The sodium expansion curves of semi-graphitic cathode measured with the improved Rapoport-Samoilenko apparatus. The and TiB2/C composite cathode with different TiB2 contents were mathematic model of the sodium expansi...The sodium expansion curves of semi-graphitic cathode measured with the improved Rapoport-Samoilenko apparatus. The and TiB2/C composite cathode with different TiB2 contents were mathematic model of the sodium expansion was deduced on the basis of the experimental results. The sodium expansion parameter （a） and penetration rate factor （Q）, were introduced into the model The model was validated with the experimental sodium expansion curves self-measured and reported. The results show that the variation tendency of the sodium expansion parameter （a） and penetration rate factor （Q） is consistent with that of the experimental curves. The model is capable of not only conveniently judging the cathode quality, but also favorably establishing a unified standard of the resistance to sodium penetration of cathode.展开更多
Development and sustainability are the core connotation of sustainable development. Sustainability of economic development and the provision capability of resources and environment are two aspects of sustainable devel...Development and sustainability are the core connotation of sustainable development. Sustainability of economic development and the provision capability of resources and environment are two aspects of sustainable development. The former ones are the foundation of the latter ones. Industrial structure has a close relationship with sustainable development. The optimization of industrial structure is the important base for the sustainable development of modern economy and also the important ways of the sustainable utilization of resources and environment. The intensive growth effect of industrial structure change has the meaning of sustainable development. This paper reviews and explains the theory on the contribution of industrial structure change to sustainable development, builds the calculation model through introducing the coeff icient of industrial structure change, makes an empirical study on the contribution of industrial structure change to sustainable development in Fujian, and puts forward ways and policies of optimizing industrial structure both among industries and inside the industry in the process of industrial structure change.展开更多
The ethoxycarbonyl isothiocyanate has been investigated by using supersonic jet Fourier transform microwave spectroscopy.Two sets of rotational spectra belonging to conformers TCC(with the backbone of C-C-O-C,C-O-C=O,...The ethoxycarbonyl isothiocyanate has been investigated by using supersonic jet Fourier transform microwave spectroscopy.Two sets of rotational spectra belonging to conformers TCC(with the backbone of C-C-O-C,C-O-C=O,and O-C(=O)-NCS being trans,cis,and cis arranged,respectively)and GCC(gauche,cis,and cis arrangement of the C-C-O-C,C-O-C=O,and O-C(=O)-NCS)have been measured and assigned.The measurements of13C,15N and34S mono-substituted species of the two conformers have also been performed.The comprehensive rotational spectroscopic investigations provide accurate values of rotational constants and14N quadrupole coupling constants,which lead to structural determinations of the two conformers of ethoxycarbonyl isothiocyanate.For conformer TCC,the values of Pcckeep constant upon isotopic substitution,indicating that the heavy atoms of TCC are effectively located in the ab plane.展开更多
Weathered clastic crust can be subdivided into weathered clay and leached zone in terms of variable weathering of different minerals and mobility of weathered products.On the basis of clastic outcrops and well cores i...Weathered clastic crust can be subdivided into weathered clay and leached zone in terms of variable weathering of different minerals and mobility of weathered products.On the basis of clastic outcrops and well cores in the Junggar Basin,the dark red Fe-rich weathered clay is formed in an arid environment,whereas the light blue Al-rich weathered clay under humid conditions.According to the geochemical analysis,a new weathering index for weathered clastic crust is built mainly on Fe and Al contents,accurately indicating the weathered clay,sandy leached zone,and muddy leached zone in the Junggar Basin.The breaking pressure of weathered clay is rather large,the same as that of normal muddy cap,effectively to seal oil or gas.The porosity of underlying leached zone is greatly enhanced by weathering and leaching,but its permeability is a function of clay mineral content,i.e.,the higher the clay content,the worse the permeability.Weathered crust provides effective sealing conditions for both top and bottom layers of a petroleum reservoir,and is important in the clastic hydrocarbon exploration.展开更多
A novel pseudo rubrene analogue,6,11-di(thiophen-2-yl)-tetracene-5,12-dione (DTTDO) was synthesized,in which two thienyl groups and two carbonyl groups replacing four phenyl groups in the rubrene molecule were connect...A novel pseudo rubrene analogue,6,11-di(thiophen-2-yl)-tetracene-5,12-dione (DTTDO) was synthesized,in which two thienyl groups and two carbonyl groups replacing four phenyl groups in the rubrene molecule were connected to the backbone of tetracene.This compound was characterized by single crystal X-ray structure analysis,thermogravimetric analysis,absorption spectra and electrochemical measurements.Unlike rubrene,DTTDO exhibited excellent film forming ability by normal vacuum deposition,indicating its promising applications in organic thin film transistors.展开更多
基金Project(2005CB623703) supported by the Major State Basic Research and Development Program of ChinaProject(2008AA030502) supported by the National High-Tech Research and Development Program of ChinaProject(GUIKEJI0639032) supported by the Science Fund Project of Guangxi Province, China
文摘The sodium expansion curves of semi-graphitic cathode measured with the improved Rapoport-Samoilenko apparatus. The and TiB2/C composite cathode with different TiB2 contents were mathematic model of the sodium expansion was deduced on the basis of the experimental results. The sodium expansion parameter （a） and penetration rate factor （Q）, were introduced into the model The model was validated with the experimental sodium expansion curves self-measured and reported. The results show that the variation tendency of the sodium expansion parameter （a） and penetration rate factor （Q） is consistent with that of the experimental curves. The model is capable of not only conveniently judging the cathode quality, but also favorably establishing a unified standard of the resistance to sodium penetration of cathode.
文摘Development and sustainability are the core connotation of sustainable development. Sustainability of economic development and the provision capability of resources and environment are two aspects of sustainable development. The former ones are the foundation of the latter ones. Industrial structure has a close relationship with sustainable development. The optimization of industrial structure is the important base for the sustainable development of modern economy and also the important ways of the sustainable utilization of resources and environment. The intensive growth effect of industrial structure change has the meaning of sustainable development. This paper reviews and explains the theory on the contribution of industrial structure change to sustainable development, builds the calculation model through introducing the coeff icient of industrial structure change, makes an empirical study on the contribution of industrial structure change to sustainable development in Fujian, and puts forward ways and policies of optimizing industrial structure both among industries and inside the industry in the process of industrial structure change.
基金The support from the National Natural Science Foundation of China(No.22273009)Chongqing University。
文摘The ethoxycarbonyl isothiocyanate has been investigated by using supersonic jet Fourier transform microwave spectroscopy.Two sets of rotational spectra belonging to conformers TCC(with the backbone of C-C-O-C,C-O-C=O,and O-C(=O)-NCS being trans,cis,and cis arranged,respectively)and GCC(gauche,cis,and cis arrangement of the C-C-O-C,C-O-C=O,and O-C(=O)-NCS)have been measured and assigned.The measurements of13C,15N and34S mono-substituted species of the two conformers have also been performed.The comprehensive rotational spectroscopic investigations provide accurate values of rotational constants and14N quadrupole coupling constants,which lead to structural determinations of the two conformers of ethoxycarbonyl isothiocyanate.For conformer TCC,the values of Pcckeep constant upon isotopic substitution,indicating that the heavy atoms of TCC are effectively located in the ab plane.
基金supported by National Science and Technology Major Projects(Grant No.2011ZX05001-003)
文摘Weathered clastic crust can be subdivided into weathered clay and leached zone in terms of variable weathering of different minerals and mobility of weathered products.On the basis of clastic outcrops and well cores in the Junggar Basin,the dark red Fe-rich weathered clay is formed in an arid environment,whereas the light blue Al-rich weathered clay under humid conditions.According to the geochemical analysis,a new weathering index for weathered clastic crust is built mainly on Fe and Al contents,accurately indicating the weathered clay,sandy leached zone,and muddy leached zone in the Junggar Basin.The breaking pressure of weathered clay is rather large,the same as that of normal muddy cap,effectively to seal oil or gas.The porosity of underlying leached zone is greatly enhanced by weathering and leaching,but its permeability is a function of clay mineral content,i.e.,the higher the clay content,the worse the permeability.Weathered crust provides effective sealing conditions for both top and bottom layers of a petroleum reservoir,and is important in the clastic hydrocarbon exploration.
基金support of the National Natural Science Foundation of China (60771031,60736004,20571079,20721061 and 50725311)National Basic Research Program of China (973 Program,2006CB806200 & 2006CB932100)Chinese Academy of Sciences
文摘A novel pseudo rubrene analogue,6,11-di(thiophen-2-yl)-tetracene-5,12-dione (DTTDO) was synthesized,in which two thienyl groups and two carbonyl groups replacing four phenyl groups in the rubrene molecule were connected to the backbone of tetracene.This compound was characterized by single crystal X-ray structure analysis,thermogravimetric analysis,absorption spectra and electrochemical measurements.Unlike rubrene,DTTDO exhibited excellent film forming ability by normal vacuum deposition,indicating its promising applications in organic thin film transistors.
