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烷基膦酸载体液膜中Cd(II)的传输 被引量:2
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作者 姚秉华 卞文娟 梁延荣 《中国环境科学》 EI CAS CSSCI CSCD 北大核心 2001年第6期511-514,共4页
采用内耦合大块液膜分离技术,通过考察料液相pH值、温度、载体浓度以及解析相组成对Cd(Ⅱ)迁移速率的影响,研究了以烷基膦酸为流动载体的液膜中镉的迁移规律,并建立了渗透系数与pH值、温度以及载体浓度之间的关系方程。结果表明,Cd... 采用内耦合大块液膜分离技术,通过考察料液相pH值、温度、载体浓度以及解析相组成对Cd(Ⅱ)迁移速率的影响,研究了以烷基膦酸为流动载体的液膜中镉的迁移规律,并建立了渗透系数与pH值、温度以及载体浓度之间的关系方程。结果表明,Cd(Ⅱ)以CdR2·2HR(Kex值为3.58×10^6)配合物形式在液膜中传输,增加载体浓度或升高温度,迁移速率明显升高,最佳传质条件为料液相pH值4.5-5.1、载体浓度5.0%-7.5%、温度298-308K。 展开更多
关键词 液膜分离 支撑体液膜 烷基膦酸 载体液膜 重金属传输 含镉废水 废水处理
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Characteristics of Heavy Metal Circulation in Biosphere
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作者 Dewu ZENG Kailin ZHU Xiaodong PEI 《Agricultural Science & Technology》 CAS 2014年第4期642-647,共6页
In order to control heavy metal pollution effectively, this paper reviews heavy metal source and transport characteristics in heavy metal circulation in bio- sphere, including geochemical cycle and biological cycle of... In order to control heavy metal pollution effectively, this paper reviews heavy metal source and transport characteristics in heavy metal circulation in bio- sphere, including geochemical cycle and biological cycle of heavy metals. The inter- body of geochemical cycle of heavy metals includes soil, gas as well as water body, and the interbody of biological cycle of heavy metals includes environment, plant, microorganisms and animals. As to macro-cycle, transportation character in each interbody is different. Heavy metal circulation in different interbody interacts with each other and is in dynamic balance. Heavy metals in soil include two parts, i.e. active and inert forms, which are in dynamic equilibrium. This equilibrium may be affected by different physicochemical factors. Heavy metal content at different soil depth reflects historical accumulation level of heavy metal. In contrast to agri- cultural eco-system itself, industrial and urban activities are of great menace. Fluvial transport and atmospheric input are significant pathways of heavy metal circulation. Sludge plays an accumulative role of heavy metals, and can release its heavy met- als to water body causing secondary pollution. Balance of heavy metal immobiliza- tion and release is interrupted by physicochemical characters and microbial activity. Temperature can influence atmospheric heavy metal content, and volatile heavy meal precipitation is an indLspensable source in soil and water body. In regard to micro-cycle, plants is the main part in heavy metal cycle, microorganisms play roles in accelerator and animals in recipient. Specific transportation and assigned location of heavy metal in plants are adopted to keep internal heavy metal equilibrium. 展开更多
关键词 Heavy metal Geochemical cycle Biological cycle Transport process
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