The purpose of this paper is to investigate reasonable cost benefit criteria within the framework of environmental formal safety assessment (FSA). In this study a statistical analysis of oil spill data was carried o...The purpose of this paper is to investigate reasonable cost benefit criteria within the framework of environmental formal safety assessment (FSA). In this study a statistical analysis of oil spill data was carried out based on the report of International Oil Pollution Compensation Funds. According to the statistical study of actual oil spill from tankers, it is found that collisions and groundings are the most probable causes of the oil spills from tankers. Probability distributions of costs of oil spill and oil spill amount are investigated, and a non-linear regression formula between costs of oil spills and oil spill weight are derived. Using the regression formula, an oil spill weight dependent CATStm (Cost of Averting a Ton of oil Spilt) is proposed. Moreover in order to apply the weight dependent CATSthr to cost benefit analysis (CBA), a new cost-effective criterion is newly proposed with considering its concrete application to environmental FSA.展开更多
Electrochemical carbon dioxide reduction(CO_(2)RR)has been generally regarded as green technologies that can convert renewable energy such as sunlight and wind into fuels and valuable chemicals.However,the large‐scal...Electrochemical carbon dioxide reduction(CO_(2)RR)has been generally regarded as green technologies that can convert renewable energy such as sunlight and wind into fuels and valuable chemicals.However,the large‐scale implementation of CO_(2)RR is severely hindered by the lack of high‐performance CO_(2)RR electrocatalysts.Heterogeneous molecular catalysts and metal‐organic framework with well‐defined structure and high tunability of the metal centers and ligands show great promise for CO_(2)RR in terms of both fundamental understanding and practical application.Here,structural and interfacial engineering of these well‐defined metal‐organic ensembles is summarized.This review starts from the fundamental electrochemistry of CO_(2)RR and its evaluation criteria,and then moves to the heterogeneous molecular catalysts and metal‐organic framework with emphasis on the engineering of metal centers and ligands,their interaction with supports,as well as in situ reconstruction of metal‐organic ensembles.Summary and outlook are present in the end,with the hope to inspire and provoke more genuine thinking on the design and fabrication of efficient CO_(2)RR electrocatalysts.展开更多
The processing speed of the communication between nodes in a parallel processor has become the major bottleneck of the processor's performance.RDMA(Remote Direct Memory Access) technology has drawn more attention ...The processing speed of the communication between nodes in a parallel processor has become the major bottleneck of the processor's performance.RDMA(Remote Direct Memory Access) technology has drawn more attention recently due to its capability of transferring a larger amount of data, higher speed and reliability.4DSP(4 Digital Signal Processing) module comprised of Tiger-SHARC201 chip is connected by LVDS(Low Voltage Differential Signal) circuits.This paper proposes a general and reconfigurable RDMA platform and its corresponding communication protocol with all the routes linked based on the zero copy.The protocol transfers message of DSP by interrupting of DMA and is applied on massive remote image impression, which reduces memory needs and working burden of CPU.The experiment results show this platform is efficient, flexible, and expandable of being integrated to a larger scale in the next development stages.展开更多
Approaches to building renovation require high professional levels, interdisciplinary elements, team work and time to study and do research on the buildings. The process of renovating historic buildings is made up of ...Approaches to building renovation require high professional levels, interdisciplinary elements, team work and time to study and do research on the buildings. The process of renovating historic buildings is made up of agreements and compromises between the interests of the government, common interests, and the motives and interests of individual owners and prospective investors. Research that deals with any portion of cultural heritages always carried out very precisely, but there is still no precise knowledge of how to define a system and draw up a model that accurately represents a cultural heritage. In the existing literature on this topic, the authors have written about the different views of how to explain the construction project as a system. While many authors focus on "sub-phases" directly connected to the building of an object, the process involved in the construction phase often neglects the phases required before beginning work, which culminates in a logical sequence in the process of preparing a project. Irregularities or deficiencies which occur during the preparation process of a project often directly impact the construction itself. What the scope of this impact depends on the approach of the contractual organization, the organization of construction companies and on co-operation between the customer (or architects) and the contractors. Unlike the projects for newly built objects, the conservation projects of cultural heritage are not only more demanding because of lack of knowledge of the building materials, construction, foundation and interaction of the mentioned individual parts into a unit called a building. The authors analyzed the structural aspects of building conservation which were suggested by Beckmaun and Bowles and another methodology, which was developed as part of the 5th framework program for the purpose of providing a comprehensive and interdisciplinary treatment of the revitalization of a historical city. The authors found that both methodologies do not include modern IT tools and methods. By analyzing and monitoring the restoration of historic buildings in Slovenia, specifically in the city of Maribor (including all documentation, interviews and direct views) the authors found that the project was regarded as a collection of individual projects rather than a unified whole (a system). The authors have demonstrated the consequences of structuring a historic building restoration project in a non-systemic way. This type of project can be classified as a non-sustainable renovation. In this article, at first the authors will try to clarify what types of systems and subsystems are considered in renovating historic buildings. The authors show when and why a system becomes stochastic (a probability) and in the end what would be needed to successfully re-establish it back to a determined system. By analyzing the work and reconstruction of old buildings in Maribor, the authors found that it would be necessary to give a new framework with IT tools for the preparation of a historic building restoration project.展开更多
A new 2D Eu-BTB framework(1) with stratified gridding structure of about 14.6×16.9was synthesized and characterized.Compound 1 displays excellent water stability with the pH 2–12. The luminescent investigations ...A new 2D Eu-BTB framework(1) with stratified gridding structure of about 14.6×16.9was synthesized and characterized.Compound 1 displays excellent water stability with the pH 2–12. The luminescent investigations suggest that 1 could represent a chemical sensor of PO43. with high sensitivity and selectivity. Importantly, 1 as a sensor of PO_4^(3-) can be reused at least five times.On the other hand, the catalytic investigations of 1 were carried out, indicating that 1 could be demonstrated as a recyclable catalyst for CO_2 conversion with epoxides.展开更多
Within the framework of the dynamical cluster decay model (DCM), the in evaporation cross-sections (σ1n) of cold fusion reactions (Pb and Bi targets) are calculated for ZCN = 104-113 superheavy nuclei. The calc...Within the framework of the dynamical cluster decay model (DCM), the in evaporation cross-sections (σ1n) of cold fusion reactions (Pb and Bi targets) are calculated for ZCN = 104-113 superheavy nuclei. The calculations are carried out in the fixed range of excitation energy ECN = 15 ± 1 MeV, so that the comparative analysis of reaction dynamics can be worked out. First of all, the fission barriers (Bf ) and neutron separation energies (S1n) are estimated to account the decreasing cross-sections of cold fusion reactions. In addition to this, the importance of hot optimum orientations of β24-deformed nuclei over cold one is explored at fixed angular momentum and neck-length parameters. The hot optimum orientations support all the target-projectile (t,p) combinations, which are explored experimentally in the cold fusion reactions. Some new target-projectile combinations are also predicted for future exploration. Further, the In cross-sections are addressed for ZCN = 104-113 superheavy nuclei at comparable excitation energies which show the decent agrement with experimental data upto ZCN = 109 nuclei. Finally, to understand the dynamics of higher-Z superheavy nuclei, the cross-sections are also calculated at maximum available energies around the Coulomb barrier and the effect of non-sticking moment of inertia (INS) is also investigated at these energies.展开更多
The long-term safe operation of high-power equipment and integrated electronic devices requires efficient thermal management,which in turn increases the energy consumption further.Hence,the sustainable development of ...The long-term safe operation of high-power equipment and integrated electronic devices requires efficient thermal management,which in turn increases the energy consumption further.Hence,the sustainable development of our society needs advanced thermal management with low,even zero,energy consumption.Harvesting water from the atmosphere,followed by moisture desorption to dissipate heat,is an efficient and feasible approach for zero-energy-consumption thermal management.However,current methods are limited by the low absorbance of water,low water vapor transmission rate(WVTR)and low stability,thus resulting in low thermal management capability.In this study,we report an innovative electrospinning method to process hierarchically porous metal–organic framework(MOF)composite fabrics with high-efficiency and zero-energy-consumption thermal management.The composite fabrics are highly loaded with MOF(75 wt%)and their WVTR value can be up to 3138 g m^(-2) d^(-1).The composite fabrics also exhibit stable microstructure and performance.Under a conventional environment(30℃,60%relative humidity),the composite fabrics adsorb water vapor for regeneration within 1.5 h to a saturated value Wsat of 0.614 g g^(-1),and a corresponding equivalent enthalpy of 1705.6 J g^(-1).In the thermal management tests,the composite fabrics show a strong cooling capability and significantly improve the performance of thermoelectric devices,portable storage devices and wireless chargers.These results suggest that hierarchically porous MOF composite fabrics are highly promising for thermal management of intermittent-operation electronic devices.展开更多
文摘The purpose of this paper is to investigate reasonable cost benefit criteria within the framework of environmental formal safety assessment (FSA). In this study a statistical analysis of oil spill data was carried out based on the report of International Oil Pollution Compensation Funds. According to the statistical study of actual oil spill from tankers, it is found that collisions and groundings are the most probable causes of the oil spills from tankers. Probability distributions of costs of oil spill and oil spill amount are investigated, and a non-linear regression formula between costs of oil spills and oil spill weight are derived. Using the regression formula, an oil spill weight dependent CATStm (Cost of Averting a Ton of oil Spilt) is proposed. Moreover in order to apply the weight dependent CATSthr to cost benefit analysis (CBA), a new cost-effective criterion is newly proposed with considering its concrete application to environmental FSA.
文摘Electrochemical carbon dioxide reduction(CO_(2)RR)has been generally regarded as green technologies that can convert renewable energy such as sunlight and wind into fuels and valuable chemicals.However,the large‐scale implementation of CO_(2)RR is severely hindered by the lack of high‐performance CO_(2)RR electrocatalysts.Heterogeneous molecular catalysts and metal‐organic framework with well‐defined structure and high tunability of the metal centers and ligands show great promise for CO_(2)RR in terms of both fundamental understanding and practical application.Here,structural and interfacial engineering of these well‐defined metal‐organic ensembles is summarized.This review starts from the fundamental electrochemistry of CO_(2)RR and its evaluation criteria,and then moves to the heterogeneous molecular catalysts and metal‐organic framework with emphasis on the engineering of metal centers and ligands,their interaction with supports,as well as in situ reconstruction of metal‐organic ensembles.Summary and outlook are present in the end,with the hope to inspire and provoke more genuine thinking on the design and fabrication of efficient CO_(2)RR electrocatalysts.
基金Supported by the NSFC (National Natural Science Foundation of China)the 863 Program (2006AA1332)ERIPKU, the Program for New Century Excellent Talents in University.
文摘The processing speed of the communication between nodes in a parallel processor has become the major bottleneck of the processor's performance.RDMA(Remote Direct Memory Access) technology has drawn more attention recently due to its capability of transferring a larger amount of data, higher speed and reliability.4DSP(4 Digital Signal Processing) module comprised of Tiger-SHARC201 chip is connected by LVDS(Low Voltage Differential Signal) circuits.This paper proposes a general and reconfigurable RDMA platform and its corresponding communication protocol with all the routes linked based on the zero copy.The protocol transfers message of DSP by interrupting of DMA and is applied on massive remote image impression, which reduces memory needs and working burden of CPU.The experiment results show this platform is efficient, flexible, and expandable of being integrated to a larger scale in the next development stages.
文摘Approaches to building renovation require high professional levels, interdisciplinary elements, team work and time to study and do research on the buildings. The process of renovating historic buildings is made up of agreements and compromises between the interests of the government, common interests, and the motives and interests of individual owners and prospective investors. Research that deals with any portion of cultural heritages always carried out very precisely, but there is still no precise knowledge of how to define a system and draw up a model that accurately represents a cultural heritage. In the existing literature on this topic, the authors have written about the different views of how to explain the construction project as a system. While many authors focus on "sub-phases" directly connected to the building of an object, the process involved in the construction phase often neglects the phases required before beginning work, which culminates in a logical sequence in the process of preparing a project. Irregularities or deficiencies which occur during the preparation process of a project often directly impact the construction itself. What the scope of this impact depends on the approach of the contractual organization, the organization of construction companies and on co-operation between the customer (or architects) and the contractors. Unlike the projects for newly built objects, the conservation projects of cultural heritage are not only more demanding because of lack of knowledge of the building materials, construction, foundation and interaction of the mentioned individual parts into a unit called a building. The authors analyzed the structural aspects of building conservation which were suggested by Beckmaun and Bowles and another methodology, which was developed as part of the 5th framework program for the purpose of providing a comprehensive and interdisciplinary treatment of the revitalization of a historical city. The authors found that both methodologies do not include modern IT tools and methods. By analyzing and monitoring the restoration of historic buildings in Slovenia, specifically in the city of Maribor (including all documentation, interviews and direct views) the authors found that the project was regarded as a collection of individual projects rather than a unified whole (a system). The authors have demonstrated the consequences of structuring a historic building restoration project in a non-systemic way. This type of project can be classified as a non-sustainable renovation. In this article, at first the authors will try to clarify what types of systems and subsystems are considered in renovating historic buildings. The authors show when and why a system becomes stochastic (a probability) and in the end what would be needed to successfully re-establish it back to a determined system. By analyzing the work and reconstruction of old buildings in Maribor, the authors found that it would be necessary to give a new framework with IT tools for the preparation of a historic building restoration project.
基金supported by the National Natural Science Foundation of China (21571123, 21571107, 21421001)the Natural Science Foundation of Tianjin (15JCZDJC37700)+1 种基金111 Project (B12015)MOE Innovation Team (IRT13022, IRT-13R30) of China
文摘A new 2D Eu-BTB framework(1) with stratified gridding structure of about 14.6×16.9was synthesized and characterized.Compound 1 displays excellent water stability with the pH 2–12. The luminescent investigations suggest that 1 could represent a chemical sensor of PO43. with high sensitivity and selectivity. Importantly, 1 as a sensor of PO_4^(3-) can be reused at least five times.On the other hand, the catalytic investigations of 1 were carried out, indicating that 1 could be demonstrated as a recyclable catalyst for CO_2 conversion with epoxides.
基金Supported by the Council of Scientific and Industrial Research(CSIR),in the Form of Research Project Grant No.03(1341)/15/EMR-Ⅱ and to DST,New DelhiINSPIRE-Fellowship Grant No.DST/INSPIRE/03/2015/000199
文摘Within the framework of the dynamical cluster decay model (DCM), the in evaporation cross-sections (σ1n) of cold fusion reactions (Pb and Bi targets) are calculated for ZCN = 104-113 superheavy nuclei. The calculations are carried out in the fixed range of excitation energy ECN = 15 ± 1 MeV, so that the comparative analysis of reaction dynamics can be worked out. First of all, the fission barriers (Bf ) and neutron separation energies (S1n) are estimated to account the decreasing cross-sections of cold fusion reactions. In addition to this, the importance of hot optimum orientations of β24-deformed nuclei over cold one is explored at fixed angular momentum and neck-length parameters. The hot optimum orientations support all the target-projectile (t,p) combinations, which are explored experimentally in the cold fusion reactions. Some new target-projectile combinations are also predicted for future exploration. Further, the In cross-sections are addressed for ZCN = 104-113 superheavy nuclei at comparable excitation energies which show the decent agrement with experimental data upto ZCN = 109 nuclei. Finally, to understand the dynamics of higher-Z superheavy nuclei, the cross-sections are also calculated at maximum available energies around the Coulomb barrier and the effect of non-sticking moment of inertia (INS) is also investigated at these energies.
基金supported by the National Natural Science Foundation of China(51877132,U19A20105,and 52003153)the Program of Shanghai Academic Research Leader(21XD1401600)。
文摘The long-term safe operation of high-power equipment and integrated electronic devices requires efficient thermal management,which in turn increases the energy consumption further.Hence,the sustainable development of our society needs advanced thermal management with low,even zero,energy consumption.Harvesting water from the atmosphere,followed by moisture desorption to dissipate heat,is an efficient and feasible approach for zero-energy-consumption thermal management.However,current methods are limited by the low absorbance of water,low water vapor transmission rate(WVTR)and low stability,thus resulting in low thermal management capability.In this study,we report an innovative electrospinning method to process hierarchically porous metal–organic framework(MOF)composite fabrics with high-efficiency and zero-energy-consumption thermal management.The composite fabrics are highly loaded with MOF(75 wt%)and their WVTR value can be up to 3138 g m^(-2) d^(-1).The composite fabrics also exhibit stable microstructure and performance.Under a conventional environment(30℃,60%relative humidity),the composite fabrics adsorb water vapor for regeneration within 1.5 h to a saturated value Wsat of 0.614 g g^(-1),and a corresponding equivalent enthalpy of 1705.6 J g^(-1).In the thermal management tests,the composite fabrics show a strong cooling capability and significantly improve the performance of thermoelectric devices,portable storage devices and wireless chargers.These results suggest that hierarchically porous MOF composite fabrics are highly promising for thermal management of intermittent-operation electronic devices.