The catalysts Ni/Al2O3, Ni/ZrO2-CeO2-Al2O3 and Ni/CuO-ZrO2-CeO2-Al2O3 were prepared by the co-precipitation method at a pH of 9 using Na2CO3 as the precipitant. The Ni loading(mass fraction) of the catalysts was 10%. ...The catalysts Ni/Al2O3, Ni/ZrO2-CeO2-Al2O3 and Ni/CuO-ZrO2-CeO2-Al2O3 were prepared by the co-precipitation method at a pH of 9 using Na2CO3 as the precipitant. The Ni loading(mass fraction) of the catalysts was 10%. The ignition process on the catalysts for the autothermal reforming of methane to hydrogen was investigated and the surface properties of the catalysts were characterized by XPS. The results showed that the Ni/Al2O3 catalyst could not ignite the process of autothermal reforming of methane to hydrogen. However, the Ni/CuO-ZrO2-CeO2-Al2O3 catalyst could ignite the process of autothermal reforming of methane to hydrogen at lower reaction temperature(650 ℃) with the conversion of methane reaching 76%. The result of XPS analysis indicated that the promoters could change the binding energy(BE) of Ni2p3/2 obviously. The species of Cu in the Ni/CuO-ZrO2-CeO2-Al2O3 catalyst comprised Cu2 O and Cu2+. The formation of ZrO2-CeO2 solid solution and a large amount of Cu2 O might be the reason leading to good oxygen storage capacity and mobility of lattice oxygen of the Ni/CuO-ZrO2-CeO2-Al2O3 catalyst, which could ignite the process of autothermal reforming of methane to hydrogen at lower reaction temperature.展开更多
This paper presents an analysis of the fire trends in southern European countries, where forest fires are a major hazard. Data on number of fires and burned area size from 1985 until 2009 were retrieved from the Europ...This paper presents an analysis of the fire trends in southern European countries, where forest fires are a major hazard. Data on number of fires and burned area size from 1985 until 2009 were retrieved from the European Fire Database in the European Forest Fire Information System and used to study the temporal and spatial variability of fire occurrence at three different spatial scales： the whole European Mediterranean region, country level and province level （NUTS3）. The temporal trends were assessed with the Mann-Kendall test and Sen＇s slope in the period 1985-2009. At regional （supranational） level, our results suggest a significant decreasing trend in the burned area for the whole study period. At country level, the trends vary by country, although there is a general increase in number of fires, mainly in Portugal, and a decrease in bumed areas, as is the case of Spain. A similar behavior was found at NUTS3 level, with an increase of number of fires in the Spanish and Portuguese provinces and a generalized decrease of the burned area in most provinces of the region. These results provide an important insight into the spatial distribution and temporal evolution of fires, a crucial step to investigate the underlying causes and impacts of fire occurrence in this region.展开更多
基金supported by the Guangdong Provincial Natural Science Foundation (030514)the Science and Technology Plan of Guangdong Province of China (2004B33401006)the Doctoral Startup Foundation of Guangdong Pharmaceutical University
文摘The catalysts Ni/Al2O3, Ni/ZrO2-CeO2-Al2O3 and Ni/CuO-ZrO2-CeO2-Al2O3 were prepared by the co-precipitation method at a pH of 9 using Na2CO3 as the precipitant. The Ni loading(mass fraction) of the catalysts was 10%. The ignition process on the catalysts for the autothermal reforming of methane to hydrogen was investigated and the surface properties of the catalysts were characterized by XPS. The results showed that the Ni/Al2O3 catalyst could not ignite the process of autothermal reforming of methane to hydrogen. However, the Ni/CuO-ZrO2-CeO2-Al2O3 catalyst could ignite the process of autothermal reforming of methane to hydrogen at lower reaction temperature(650 ℃) with the conversion of methane reaching 76%. The result of XPS analysis indicated that the promoters could change the binding energy(BE) of Ni2p3/2 obviously. The species of Cu in the Ni/CuO-ZrO2-CeO2-Al2O3 catalyst comprised Cu2 O and Cu2+. The formation of ZrO2-CeO2 solid solution and a large amount of Cu2 O might be the reason leading to good oxygen storage capacity and mobility of lattice oxygen of the Ni/CuO-ZrO2-CeO2-Al2O3 catalyst, which could ignite the process of autothermal reforming of methane to hydrogen at lower reaction temperature.
文摘This paper presents an analysis of the fire trends in southern European countries, where forest fires are a major hazard. Data on number of fires and burned area size from 1985 until 2009 were retrieved from the European Fire Database in the European Forest Fire Information System and used to study the temporal and spatial variability of fire occurrence at three different spatial scales： the whole European Mediterranean region, country level and province level （NUTS3）. The temporal trends were assessed with the Mann-Kendall test and Sen＇s slope in the period 1985-2009. At regional （supranational） level, our results suggest a significant decreasing trend in the burned area for the whole study period. At country level, the trends vary by country, although there is a general increase in number of fires, mainly in Portugal, and a decrease in bumed areas, as is the case of Spain. A similar behavior was found at NUTS3 level, with an increase of number of fires in the Spanish and Portuguese provinces and a generalized decrease of the burned area in most provinces of the region. These results provide an important insight into the spatial distribution and temporal evolution of fires, a crucial step to investigate the underlying causes and impacts of fire occurrence in this region.
