电力量子计量技术的进展与趋势

现有的电力基标准均是基于电磁原理,受限于原理和测量技术,继续提升准确度水平已接近物理极限。相较于传统电力基标准,量子计量与传感将物理量溯源至基本物理常数,具有准确度高、复现不受客观条件制约等显著优点,近年来得到了很快的发展。因此,围绕电力计量主要的参量,包括电流、电压、电能及时间4个方面,比较了基于单电子隧道效应和粒子加速器的两种量子电流技术的发展趋势,介绍了基于量子精密磁测量的新型电流传感技术以及电流量子比例技术;总结了交直流量子电压装置的发展,以及在电压比例溯源和电能的溯源应用,可有效提升现有的电压/电能的溯源水平;总结了时间频率计量技术的整体进展和趋势,以国家电网计量中心建立的国家电网时间频率体系架构和应用为例,介绍了量子时间的应用形态。目前电力量子计量技术取得了突破性的发展,电力与量子的融合研究刚刚起步,研究潜力很大,值得重点关注和深入研究。

Highly Sensitive Photodetectors Based on WS_(2)Quantum Dots/GaAs Heterostructures

The performance of the photodetector is significantly impacted by the inherent surface faults in GaAs nanowires(NWs).We combined three-dimensional(3D)gallium arsenide nanowires with zero-dimensional(0D)WS_(2)quantum dot(QDs)materials in a simple and convenient way to form a heterogeneous structure.Various performance enhancements have been realized through the formation of typeⅡenergy bands in heterostructures,opening up new research directions for the future development of photodetector devices.This work successfully fabricated a high-sensitivity photodetector based on WS_(2)QDs/GaAs NWs heterostructure.Under 660 nm laser excitation,the photodetector exhibits a responsivity of 368.07 A/W,a detectivity of 2.7×10^(12)Jones,an external quantum efficiency of 6.47×10^(2)%,a low-noise equivalent power of 2.27×10^(-17)W·Hz-1/2,a response time of 0.3 s,and a recovery time of 2.12 s.This study provides a new solution for the preparation of high-performance GaAs detectors and promotes the development of optoelectronic devices for GaAs NWs.

Beryllium-distribution in metallic glass matrix composite containing beryllium

The morphologies, sizes, compositions and volume fractions of dendritic phases in in situ Ti-based metallic glass matrix composites （MGMCs） containing beryllium （Be） with the nominal composition of Tia7Zr19Cu5V12Be17 （mole fraction, %） were investigated using XRD, SEM, EBSD, TEM, EDS and three-dimensional reconstruction method. Moreover, visualized at the nanoscale, Be distribution is confirmed to be only present in the matrix using scanning transmission electron microscopy-electron energy loss spectroscopy （STEM-EELS）. Based on these findings, it has been obtained that the accurate chemical compositions are Wi28.3Zr19.7Cu8V6.4Be37.6 （mole fraction, %） for glass matrix and Wi62.nZr18.aCu2.6V16.6 （mole fraction, %） for the dendritic phases, and the volume fractions are 38.5% and 61.5%, respectively. It is believed that the results are of particular importance for the designing of Be-containing MGMCs.

Bound Polaron in a Quantum Well Under an Electric Field

We conduct a theoretical study on the properties of a bound polaron in a quantum well under an electric field using linear combination operator and unitary transformation methods, which are valid in the whole range of electron-LO phonon coupling. The changing relations between the ground-state energy of the bound polaron in the quantum well and the Coulomb bound potential, the electric field strength, and the well width are derived. The numerical results show that the ground-state energy increases with the increase of the electric field strength and the Coulomb bound potential and decreases as the well width increases.

Effect of Surface Potential Barrier on the Electron Energy Distribution of NEA Photocathodes

By calculating the energy distribution of electrons reaching the photocathode surface and solving the Schrodinger equation that describes the behavior of an electron tunneling through the surface potential barrier,we obtain an equation to calculate the emitted electron energy distribution of transmission-mode NEA GaAs photocathodes. Accord- ing to the equation,we study the effect of cathode surface potential barrier on the electron energy distribution and find a significant effect of the barrier-Ⅰ thickness or end height,especially the thickness,on the quantum efficiency of the cath- ode. Barrier Ⅱ has an effect on the electron energy spread, and an increase in the vacuum level will lead to a narrower electron energy spread while sacrificing a certain amount of cathode quantum efficiency. The equation is also used to fit the measured electron energy distribution curve of the transmission-mode cathode and the parameters of the surface barri- er are obtained from the fitting. The theoretical curve is in good agreement with the experimental curve.

Comparative Investigation of Mo（CO）6 Adsorption on Clean and OxidiZed Si（111） Surfaces

Mo（CO）6 adsorption on the clean, oxygen-precovered and deeply oxidized Si（lll） surfaces was comparatively investigated by high-resolution electron energy loss spectroscopy. The downward vibrational frequency shift of the C-O stretching mode in adsorbed Mo（CO）6 illustrates that different interactions of adsorbed Mo（CO）6 occur on clean Si（111） and SiO2/Si（111） surfaces, weak on the former and strong on the latter. The strong interaction on SiO2/Si（111） might lead to the partial dissociation of Mo（CO）6, consequently the formation of molybdenum subcarbonyls. Therefore, employing Mo（CO）6 as the precursor, metallic molybdenum could be successfully deposited on the SiO2/Si（111） surface but not on the clean Si（111） surface. A portion of the deposited metallic molybdenum is transformed into the MoOa on the SiO2/Si（111） surface upon heating, and the evolved MoO3 finally desorbs from the substrate upon annealing at elevated temperatures.

Collisional Line Assignments and Hyperfine Structure Interpretation in Cs22^3△1g State

Accurately known energy level structure of the A＇∑u＋b3 IIu complex of states from a recent global de-perturbation of these states has enabled additional assignments of 140 perturbation facilitated infrared-infrared double resonance （PFIIDR） transitions to the 2^3△1g state from collisionally populated intermediate 1 ＋ A Eu levels. Together with the 221 previously observed 2^3△1g←A1∑u＋←X1∑g＋ Eu X Eg double resonance lines [J. Chem. Phys. 128, 204313 （2008）], molecular constants and the Rydberg-Klein-Rees potential energy curve of the 23△1g state have been recalculated （excluding 54 perturbed levels）. The centrifugal distortion constant has been determined and agrees well with the value calculated based on standard empirical formulas. The hyperfine structure of the 23△1g state, which has not resolved in our sub-Doppler excitation spectra of the 23△1g state, has been interpreted with a preliminary simulation.

多天线频谱共享CR-NOMA系统安全中断性能分析

认知无线电(CR)非正交多址接入(NOMA)网络(记为CR-NOMA)已是无线通信领域的研究热点之一。由于无线信道的开放性,使得无线网络的安全通信成为当前急需解决的问题。该文研究了频谱共享多天线CR-NOMA网络安全中断性能,首先分析了最优天线选择(OAS)方案的安全中断概率(SOP),并推导了其精确的闭合表达式。其次,分析了空时传输(STT)方案的SOP,并推导了其精确的闭合表达式。最后,对次用户两种方案的SOP渐近性能进行了分析,揭示了系统参数对SOP的影响。最后,采用Monte Carlo仿真验证了理论分析的正确性。研究发现,两种方案基站分别存在一个最优峰值发射功率,使得远距离次用户的安全中断性能最佳。仿真结果表明增大基站峰值发射功率,OAS方案的近距离次用户的SOP会始终优于STT方案,远距离次用户的SOP会劣于STT方案。

Two—Electron Energy Spectrum in a Parabolic Quantum Dot Under a Magnetic Field

Two interacting electrons in a harmonic oscillator potential under the influence of a perpendicular homo-geneous magnetic field are considered. The energies of two-electron quantum dots with the electron-LO-phonon couplingas a function of magnetic field are calculated. Calculations are made by using the method of few-body physics withinthe effective-mass approximation. Our results show that the electron-LO-phonon coupling effect is very important insemiconductor quantum dots.

Near Resonant Electronic and Rotational Energy Transfer AB（^1∏, J）＋C（^slj）→AB（^1∏, J＇）＋C（^sl j＇）

In our previous theoretical study, the theoretical model of thecollision-induced electronic and rotational energy transfer of AB(~1Σ, J) + C(~sl_j) → AB(~1Σ,J′) + C(~sl_(j′)) was presented. To further study the collision-induced electronic and rotationalenergy transfer theoretically on AB( ~1Π, J) + C(~sl_j) → AB( ~1Π, J′) + C(~sl_(j′)), atheoretical model is presented, based on the time-dependent first-order Born approximation, takinginto account the anisotropic Lennard-Jones interaction potential and 'straight-line' trajectoryapproximation. The changing tendency of the transitional probabilities with the anisotropicparameter is discussed.

Improving effect of carbonized quantum dots(CQDs)in pure copper matrix composites

Carbon quantum dots(CQDs),which contain a core structure composed of sp^(2)carbon,can be used as the reinforcing phase like graphene and carbon nanotubes in metal matrix.In this paper,the CQD/Cu composite material was prepared by powder metallurgy method.The composite powder was prepared by molecular blending method and ball milling method at first,and then densified into bulk material by spark plasma sintering(SPS).X-ray diffraction,Raman spectroscopy,infrared spectroscopy,and nuclear magnetic resonance were employed to characterize the CQD synthesized under different temperature conditions,and then CQDs with a higher degree of sp^(2)were utilized as the reinforcement to prepare composite materials with different contents.Mechanical properties and electrical conductivity results show that the tensile strength of the 0.2 CQD/Cu composite material is~31%higher than that of the pure copper sample,and the conductivity of 0.4 CQD/Cu is~96%IACS,which is as high as pure copper.TEM and HRTEM results show that good interface bonding of CQD and copper grain is the key to maintaining high mechanical and electrical conductivity.This research provides an important foundation and direction for new carbon materials reinforced metal matrix composites.

Mechanism for capacity fading of 18650 cylindrical lithium ion batteries

The mechanism for capacity fading of18650lithium ion full cells under room-temperature(RT)is discussedsystematically.The capacity loss of18650cells is about12.91%after500cycles.The cells after cycles are analyzed by XRD,SEM,EIS and CV.Impedance measurement shows an overall increase in the cell resistance upon cycling.Moreover,it also presents anincreased charge-transfer resistance(Rct)for the cell cycled at RT.CV test shows that the reversibility of lithium ioninsertion/extraction reaction is reduced.The capacity fading for the cells cycled can be explained by taking into account the repeatedfilm formation over the surface of anode and the side reactions.The products of side reactions deposited on separator are able toreduce the porosity of separator.As a result,the migration resistance of lithium ion between the cathode and anode would beincreased,leading the fading of capacity and potential.

Photodetachment of H^- Near a Dielectric Surface

Using the closed orbit theory, the photodetachment cross section of H- near a dielectric surface has been derived and calculated. The results show that the dielectric surface has great influence on the photodetachment process of negative ion near the ionization threshold. Above the ionization threshold, the photodetachment cross section starts to oscillate. With the increase of the energy, the oscillating amplitude decreases and the oscillating frequency increases. The oscillation in the photodetachment cross section of H- in the presence of a dielectric surface is either larger or smaller than the photodetachment of H- without the surface. As the photon energy is larger than the critical value Epc, the oscillatory structure disappeared and the cross section approaches to the case of the photodetachment of H- without any external fields. For a given detached-electron energy, the photodetachment cross section becomes decreased with the increase of the ion-surface distance. Besides, the dielectric constant has great influence on the photodetachment of H-. With the increase of the dielectric constant, the oscillation in the cross section becomes increased. As the dielectric constant increases to infinity, the cross section is the same as the photodetachment of H- near a metal surface. This study provides a new understanding on the photodetachment process of H- in the presence of a dielectric surface.

Direct View of Cr Atoms Doped in Anatase TiO2（001） Thin Film

Imaging the doping elements is doped TiO2 thin film. But it is critical for understanding the photocatalytic activity of still a challenge to characterize the interactions between the dopants and the TiO2 lattice at the atomic level. Here, we use high angle annular dark- field/annular bright-field scanning transmission electron microscope （HAADF/ABF-STEM） combined with electron energy loss spectroscopy （EELS） to directly image the individual Cr atoms doped in anatase TiO2（001） thin film from [100] direction. The Cr dopants, which are clearly imaged through the atomic-resolution EELS mappings while can not be seen by HADDF/ABF-STEM, occupy both the substitutional sites of Ti atoms and the interstitial sites of TiO2 matrix. Most of them preferentially locate at the substitutional sites of Ti atoms. These results provide the direct evidence for the doping structure of Cr-doped A- TiO2 thin film at the atomic level and also prove the EELS mapping is an excellent technique for characterizing the doped materials.

Defects Energetics and Electronic Properties of Li Doped ZnO： A Hybrid Hartree-Fock and Density Functional Study

The electronic properties and stability of Li-doped ZnO with various defects have been stud- ied by calculating the electronic structures and defect formation energies via first-principles calculations using hybrid Hartree-Fock and density functional methods. The results from formation energy calculations show that Li pair complexes have the lowest formation energy in most circumstances and they consume most of the Li content in Li doped ZnO, which make the p-type conductance hard to obtain. The formation of Li pair complexes is the main obstacle to realize p-type conductance in Li doped ZnO. However, the formation energy of Lizn decreases as environment changes from Zn-rich to O-rich and becomes more stable than that of Li-pair complexes at highly O-rich environment. Therefore, p-type conductance can be obtained by Li doped ZnO grown or post annealed in oxygen rich atmosphere.

Ultrasonic power features of wire bonding and thermosonic flip chip bonding in microelectronics packaging

The driving voltage and current signals of piezoceramic transducer (PZT) were measured directly by designing circuits from ultrasonic generator and using a data acquisition software system. The input impedance and power of PZT were investigated by using root mean square (RMS) calculation. The vibration driven by high frequency was tested by laser Doppler vibrometer (PSV-400-M2). And the thermosonic bonding features were observed by scanning electron microscope (JSM-6360LV). The results show that the input power of bonding is lower than that of no load. The input impedance of bonding is greater than that of no load. Nonlinear phase, plastic flow and expansion period, and strengthening bonding process are shown in the impedance and power curves. The ultrasonic power is in direct proportion to the vibration displacement driven by the power, and greater displacements driven by high power (>5 W) result in welding failure phenomena, such as crack, break, and peeling off in wedge bonding. For thermosonic flip chip bonding, the high power decreases position precision of bonding or results in slippage and rotation phenomena of bumps. To improve reliability and precision of thermosonic bonding, the low ultrasonic power (about 1-5 W) should be chosen.

Anomalous Optical and Electronic Properties of CaTiO3 Perovskites

With the help of the first-prlnciples full potential linearized augmented plane wave method, absorption coefficients, reflect/vity, dielectric behavior and electronic properties, including electronic energy bands, density of states and charge density distributions, are studied for the tetragonal and cubic CaTiO3. By considering the thermal expansion effects, an approximate method is proposed for the study of the stability of ground state and a tendency of phase transition, based on the minimum free energy principle. Subsequently, numerical calculations are carried out by using the first-principles perturbation method. We demonstrate that the high-temperature phase is cubic. It is shown that optical spectra in tetragonal phase exhibit single-peak feature and differ from multi-peak character in cubic. We find that strong orbital hybridization results in the co-valent bonds between Ti 3d and O 2p electrons and forms two-type dipoles （Ti-Ol and Ti-02） in tetragonal, while the Ti-O dipoles are identical in cubic. It is argued that crystal structure determines the dipole distributions and leads to some electron states among which the dipole-dipole transit/on forbidden is a key, causing such anomalous optical phenomena with the insulator characteristics. The predicted charge density distribution and the tendency of phase transition from tetragonal to cubic are in good agreement with experimental observations.

Electron Acceleration and Bunch Generation by Intense Femtosecond Laser Pulse in Preplasma of a Target

We present analytical studies of electron acceleration in the low-density preplasma of a thin solid target byan intense femtosecond laser pulse.Electrons in the preplasma are trapped and accelerated by the ponderomotive forceas well as the wake field.Two-dimensional particle-in-cell simulations show that when the laser pulse is stopped by thetarget,electrons trapped in the laser pules can be extracted and move forward inertially.The energetic electron bunchin the bubble is unaffected by the reflected pulse and passes through the target with small energy spread and emittance.There is an optimal preplasma density for the generation of the monoenergetic electron bunch if a laser pulse is given.The maximum electron energy is inverse proportion to the preplasma density.

Supersymmetry for Fermion Masses

It is proposed that supersymmetry （SUSY） may be used to understand fermion mass hierarchies. A family symmetry ZSL is introduced, which is the cyclic symmetry among the three generation SU（2） doublets. SUSY breaks at a high energy scale - 10^11 GeV. The electroweak energy scale- 100 GeV is unnaturally small No additional global symmetry, like the R-parlty, is imposed. The Yukawa couplings and R-parity violating couplings all take their natural values, which are О（10^0 -10^-2）. Under the family symmetry, only the third generation charged ferrnions get their masses. This family symmetry is broken in the soft SUSY breaking terms, which result in a hierarchical pattern of the fermion masses. It turns out that for the charged leptons, the r mass is from the Higgs vacuum expectation value （VEV） and the sneutrino VEVs, the muon mass is due to the sneutrino VEVs, and the electron gains its mass due to both ZZL and SUSY hreaking. The large neutrino mixing are produced with neutralinos playing the partial role of right-handed neutrinos. │Ve3│, which is for Ve-Vr mixing, is expected to be about 0.1. For the quarks, the third generation masses are from the Higgs VEVs, the second generation masses are from quantum corrections, and the down quark mass due to the sneutrino VEVs. It explains me/ms, ms/me, md 〉 mu and so on. Other aspects of the model are discussed.

Analysis of Do D inkjet printhead performance for printable electronics fabrication using dynamic lumped element modeling and swarm intelligence based optimal prediction

The major challenge in printable electronics fabrication is to effectively and accurately control a drop-on-demand(Do D) inkjet printhead for high printing quality. In this work, an optimal prediction model, constructed with the lumped element modeling(LEM) and the artificial bee colony(ABC) algorithm, was proposed to efficiently predict the combination of waveform parameters for obtaining the desired droplet properties. For acquiring higher simulation accuracy, a modified dynamic lumped element model(DLEM) was proposed with time-varying equivalent circuits, which can characterize the nonlinear behaviors of piezoelectric printhead. The proposed method was then applied to investigate the influences of various waveform parameters on droplet volume and velocity of nano-silver ink, and to predict the printing quality using nano-silver ink. Experimental results show that, compared with two-dimension manual search, the proposed optimal prediction model perform efficiently and accurately in searching the appropriate combination of waveform parameters for printable electronics fabrication.