The aim of the present work is to remove heavy metals （copper, manganese, and zinc） from industrial wastewater of Baiji refinery using GAC （granular activated carbon）. The most important factors affecting adsorpti...The aim of the present work is to remove heavy metals （copper, manganese, and zinc） from industrial wastewater of Baiji refinery using GAC （granular activated carbon）. The most important factors affecting adsorption process have been studied, which are granular activated carbon thickness, H, inlet pollutant concentration, Cv, and liquid hourly space velocity, LHSV. All experiments were performed under constant temperature at 25℃ and pH = 7. The experimental apparatus was designed and constructed to enable controlling of the operating conditions. Employing five levels for each of H and LHSV and three levels for Co required 75 runs for each metal. Box-Wilson method was used to reduce the number of experiments to 15 for each metal. The results indicated that copper, manganese, and zinc can be completely removed from wastewater using activated carbon. However, breakthrough time for zinc is low. It is also shown that breakthrough time （TB） and exhaustion time （TE） are inversely proportional with pollutant concentration and LHSV （liquid hour space velocity） while it is directly proportional with the thickness of activated carbon column.展开更多
The Niger Delta has experienced tons of crude oil spill within their environment over the years and its impact on the environment is quite lethal. The soil is a major recipient of this spilled crude. When contaminated...The Niger Delta has experienced tons of crude oil spill within their environment over the years and its impact on the environment is quite lethal. The soil is a major recipient of this spilled crude. When contaminated with crude oil, the load bearing capacity is consequently affected. This study aimed at providing a statistical evidence to prove that the impact of crude oil contamination on the soil＇s bearing capacity is significant. Four samples of uncontaminated soil of Kwale were collected and analyzed for their load bearing properties： cohesion （c）, angle of internal friction （θ°） and bulk density （γ）. These soil samples were polluted with crude oil in levels of 5%, 10%, 15% and 20% and compared with intact soil. A consistent reduction was observed in the bearing capacity as the crude oil level increased. Using the SPSS （statistically package for social sciences）, the significance was tested at the various contamination levels at a 5% confidence level and the result showed significance at 15% and 20% levels with calculated P-values of 0.038 and 0.035 respectively for both the square and strip foundation footings.展开更多
Twenty-two soil samples were collected at the subregional scale （50 km2） around Gudao Town, a typical oil-producing region of the Shengli Oilfield in the Yellow River Delta, China to determine the spatial distributi...Twenty-two soil samples were collected at the subregional scale （50 km2） around Gudao Town, a typical oil-producing region of the Shengli Oilfield in the Yellow River Delta, China to determine the spatial distribution patterns and potential sources of heavy metals in soils of crude oil-polluted regions. The concentrations of total petroleum hydrocaxbons （TPHs） and heavy metals as well as other soil properties were determined and the enrichment factor values were calculated for the heavy metals measured. Principal component analysis （PCA） and cluster analysis （CA） were used to estimate potential sources contributing to the concentrations of heavy metals in the soils. The results revealed that the soils were slightly alkaline （pH = 7.33-8.05） and high in salinity （1.43-41.30 g kg-1）, TPHs （0.51 28.40 g kg-1） and organic matter （1.74-31.50 g kg-1）. The mean concentrations of the measured heavy metals Cu, Zn, Pb, Cd, Cr, Ni and V were 18.4, 78.2, 20.8, 0.19, 56.6, 26.3 and 62.1 mg kg-1, respectively. Although the concentrations of all the metals measured in this study were not high enough to exceed the national control standards, there was a significant enrichment of Cd in the study area and Zn and Ni were in the category of deficiency to minimal enrichment. The spatial distribution patterns of Cu, Cr, Ni and V were similar and partially affected by oil exploitation and petroleum hydrocarbon spills. Potential sources of Cr, Ni, V and Cu in the soils were both natural sources and petroleum hydrocarbon spills, while Zn, Pb and Cd were probably from anthropogenic sources such as farming activities and traffic.展开更多
文摘The aim of the present work is to remove heavy metals （copper, manganese, and zinc） from industrial wastewater of Baiji refinery using GAC （granular activated carbon）. The most important factors affecting adsorption process have been studied, which are granular activated carbon thickness, H, inlet pollutant concentration, Cv, and liquid hourly space velocity, LHSV. All experiments were performed under constant temperature at 25℃ and pH = 7. The experimental apparatus was designed and constructed to enable controlling of the operating conditions. Employing five levels for each of H and LHSV and three levels for Co required 75 runs for each metal. Box-Wilson method was used to reduce the number of experiments to 15 for each metal. The results indicated that copper, manganese, and zinc can be completely removed from wastewater using activated carbon. However, breakthrough time for zinc is low. It is also shown that breakthrough time （TB） and exhaustion time （TE） are inversely proportional with pollutant concentration and LHSV （liquid hour space velocity） while it is directly proportional with the thickness of activated carbon column.
文摘The Niger Delta has experienced tons of crude oil spill within their environment over the years and its impact on the environment is quite lethal. The soil is a major recipient of this spilled crude. When contaminated with crude oil, the load bearing capacity is consequently affected. This study aimed at providing a statistical evidence to prove that the impact of crude oil contamination on the soil＇s bearing capacity is significant. Four samples of uncontaminated soil of Kwale were collected and analyzed for their load bearing properties： cohesion （c）, angle of internal friction （θ°） and bulk density （γ）. These soil samples were polluted with crude oil in levels of 5%, 10%, 15% and 20% and compared with intact soil. A consistent reduction was observed in the bearing capacity as the crude oil level increased. Using the SPSS （statistically package for social sciences）, the significance was tested at the various contamination levels at a 5% confidence level and the result showed significance at 15% and 20% levels with calculated P-values of 0.038 and 0.035 respectively for both the square and strip foundation footings.
基金Supported by the Environmental Protection Public Welfare Industry Research Program of China(No.201109022)
文摘Twenty-two soil samples were collected at the subregional scale （50 km2） around Gudao Town, a typical oil-producing region of the Shengli Oilfield in the Yellow River Delta, China to determine the spatial distribution patterns and potential sources of heavy metals in soils of crude oil-polluted regions. The concentrations of total petroleum hydrocaxbons （TPHs） and heavy metals as well as other soil properties were determined and the enrichment factor values were calculated for the heavy metals measured. Principal component analysis （PCA） and cluster analysis （CA） were used to estimate potential sources contributing to the concentrations of heavy metals in the soils. The results revealed that the soils were slightly alkaline （pH = 7.33-8.05） and high in salinity （1.43-41.30 g kg-1）, TPHs （0.51 28.40 g kg-1） and organic matter （1.74-31.50 g kg-1）. The mean concentrations of the measured heavy metals Cu, Zn, Pb, Cd, Cr, Ni and V were 18.4, 78.2, 20.8, 0.19, 56.6, 26.3 and 62.1 mg kg-1, respectively. Although the concentrations of all the metals measured in this study were not high enough to exceed the national control standards, there was a significant enrichment of Cd in the study area and Zn and Ni were in the category of deficiency to minimal enrichment. The spatial distribution patterns of Cu, Cr, Ni and V were similar and partially affected by oil exploitation and petroleum hydrocarbon spills. Potential sources of Cr, Ni, V and Cu in the soils were both natural sources and petroleum hydrocarbon spills, while Zn, Pb and Cd were probably from anthropogenic sources such as farming activities and traffic.
