期刊文献+
共找到337篇文章
< 1 2 17 >
每页显示 20 50 100
重“学”与重“道”:关于苏辙道德文章的考察
1
作者 杨胜宽 《西华大学学报(哲学社会科学版)》 2017年第6期1-7,共7页
苏辙在文学史上的评价呈逐渐走低的态势。古代文章"一门三父子"的千古美誉,苏辙成为最黯淡无光的一位。人们通常认为,这种现象是由于苏轼光环的遮蔽所致,其实最重要的原因是人们对苏辙研究不够,认识不深。苏辙一生重"学&... 苏辙在文学史上的评价呈逐渐走低的态势。古代文章"一门三父子"的千古美誉,苏辙成为最黯淡无光的一位。人们通常认为,这种现象是由于苏轼光环的遮蔽所致,其实最重要的原因是人们对苏辙研究不够,认识不深。苏辙一生重"学"重"道",强调学道既是学习之本,更是立身行世之要;他毕生追求道德文章相统一,故其文汪洋淡泊,有一唱三叹之致。苏轼与秦观不约而同地对此高度推崇,现代研究者不能熟视无睹。 展开更多
关键词 重“学” 重“道” 自得 道性为一 立身行世 文如其人
下载PDF
重“學”與重“道”:關於蘇轍道德文章的考察
2
作者 楊勝寬 《蜀学》 2019年第1期136-147,共12页
蘇轍在文學史上的評價逞逐漸走低的態勢。古代文章"一門三父子"的千古美譽,蘇轍成爲最黯淡無光的一位。人們通常認爲,這種現象是由於蘇軾光環的遮蔽所致,其實最重要的原因是人們對蘇轍研究不够,認識不深。蘇轍一生重"學&... 蘇轍在文學史上的評價逞逐漸走低的態勢。古代文章"一門三父子"的千古美譽,蘇轍成爲最黯淡無光的一位。人們通常認爲,這種現象是由於蘇軾光環的遮蔽所致,其實最重要的原因是人們對蘇轍研究不够,認識不深。蘇轍一生重"學"重"道",强調學道既是學習之本,更是立身行世之要;他畢生追求道德文章相統一,故其文汪洋淡泊,有一唱三歎之致。蘇軾與秦觀不約而同地對此高度推崇,現代研究者不能熟視無睹。 展开更多
关键词 苏辙 重“學”重“道” 自得 道性爲一 立身行世 文如其人
下载PDF
也谈由重“教”转为重“学”
3
作者 黄维树 《安徽广播电视大学学报》 2000年第3期57-61,共5页
:什么是教学 ?过去往往理解成“教师教———学生学” ,现代教学论认为应是“教师———教学生学”。学生的学习固然需要教师的指导 ,但归根结蒂是要靠自身的努力和能力。教师的“教”只有通过学生主动的“学”才能起作用 ,离开了学生... :什么是教学 ?过去往往理解成“教师教———学生学” ,现代教学论认为应是“教师———教学生学”。学生的学习固然需要教师的指导 ,但归根结蒂是要靠自身的努力和能力。教师的“教”只有通过学生主动的“学”才能起作用 ,离开了学生的自主学习 ,实现教学目的将是一句空话。学生在校期间获得的知识是有限的 ,大量的要靠离校后的体现。因此 ,掌握学习本领至关重要。教师“教”学生“学会了”学习 (即掌握了学习本领 ) ,并养成自我学习的习惯 ,那么 ,教学目标才能实现 ,教学的价值才得以真正的体现。本文从教师要教“学”的理由 (转变观念 )、如何教“学”(改革教法 )、完成教学轨道转移的标志 (达到效果 ) 展开更多
关键词 重“学” 自主 改革 习方法指导 非智力因素
下载PDF
教学贵在于重“学”
4
作者 徐滨 《太原教育学院学报》 2006年第1期8-11,共4页
学生的学习固然需要教师的指导,但归根结底是要靠自身的努力和能力。教师的“教”只有通过学生主动的“学”才能起作用。离开了学生的自主学习,实现教学目的将是一句空话。学生在校期间获得的知识是有限的,大量的要靠离校后的摄取。
关键词 重“学”理由 方法 标志
下载PDF
对外汉语教学侧重性分析
5
作者 綦志 《中国科教创新导刊》 2008年第5期140-141,共2页
根据在中国大陆地区学习汉语的外国人来源情况,以及针对东西方文化上存在的差异,作者提出了外籍学生在学习汉语时所面临的重点与难点问题及其可能的解决办法。在对比和参照其它语言教学过程中存在的优缺点基础上,本文作者在教学方法和... 根据在中国大陆地区学习汉语的外国人来源情况,以及针对东西方文化上存在的差异,作者提出了外籍学生在学习汉语时所面临的重点与难点问题及其可能的解决办法。在对比和参照其它语言教学过程中存在的优缺点基础上,本文作者在教学方法和课堂设计上提出了一些富有建设性的意见和做法,提供了一些有侧重性的教学参考示例。 展开更多
关键词 对外汉语教 对外语言教 东西方生特点比较 方法 性分析
下载PDF
笔墨创新在重彩山水画教学过程中的运用
6
作者 戴海涛 《艺术家》 2021年第10期92-93,共2页
笔墨创新建立在艺术家对传统重彩山水画的深刻体会、认识和把握上。与此同时,它也脱离不了中国哲学思想的滋养。重彩山水画创新可以通过笔墨创新来实现,在重彩山水画教学过程中,教师要把创新与传统联系起来,培养学生的笔墨创新思维,以... 笔墨创新建立在艺术家对传统重彩山水画的深刻体会、认识和把握上。与此同时,它也脱离不了中国哲学思想的滋养。重彩山水画创新可以通过笔墨创新来实现,在重彩山水画教学过程中,教师要把创新与传统联系起来,培养学生的笔墨创新思维,以达到借古开今的目的,促进重彩山水画教学的发展。 展开更多
关键词 彩士水画 笔墨创新 设计
下载PDF
建立学习学的思考和设想 被引量:1
7
作者 李自章 《北京师范学院学报(社会科学版)》 1989年第3期22-24,共3页
长期以来,在教学理论和实践中,存在着一种失之偏颇的现象;在教学理论的研究中,“教”研究得较多,“学”研究得较少。虽然呼吁和倡导开展“学”的研究的不乏其人,但身体力行,脚踏实地,全面系统地研究“学”的人却不多。可以说,“学”的... 长期以来,在教学理论和实践中,存在着一种失之偏颇的现象;在教学理论的研究中,“教”研究得较多,“学”研究得较少。虽然呼吁和倡导开展“学”的研究的不乏其人,但身体力行,脚踏实地,全面系统地研究“学”的人却不多。可以说,“学”的研究一直是教学理论研究的一个薄弱环节;在教学实践中,重“教”而不重“学”。 展开更多
关键词 重“学” 习理论 应用性 实践 主导作用 系统性 习科 理论研究 教师
下载PDF
Optimizing polypharmacy interventions and evaluating their impact on elderly inpatients using dual criteria and medication appropriateness index
8
作者 Zhipeng Wang Zhile Wu +2 位作者 Jianen Zhu Li Wei Pengjiu Yu 《Journal of Chinese Pharmaceutical Sciences》 CAS CSCD 2024年第10期977-983,共7页
With the acceleration of society’s aging process,the widespread phenomenon of polypharmacy among the elderly has become a significant concern.This research aimed to analyze potential inappropriate medication among 17... With the acceleration of society’s aging process,the widespread phenomenon of polypharmacy among the elderly has become a significant concern.This research aimed to analyze potential inappropriate medication among 178 inpatients in the geriatric general department of our hospital from January 2022 to September 2022.The participants were randomly assigned to an observation group and a control group.The observation group received pharmaceutical intervention,whereas the control group did not.The objective was to explore the impact of pharmaceutical intervention on polypharmacy in this population.The results revealed that after pharmaceutical intervention,there were no significant differences in medication adherence,medication appropriateness index(MAI),quantity of medicine,and potentially inappropriate medication(PIM)in the control group compared to before the intervention(P>0.05).However,the observation group showed significant improvement(P<0.05).The proportion of patients with good adherence increased from 57%to 78%,and the percentage of patients with MAI scores over 10 decreased from 60%to 40%.Moreover,there was a reduction in the number of medications prescribed,with only 47%of patients receiving more than five different types compared to the initial rate of 64%.Additionally,the occurrence of PIM declined from an initial rate of 64%to just 44%,surpassing that observed in the control group.Therefore,the implementation of pharmaceutical intervention can effectively enhance medication adherence and appropriateness among elderly patients,mitigate the risk of PIM,and promote rational medicine utilization. 展开更多
关键词 POLYPHARMACY Pharmaceutical intervention Medication appropriateness index Beers Criteria
原文传递
数学结课的原则
9
作者 徐润 《陕西教育(教学)》 1996年第6期31-32,共2页
好的结课就能发挥前馈控制的功能,强化对知识的正确认识,减少出现知识偏差的人次。好的结课能改变重“教”不重“学”的主观性,改变重“知”不重“思”的浅层性,改变重“灌”不重“趣”的强制性。帮助学生总结、归纳知识,形成新的认知... 好的结课就能发挥前馈控制的功能,强化对知识的正确认识,减少出现知识偏差的人次。好的结课能改变重“教”不重“学”的主观性,改变重“知”不重“思”的浅层性,改变重“灌”不重“趣”的强制性。帮助学生总结、归纳知识,形成新的认知结构。能培养学生归纳概括能力,使学生享受成功的乐趣,提高学习的自信心,激发学生的探索欲望。能启动学生的内在活力,对学生产生良好的心理影响。因此,笔者认为在教学实践中,结课应该遵循以下几方面原则。 一、简明扼要、突出重点的原则 课尾结课一般安排2—3分钟左右,结课不可能面面俱到,要紧扣教学目标、重点和知识结构,针对学生的知识掌握情况进行及时的精练的归纳。 展开更多
关键词 结课 认知结构 问题 基本性质 前馈控制 实践 目标 知识结构 重“学” 心理影响
下载PDF
Re-identifying beef cattle using improved AlignedReID++
10
作者 YING Xiaoyi ZHAO Jizheng +7 位作者 YANG Lingling ZHOU Xinyi WANG Lei GAO Yannian ZAN Linsen YANG Wucai LIU Han SONG Huaibo 《农业工程学报》 EI CAS CSCD 北大核心 2024年第18期132-146,共15页
Accurate and continuous identification of individual cattle is crucial to precision farming in recent years.It is also the prerequisite to monitor the individual feed intake and feeding time of beef cattle at medium t... Accurate and continuous identification of individual cattle is crucial to precision farming in recent years.It is also the prerequisite to monitor the individual feed intake and feeding time of beef cattle at medium to long distances over different cameras.However,beef cattle can tend to frequently move and change their feeding position during feeding.Furthermore,the great variations in their head direction and complex environments(light,occlusion,and background)can also lead to some difficulties in the recognition,particularly for the bio-similarities among individual cattle.Among them,AlignedReID++model is characterized by both global and local information for image matching.In particular,the dynamically matching local information(DMLI)algorithm has been introduced into the local branch to automatically align the horizontal local information.In this research,the AlignedReID++model was utilized and improved to achieve the better performance in cattle re-identification(ReID).Initially,triplet attention(TA)modules were integrated into the BottleNecks of ResNet50 Backbone.The feature extraction was then enhanced through cross-dimensional interactions with the minimal computational overhead.Since the TA modules in AlignedReID++baseline model increased the model size and floating point operations(FLOPs)by 0.005 M and 0.05 G,the rank-1 accuracy and mean average precision(mAP)were improved by 1.0 percentage points and 2.94 percentage points,respectively.Specifically,the rank-1 accuracies were outperformed by 0.86 percentage points and 0.12 percentage points,respectively,compared with the convolution block attention module(CBAM)and efficient channel attention(ECA)modules,although 0.94 percentage points were lower than that of squeeze-and-excitation(SE)modules.The mAP metric values were exceeded by 0.22,0.86 and 0.12 percentage points,respectively,compared with the SE,CBAM,and ECA modules.Additionally,the Cross-Entropy Loss function was replaced with the CosFace Loss function in the global branch of baseline model.CosFace Loss and Hard Triplet Loss were jointly employed to train the baseline model for the better identification on the similar individuals.AlignedReID++with CosFace Loss was outperformed the baseline model by 0.24 and 0.92 percentage points in the rank-1 accuracy and mAP,respectively,whereas,AlignedReID++with ArcFace Loss was exceeded by 0.36 and 0.56 percentage points,respectively.The improved model with the TA modules and CosFace Loss was achieved in a rank-1 accuracy of 94.42%,rank-5 accuracy of 98.78%,rank-10 accuracy of 99.34%,mAP of 63.90%,FLOPs of 5.45 G,frames per second(FPS)of 5.64,and model size of 23.78 M.The rank-1 accuracies were exceeded by 1.84,4.72,0.76 and 5.36 percentage points,respectively,compared with the baseline model,part-based convolutional baseline(PCB),multiple granularity network(MGN),and relation-aware global attention(RGA),while the mAP metrics were surpassed 6.42,5.86,4.30 and 7.38 percentage points,respectively.Meanwhile,the rank-1 accuracy was 0.98 percentage points lower than TransReID,but the mAP metric was exceeded by 3.90 percentage points.Moreover,the FLOPs of improved model were only 0.05 G larger than that of baseline model,while smaller than those of PCB,MGN,RGA,and TransReID by 0.68,6.51,25.4,and 16.55 G,respectively.The model size of improved model was 23.78 M,which was smaller than those of the baseline model,PCB,MGN,RGA,and TransReID by 0.03,2.33,45.06,14.53 and 62.85 M,respectively.The inference speed of improved model on a CPU was lower than those of PCB,MGN,and baseline model,but higher than TransReID and RGA.The t-SNE feature embedding visualization demonstrated that the global and local features were achieve in the better intra-class compactness and inter-class variability.Therefore,the improved model can be expected to effectively re-identify the beef cattle in natural environments of breeding farm,in order to monitor the individual feed intake and feeding time. 展开更多
关键词 method IDENTIFY beef cattle precision livestock re-identification AlignedReID++ deep learning
下载PDF
初中文言文教学:对“标”找差
11
作者 裴洪兵 《教育研究与评论(中学教育教学)》 2018年第6期52-55,共4页
初中文言文教学应避免重"教"轻"学",教师要引导学生在疑问中突破自己,在解决疑问中有了新的认知体验与成长体验,然后进一步巩固自主学习的意识,这才是真学习,才是课标中所说的"理解"。教学还应避免重"言"轻"文",教师要在教学... 初中文言文教学应避免重"教"轻"学",教师要引导学生在疑问中突破自己,在解决疑问中有了新的认知体验与成长体验,然后进一步巩固自主学习的意识,这才是真学习,才是课标中所说的"理解"。教学还应避免重"言"轻"文",教师要在教学时适当突破文言文本身的知识价值,突破文言文传统的教学范式,从"文"的角度着眼追求一些语文味,学生的学习乐趣才会更浓些,学习效果也才会更好些。 展开更多
关键词 文言文教 重“教”轻“学 重“言”轻“文”
下载PDF
儒家人格理想的铸造
12
作者 李军 《湖南大学学报(社会科学版)》 1996年第4期12-18,共7页
一论教育的本质和价值孔子首先从个体的人的先天遗传素质出发,讨论教育的本质和价值问题,然后在此基础上展开对其他基本理论问题的论述。在讨论教育本质问题时,孔子强调由论“学”而论“教”、由重“学”而重“教”。例如,《论语》(本... 一论教育的本质和价值孔子首先从个体的人的先天遗传素质出发,讨论教育的本质和价值问题,然后在此基础上展开对其他基本理论问题的论述。在讨论教育本质问题时,孔子强调由论“学”而论“教”、由重“学”而重“教”。例如,《论语》(本文引用论语只注篇名)中“性”四见、“学”六十四见、“教”七见、“诲”五见,且开篇第一句便讨论“学”和“习”。一位终身从事教育工作的教师言行录——《论语》,被其弟子和后学作如是载述和编排,绝非偶然。它反映了在教育究竟应被看作什么、应从何种角度来讨论等重大理论问题上,孔子及儒家学派的一贯观点。 展开更多
关键词 孔子 “有教无类” 《论语》 儒家人格 重“学” 教育理念 《六经》 启发诱导 《诗》 教师
下载PDF
晚清西方力学知识体系的译介与传播——以“重学”一词的使用及其演变为例 被引量:7
13
作者 聂馥玲 郭世荣 《自然辩证法通讯》 CSSCI 北大核心 2010年第2期65-70,共6页
"重学"是早期西方"力学"(Mechanics)一词的译名。它在晚清力学传播中占据了重要的位置。随着与重学相关著作的译介与传播,"重学"一词的内涵不断扩大,"重学"的译名也发生了变化,有将"Me-ch... "重学"是早期西方"力学"(Mechanics)一词的译名。它在晚清力学传播中占据了重要的位置。随着与重学相关著作的译介与传播,"重学"一词的内涵不断扩大,"重学"的译名也发生了变化,有将"Me-chanics"译为"力学"的,也有将"Dynamics"译作"力学"的,而且"力学"一词的含义当时在不同的译著中指代不同,造成了力学知识体系传播的混乱。"重学"一词的使用及其演变过程体现了力学知识体系在晚清的吸收与消化过程,并反映出当时翻译与传播中存在的问题。 展开更多
关键词 动力 传播
原文传递
Microstructure evolution and tensile mechanical properties of thixoformed AZ61 magnesium alloy prepared by squeeze casting 被引量:3
14
作者 陈添 解志文 +4 位作者 罗荘竹 杨钦 谭生 王赟姣 罗一旻 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第11期3421-3428,共8页
A novel process that combines squeeze casting with partial remelting to obtain AZ61 magnesium alloy with semi-solid microstructures was proposed. In this route, the squeeze casting was used to predeform the magnesium ... A novel process that combines squeeze casting with partial remelting to obtain AZ61 magnesium alloy with semi-solid microstructures was proposed. In this route, the squeeze casting was used to predeform the magnesium alloy billets to obtain small dendritic structures. During subsequent partial remelting, small dendritic structures transform into globular grains surrounded by liquid films. The results show that the squeeze casting AZ61 alloy after partial remelting produces more ideal, finer semi-solid microstructure compared with as-cast AZ61 alloy treated by the same isothermal holding conditions. Moreover, the mechanical properties of the thixoformed AZ61 alloy prepared by squeeze casting plus partial remelting are better than those of the thixoformed alloy prepared by conventional casting plus partial remelting. 展开更多
关键词 AZ61 magnesium alloy squeeze casting partial remelting mechanical properties
下载PDF
Ecological risk assessment of heavy metals in sediments of Xiawan Port based on modified potential ecological risk index 被引量:40
15
作者 祝慧娜 袁兴中 +7 位作者 曾光明 蒋敏 梁婕 张长 尹娟 黄华军 刘智峰 江洪炜 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第6期1470-1477,共8页
Modified potential ecological risk index (MRI) was proposed based on the potential ecological risk index (RI) and risk assessment code (RAC) by modifying an index. The modified index was relevant to the chemical... Modified potential ecological risk index (MRI) was proposed based on the potential ecological risk index (RI) and risk assessment code (RAC) by modifying an index. The modified index was relevant to the chemical speciation of heavy metals. Xiawan Port, a typical region contaminated by industrial production, was selected as a case study area. The total concentrations and chemical speciation of heavy metals in sediments of Xiawan Port were analyzed. The experimental data indicate that Xiawan Port is seriously polluted by heavy metals, especially by Cd. The risks of heavy metals are evaluated by RI, RAC and MRI, respectively. The resluts of MRI show that the risks of heavy metals are in the decreasing order of Cd〉Pb〉Cu〉Zn. Comparison of results by different methods reveals that MRI integrates the characters of RI and RAC. MRI is recognized to be useful for risk managemnt of heavy metals in sediments. 展开更多
关键词 heavy metals chemical speciation modified potential ecological risk index SEDIMENTS Xiawan Port
下载PDF
Fractional distribution and risk assessment of heavy metal contaminated soil in vicinity of a lead/zinc mine 被引量:17
16
作者 黄顺红 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第10期3324-3331,共8页
The pollution characteristics of Pb, Cd, Zn, Cu and Ni in soil of lead-zinc mining area were studied. The results indicate that the contamination degree followed the sequence of Cd〉Pb〉Zn〉Ni〉Cu and concentrations o... The pollution characteristics of Pb, Cd, Zn, Cu and Ni in soil of lead-zinc mining area were studied. The results indicate that the contamination degree followed the sequence of Cd〉Pb〉Zn〉Ni〉Cu and concentrations of Pb, Cd and Zn exceeded corresponding limits of the Chinese National Soil Environmental Quality Standard III. The soil was extremely polluted by Cd(Iego=5.26), moderately to heavily polluted by Zn(Iego=2.38), heavily to extremely polluted by Pb(Iego=4.13). The results of BCR three-step sequential extraction procedure show that the active Cd, Pb and Zn were relatively high and might exert adverse effects on the plants grown in the soil, while Cu and Ni existed in soil with a relatively stable form. Potential ecological risk results indicate that soils were engaging in a high potential ecological risk by pollution of Cd and should be given rise to concern. 展开更多
关键词 heavy metals chemical speciation geoaccumulation index potential ecological risk
下载PDF
ROBOTIC DYNAMIC MODEL ON LOAD SWING OF SLEWING CRANE 被引量:1
17
作者 王帮峰 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2000年第1期10-14,共5页
This paper sets up a robotic manipulator model on slewing crane. The model can synthetically describe the dynamic behavior of the load of slewing crane in rotating, elevating and hoisting motions. The dynamic equation... This paper sets up a robotic manipulator model on slewing crane. The model can synthetically describe the dynamic behavior of the load of slewing crane in rotating, elevating and hoisting motions. The dynamic equations of the system are recursively derived by a Newton Euler method. The dynamic behavior of the load of slewing crane in rotating motion is simulated on a computer. The method of robotic dynamics to derive the dynamic equations of the swing of load is accurate and convenient and it has good regularity. The result of the study provides a base in theory on design of crane and an accurate mathematical model for controlling the swing of load. 展开更多
关键词 ROBOT CRANE dynamics modeling swing of load computer simulation
下载PDF
Plant Developmental Biology in China: Past, Present and Future 被引量:5
18
作者 许智宏 种康 《Acta Botanica Sinica》 CSCD 2002年第9期1085-1095,共11页
Plant development is a process from germination of seed to vegetative growth, flower initiation and development, fertilization and finally to the next generation seed formation. A lot of achievements have been obtai... Plant development is a process from germination of seed to vegetative growth, flower initiation and development, fertilization and finally to the next generation seed formation. A lot of achievements have been obtained in plant developmental biology in China. Since the 1990's, those young generation scientists returned to China from abroad to use molecular and genetic techniques to study morphological, physiological and biochemical process of plant development. The present paper reviews the progress in some research area of plant developmental biology in the past decades and also prospects the chance and future of plant developmental studies, due to the recent advances of plant genome sequencing and functional genomics in China under the international research background. 展开更多
关键词 developmental biology organ differentiation flowering physiology sexual differentiation fertilization biology seed physiology
下载PDF
Influence of Soil Geochemistry to the Quality of Winter Jujube in Zhanhua 被引量:1
19
作者 高宗军 王敏 +1 位作者 庞绪贵 刘中业 《Agricultural Science & Technology》 CAS 2010年第9期209-212,216,共5页
[Objective] The aim was to investigate the effects of soil geochemistry on the quality of winter jujube.[Method]Based on the data of ecological geochemical survey in lower Yellow River Basin,the relevance of the geoch... [Objective] The aim was to investigate the effects of soil geochemistry on the quality of winter jujube.[Method]Based on the data of ecological geochemical survey in lower Yellow River Basin,the relevance of the geochemistry environment in top soils and the quality of winter jujubes was analyzed.[Result]Cd,Ni and other heavy metals in the soil more obviously affected the nutrition of winter jujubes.[Conclusion]B,Mn,MgO,Cd,Zn,K2O and other elements in the root soil played an important role in the enrichment of Cr and Hg of winter jujube fruit.And the absorption of heavy metals in winter jujube root could be interfered by improving fertilization method,to reduce the enrichment of harmful elements in jujube fruit. 展开更多
关键词 Zhanhua winter jujube Ecological geochemical environment Heavy metal element
下载PDF
Infrared Spectra and Theoretical Calculations of BS2 and BS2-: Strong Pseudo Jahn-Teller Effect
20
作者 赵杰 俞文杰 +1 位作者 黄腾飞 王雪峰 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2017年第6期678-684,I0002,共8页
Laser ablated boron atoms have been reacted with hydrogen sulfide and the reaction products condensed with argon at 4 K, which gave BS2, BS2-, HSBS, and HBS molecules. Reagent isotopic substitution (H2S, H234S, D2S, ... Laser ablated boron atoms have been reacted with hydrogen sulfide and the reaction products condensed with argon at 4 K, which gave BS2, BS2-, HSBS, and HBS molecules. Reagent isotopic substitution (H2S, H234S, D2S, 10 B, 11B) and variation of boron and hydrogen sulfide concentrations have been used to identify the major products. Both BS2-- and BS2 were identified as linear molecules with no significant difference in the structure parameters, but the B-S anti-symmetric stretching vibration of BS2 is significantly lower than that of BS2-, which is ascribed to pseudo Jahn-Teller effect. Theoretical calculation was employed to have an insight into the interaction nature of the bonds in the corresponding products. 展开更多
关键词 Matrix isolation Pseudo Jahn-Teller effect Multicenter bond
下载PDF
上一页 1 2 17 下一页 到第
使用帮助 返回顶部