paper in which the input sampled data are considered as non-stationary signals with amplitude modulation-frequency modulation (AM-FM) form, and the measurement is achieved by AM-FM demodulation. An angle-shifted energy operator (ASEO) is used to extract the instantaneous amplitude and low pass differential filter is introduced for frequency estimation. Simulation results indicate that the proposed algorithm can effectively improve the phasor measurement accuracy and has very short response time for PMU under dynamic conditions.展开更多
基金Project(20976017) supported by the National Natural Science Foundation of China
文摘Gas chromatography-mass spectrometry(GC-MS) and the chemometric resolution method(alternative moving window factor analysis,AMWFA) were used for comparative analysis of volatile constituents in herbal pair(HP) flos lonicerae-caulis lonicerae(FL-CL) and its single herbs.The temperature-programmed retention index(PTRI) was also employed for the identification of compounds.In total,44,39,and 50 volatile chemical components in volatile oil of FL,CL and HP FL-CL were separately determined qualitatively and quantitatively,accounting for 87.22%,94.54% and 90.08% total contents of volatile oil of FL,CL and HP FL-CL,respectively.The results show that there are 32 common volatile constituents between HP FL-CL and single herb FL,33 common volatile constituents between HP FL-CL and single herb CL,and 10 new constituents in the volatile oil of HP FL-CL.
基金Supported by the National Natural Science Foundation of China(21301160)
文摘A novel halogen-free phosphorus–nitrogen–silicon flame retardant monomer with reactive siloxy groups,N-(diphenylphosphino)-1,1-diphenyl-N-(3-(triethoxysilyl)propyl) phosphinamine(DPTA) has been synthesized and was applied to the fire-resistant finishing of cotton fabrics. The molecular structure of DPTA has been well characterized by elemental analysis, FTIR,1H NMR, and ^(31)P NMR spectroscopies. The chemically-grafted cotton fabrics, which were treated with 25 wt% DPTA, were obtained and confirmed by attenuated total reflectance Fourier infrared spectroscopy(ATR-FTIR). The flame retardancy and thermal property of the treated samples were investigated by limited oxygen index(LOI), vertical flammability test(VFT), thermogravimetric analysis(TGA) and microscale combustion calorimeter(MCC). It is noted that in vertical flammability test, the treated samples extinguished immediately upon removing the ignition source, whereas the untreated one was completely burned out. Furthermore, TGA and MCC tests revealed that the treated samples produced a high char formation and a low heated release during combustion. The surface morphology of the untreated and treated samples and the char residues after LOI tests were observed by scanning electron microscopy(SEM). Therefore, all the results showed that the treated cotton fabrics with 25 wt% DPTA apparently improved the fireresistant and thermal performances.
基金Project(50679056) supported by the National Natural Science Foundation of ChinaProject(06-0378) supported by Program for NewCentury Excellent Talents in University+1 种基金Project(05SG25) supported by the "Dawn" Program of Shanghai Education Commission, ChinaProject(B308) supported by the Shanghai Leading Academic Discipline, China
文摘Strain rate effects on the stress-strain behavior of sand were investigated by performing special plane strain and triaxial compression tests on saturated and air-dried sand specimens. In these tests, the loading strain rate was changed many times by a factor of up to 1 000 during otherwise monotonous loading at a constant axial strain rate. Test results show that the stress jump upon a stepwise change in the strain rate decays with an increase in the irreversible strain when monotonous loading continues at the changed strain rate and the amount of stress jump is essentially proportional to the instantaneous stress. Based on the amount of these stress jumps, a parameter fl called the rate-sensitivity coefficient is introduced to represent the quantity of the observed viscous properties of sand, which equals 0.021 3 and 0.024 2 respectively for Hostun and Toyoura sands. Further analyses on the results indicate that the effect of the presence of pore water is deemed to be negligible with sand and the fl value is rather independent of loading method, wet condition and confining pressure.
基金supported by National Natural Science Foundation of China(Grant No.11371370)
文摘Let TΩ be the singular integral operator with kernel Ω(x)/|x|n where is homogeneous of degree zero, integrable and has mean value zero on the unit sphere Sn-1. In this paper, by Fourier transform estimates, Littlewood-Paley theory and approximation, the authors prove that if Ω∈(lnL)2 (Sn- 1), then the commutator generated by TΩ and CMO(Rn) function, and the corresponding discrete maximal operator, are compact on LP(Rn, |s|γp) for p∈ (1, ∞) and γp ∈ (-1, p-l)
基金supported by the National Natural Science Foundation of China(Nos.51472125 and 51272109)the Natural Science Foundation of Zhejiang Province(No.LZ17E020001)K.C. Wong Magna Fund in Ningbo University
文摘Tm^(3+) doped Na_5Lu_9F_(32) single crystal with high optical quality was grown by an improved Bridgman method. The Judd-Ofelt intensity parameters ?_t(t=2, 4, 6) were calculated according to the measured absorption spectra and physical-chemical properties of the obtained Na_5Lu_9F_(32) single crystal. The stimulated emission cross-section of the ~3F_4→~3H_6 transition(~1.8 μm) is 0.35×10^(-20) cm^2 for Tm^(3+) doped Na_5Lu_9F_(32) single crystal. The emission spectra under the excitation of 790 nm laser diode(LD) and fluorescence lifetime at 1.8 μm were measured to reveal the fluorescence properties of Tm^(3+) doped Na_5Lu_9F_(32) single crystal. The research results show that the Tm^(3+) doped Na_5Lu_9F_(32) single crystal has larger stimulated emission cross-section compared with other crystals. All these spectral properties suggest that this kind of Tm^(3+)doped Na_5Lu_9F_(32) crystal with high physical-chemical stability and high-efficiency emission at 1.8 μm may be used as potential laser materials for optical devices.
基金supported by All India Council for Technical Education[RPS grant No:8023/RID/RPS-24/2011-12]
文摘A three node C^0 continuous isoparametric beam element is formulated to model the curved pipe conveying fluid in three dimensional configuration.The equations of motion for the combined structure and fluid domain including added mass effect,Coriolis effect,centrifugal effect and the effect of pressure on the walls of pipe have been developed by Paidoussis.This equation is converted to finite element formulation using Galerkin technique and is validated with the results available from literature.
基金supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No.20090002110040)
文摘Under dynamic conditions, the signals of power system have time-varying magnitude and frequency, which might lead to considerable errors for synchrophasor measurement. The traditional discrete Fourier transform (DFT) based algorithms used in Phasor Measurement Unit (PMU) are hard to meet the requirements of measurement accuracy because of the existence of spectral leakage. A dynamic phasor measurement algorithm is proposed in this paper in which the input sampled data are considered as non-stationary signals with amplitude modulation-frequency modulation (AM-FM) form, and the measurement is achieved by AM-FM demodulation. An angle-shifted energy operator (ASEO) is used to extract the instantaneous amplitude and low pass differential filter is introduced for frequency estimation. Simulation results indicate that the proposed algorithm can effectively improve the phasor measurement accuracy and has very short response time for PMU under dynamic conditions.