应用多尺度微扰理论研究了弱耦合非简谐参数的经典和量子四次非谐振子,得到了四次非简谐运动方程的经典和量子二阶解.此解与以前同类问题的多尺度微扰解不同,在H e isenberg表象中坐标和动量算符的对易关系的简化十分自然,并且量子解能...应用多尺度微扰理论研究了弱耦合非简谐参数的经典和量子四次非谐振子,得到了四次非简谐运动方程的经典和量子二阶解.此解与以前同类问题的多尺度微扰解不同,在H e isenberg表象中坐标和动量算符的对易关系的简化十分自然,并且量子解能十分方便地过渡到经典解.展开更多
The electrokinetic behavior and surface dissolution of serpentine mineral were studied through Zeta potential measurements, dissolution experiments and X-ray photoelectron spectroscopy. The results show that serpentin...The electrokinetic behavior and surface dissolution of serpentine mineral were studied through Zeta potential measurements, dissolution experiments and X-ray photoelectron spectroscopy. The results show that serpentine has an iso-electric point （IEP） of 11.9, which is higher than that of other phyllosilicate minerals. Dissolution experiments show that the hydroxyl is easy to dissolve with respect to the magnesium cations in the magnesium oxide octahedral sheet. As a result of hydroxyl dissolution, the magnesium ions are left on serpentine surface, which is responsible for serpentine surface charge. The removal of magnesium ions from serpentine surface by acid leaching results in a decrease of serpentine IEP. Therefore, it has been clearly established that the surface charge developed at the serpentine/aqueous electrical interface is a function of the serpentine surface incongruent dissolution.展开更多
Theoretical correspondence between classical instability and local solutions of the Schroedinger equation is discussed for Wannier's ionization threshold law.
Due to the negligible non-perturbation effect in the low-energy region, quantum chromodynamics （QCD） is limited to be applied to hadron problems in particle physics. However, QED has mature non-perturbation models w...Due to the negligible non-perturbation effect in the low-energy region, quantum chromodynamics （QCD） is limited to be applied to hadron problems in particle physics. However, QED has mature non-perturbation models which can be applied to Fermi acting-energy between quark and gluon. This paper applies quantum electrodynamics in 2 ＋ 1 dimensions （QED3） to the Fermi condensation problems. First, the Dyson-Schwinger equation which the fermions satisfy is constructed, and then the Fermi energy gap is solved. Theoretical calculations show that within the chirality limit, there exist three solutions for the energy gap; beyond the chirality limit, there are two solutions; all these solutions correspond to different fermion condensates. It can be concluded that the fermion condensates within the chirality limit can be used to analyze the existence of antiferromagnetic, pseudogap, and superconducting phases, and two fermion condensates are discovered beyond the chirality limit.展开更多
[Objective] The aim of this work was to identify molecular weight （MW） distribution and antioxidant activity of fish skin col agen hydrolysates. [Method] The MW distribution of hydrolysates was determined using both...[Objective] The aim of this work was to identify molecular weight （MW） distribution and antioxidant activity of fish skin col agen hydrolysates. [Method] The MW distribution of hydrolysates was determined using both size exclusion chromatography and matrix-assisted laser desorption ionization time-of-flight mass spec-trometry （MALDI-TOF-MS）. Fish skin were treated by the alkaline protease 2709. [Result] The optional conditions for hyerolysis were time 3 h, temperature 55 ℃, pH 10.0, substrate concentration 80 g/L and E/S 4%. The results of both methods indi-cated that the molecular weight of col agen hydrolysates was from 400 to 1 800 Da, and the peptides’ molecular weight was less than 1 400 Da mostly. The reducing power and antioxidant/radical scavenging activity [1, 1-diphenyl-2-picryl-hydrazyl （DPPH） free radical scavenging activity] were determined. [Conclusion] The results reveal that the fishskin hydrolysate is a potential source of antioxidants.展开更多
The photoionization and dissociation photoionization of toluene have been studied using quantum chemistry methods. The geometries and frequencies of the reactants, transition states and products have been performed at...The photoionization and dissociation photoionization of toluene have been studied using quantum chemistry methods. The geometries and frequencies of the reactants, transition states and products have been performed at B3LYP/6-311＋＋G（d,p） level, and single-point energy calculations for all the stationary points were carried out at DFT calculations of the optimized structures with the G3B3 level. The ionization energies of toluene and the ap- pearance energies for major fragment ions, C7H7＋, C6H5＋, C5H6＋, C5H5＋, are determined to be 8.90, 11.15 or 11.03, 12.72, 13.69, 16.28 eV, respectively, which are all in good agree- ment with published experimental data. With the help of available published experimental data and theoretical results, four dissociative photoionization channels have been proposed： CTHT＋＋H, C6Hs＋＋CH3, C5H6＋WC2H2, CsHs＋＋C2H2＋H. Transition structures and intermediates for those isomerization processes are determined in this work. Especially, the structures of C5H6＋ and C5H5＋ produced by dissociative photoionization of toluene have been defined as chain structure in this work with theoretical calculations.展开更多
The analytical solutions to 1D Schrdinger equation (in depth direction) in double gate (DG) MOSFETs are derived to calculate electron density and threshold voltage.The non uniform potential in the channel is concern...The analytical solutions to 1D Schrdinger equation (in depth direction) in double gate (DG) MOSFETs are derived to calculate electron density and threshold voltage.The non uniform potential in the channel is concerned with an arbitrary depth so that the analytical solutions agree well with numerical ones.Then,an implicit expression for electron density and a closed form of threshold voltage are presented fully comprising quantum mechanical (QM) effects.This model predicts an increased electron density with an increasing channel depth in subthreshold region or mild inversion region.However,it becomes independent on channel depth in strong inversion region,which is in accordance with numerical analysis.It is also concluded that the QM model,which barely considers a box like potential in the channel,slightly over predicts threshold voltage and underestimates electron density,and the error increases with an increasing channel depth or a decreasing gate oxide thickness.展开更多
Oxidized nanoporous g-C3N4(PCNO)decorated with graphene oxide quantum dots(ox-GQDs)was successfully prepared by a facile self-assembly method.As co-catalysts,the ultrasmall zero-dimensional(0 D)ox-GQDs can achieve uni...Oxidized nanoporous g-C3N4(PCNO)decorated with graphene oxide quantum dots(ox-GQDs)was successfully prepared by a facile self-assembly method.As co-catalysts,the ultrasmall zero-dimensional(0 D)ox-GQDs can achieve uniform dispersion on the surface/inner channels of PCNO,as well as intimate contact with PCNO through hydrogen bonding,π-π,and chemical bonding interactions.In contrast with PCNO,the ox-GQDs/PCNO composite photocatalysts possessed improved light-harvesting ability,higher charge-transfer efficiency,enhanced photooxidation capacity,and increased amounts of reactive species due to the upconversion properties,strong electron capturing ability,and peroxidase-like activity of the ox-GQDs.Therefore,the visible-light photocatalytic degradation and disinfection performances of the ox-GQDs/PCNO composite were significantly enhanced.Remarkably,the composite with a 0.2 wt.% deposited amount of ox-GQDs(ox-GQDs-0.2%/PCNO)exhibited optimum amaranth photodegradation activity,with a corresponding rate about 3.1 times as high as that of PCNO.In addition,ox-GQDs-0.2%/PCNO could inactivate about 99.6%of Escherichia coli(E.coli)cells after 4 h of visible light irradiation,whereas only^31.9% of E.coli cells were killed by PCNO.Furthermore,h+,·O2-,and·OH were determined to be the reactive species generated in the photocatalytic process of the ox-GQDs/PCNO system;these species can thoroughly mineralize azo dyes and effectively inactivate pathogenic bacteria.展开更多
By introducing a fictitious mode to be a counterpart mode of the system mode under review we introduce the entangled state representation （η｜, which can arrange master equations of density operators p（t） in quant...By introducing a fictitious mode to be a counterpart mode of the system mode under review we introduce the entangled state representation （η｜, which can arrange master equations of density operators p（t） in quantum statistics as state-vector evolution equations due to the elegant properties of （η｜. In this way many master equations （respectively describing damping oscillator, laser, phase sensitive, and phase diffusion processes with different initial density operators） can be concisely solved. Specially, for a damping process characteristic of the decay constant k we find that the matrix element of p（t） at time t in 〈η｜ representation is proportional to that of the initial po in the decayed entangled state （ηe^-kt｜ representation, accompanying with a Gaussian damping factor. Thus we have a new insight about the nature of the dissipative process. We also set up the so-called thermo-entangled state representation of density operators, ρ = f（d^2η/π）（η｜ρ〉D（η）, which is different from all the previous known representations.展开更多
We investigate the realization of 2-qutrit logic gate in a bipartite 3-level system with qusi-Ising interaction. On the basis of Caftan decomposition of matrices, the unitary matrices of 2-qutrit are factorized into p...We investigate the realization of 2-qutrit logic gate in a bipartite 3-level system with qusi-Ising interaction. On the basis of Caftan decomposition of matrices, the unitary matrices of 2-qutrit are factorized into products of a series of realizable matrices. It is equivalent to exerting a certain control field on the system, and the control goal is usually gained by a sequence of control pulses. The general discussion on the realization of 2-qutrit logic gate is made first, and then the realization of the ternary SWAP gate and the ternary √SWAP gate are discussed specifically, and the sequences of control pulses and drift processes implementing these gates are given.展开更多
The interaction of a single three-level trapped ion with two laser beams has been studied theoretically. With application of two successive unitary transformations, an analytical solution to this quantum system has be...The interaction of a single three-level trapped ion with two laser beams has been studied theoretically. With application of two successive unitary transformations, an analytical solution to this quantum system has been obtained.展开更多
The effect of solvation on the conformation of acetylene has been studied by adding one water molecule at a time. Quantum chemical calculations of the n＋ （C2H2）（H2O）n （n=1-5） clusters indicate that the H2O mole...The effect of solvation on the conformation of acetylene has been studied by adding one water molecule at a time. Quantum chemical calculations of the n＋ （C2H2）（H2O）n （n=1-5） clusters indicate that the H2O molecules prefer to form the OH...Tr interaction rather than the CH...O interaction. This solvation motif is different from that of neutral （C2H2）（H2O）n （n=1-4） clusters, in which the H2O molecules prefer to form the CH...O and OH...C Hbonds. For the H＋（C2H2）（H2O）n cationic clusters, the first solvation shell consists of one ring structure with two OH...Tr H-bonds and three water molecules, which is completed at n=4. Simulated infrared spectra reveal that vibrational frequencies of OH... H-bonded O-H stretching afford a sensitive probe for exploring the solvation of acetylene by protonated water molecules. Infrared spectra of the H＋ （C2H2）（H2O）n （n=1-5） clusters could be readily measured by the infrared photodissociation technique and thus provide useful information for the understanding of solvation processes.展开更多
基金Project(51174229) supported by the National Natural Science Foundation of China
文摘The electrokinetic behavior and surface dissolution of serpentine mineral were studied through Zeta potential measurements, dissolution experiments and X-ray photoelectron spectroscopy. The results show that serpentine has an iso-electric point （IEP） of 11.9, which is higher than that of other phyllosilicate minerals. Dissolution experiments show that the hydroxyl is easy to dissolve with respect to the magnesium cations in the magnesium oxide octahedral sheet. As a result of hydroxyl dissolution, the magnesium ions are left on serpentine surface, which is responsible for serpentine surface charge. The removal of magnesium ions from serpentine surface by acid leaching results in a decrease of serpentine IEP. Therefore, it has been clearly established that the surface charge developed at the serpentine/aqueous electrical interface is a function of the serpentine surface incongruent dissolution.
文摘Theoretical correspondence between classical instability and local solutions of the Schroedinger equation is discussed for Wannier's ionization threshold law.
基金The National Natural Science Foundation of China(No.11047005)the Science Foundation of Southeast University
文摘Due to the negligible non-perturbation effect in the low-energy region, quantum chromodynamics （QCD） is limited to be applied to hadron problems in particle physics. However, QED has mature non-perturbation models which can be applied to Fermi acting-energy between quark and gluon. This paper applies quantum electrodynamics in 2 ＋ 1 dimensions （QED3） to the Fermi condensation problems. First, the Dyson-Schwinger equation which the fermions satisfy is constructed, and then the Fermi energy gap is solved. Theoretical calculations show that within the chirality limit, there exist three solutions for the energy gap; beyond the chirality limit, there are two solutions; all these solutions correspond to different fermion condensates. It can be concluded that the fermion condensates within the chirality limit can be used to analyze the existence of antiferromagnetic, pseudogap, and superconducting phases, and two fermion condensates are discovered beyond the chirality limit.
基金Supported by Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi,China(2010127)~~
文摘[Objective] The aim of this work was to identify molecular weight （MW） distribution and antioxidant activity of fish skin col agen hydrolysates. [Method] The MW distribution of hydrolysates was determined using both size exclusion chromatography and matrix-assisted laser desorption ionization time-of-flight mass spec-trometry （MALDI-TOF-MS）. Fish skin were treated by the alkaline protease 2709. [Result] The optional conditions for hyerolysis were time 3 h, temperature 55 ℃, pH 10.0, substrate concentration 80 g/L and E/S 4%. The results of both methods indi-cated that the molecular weight of col agen hydrolysates was from 400 to 1 800 Da, and the peptides’ molecular weight was less than 1 400 Da mostly. The reducing power and antioxidant/radical scavenging activity [1, 1-diphenyl-2-picryl-hydrazyl （DPPH） free radical scavenging activity] were determined. [Conclusion] The results reveal that the fishskin hydrolysate is a potential source of antioxidants.
文摘The photoionization and dissociation photoionization of toluene have been studied using quantum chemistry methods. The geometries and frequencies of the reactants, transition states and products have been performed at B3LYP/6-311＋＋G（d,p） level, and single-point energy calculations for all the stationary points were carried out at DFT calculations of the optimized structures with the G3B3 level. The ionization energies of toluene and the ap- pearance energies for major fragment ions, C7H7＋, C6H5＋, C5H6＋, C5H5＋, are determined to be 8.90, 11.15 or 11.03, 12.72, 13.69, 16.28 eV, respectively, which are all in good agree- ment with published experimental data. With the help of available published experimental data and theoretical results, four dissociative photoionization channels have been proposed： CTHT＋＋H, C6Hs＋＋CH3, C5H6＋WC2H2, CsHs＋＋C2H2＋H. Transition structures and intermediates for those isomerization processes are determined in this work. Especially, the structures of C5H6＋ and C5H5＋ produced by dissociative photoionization of toluene have been defined as chain structure in this work with theoretical calculations.
文摘The analytical solutions to 1D Schrdinger equation (in depth direction) in double gate (DG) MOSFETs are derived to calculate electron density and threshold voltage.The non uniform potential in the channel is concerned with an arbitrary depth so that the analytical solutions agree well with numerical ones.Then,an implicit expression for electron density and a closed form of threshold voltage are presented fully comprising quantum mechanical (QM) effects.This model predicts an increased electron density with an increasing channel depth in subthreshold region or mild inversion region.However,it becomes independent on channel depth in strong inversion region,which is in accordance with numerical analysis.It is also concluded that the QM model,which barely considers a box like potential in the channel,slightly over predicts threshold voltage and underestimates electron density,and the error increases with an increasing channel depth or a decreasing gate oxide thickness.
基金supported by the National Natural Science Foundation of China(21707052)Jiangsu Agriculture Science and Technology Innovation Fund(CX(18)2025)+1 种基金Fundamental Research Funds for the Central Universities(JUSRP11905 and JUSRP51714B)Key Research and Development Program of Jiangsu Province(BE2017623)~~
文摘Oxidized nanoporous g-C3N4(PCNO)decorated with graphene oxide quantum dots(ox-GQDs)was successfully prepared by a facile self-assembly method.As co-catalysts,the ultrasmall zero-dimensional(0 D)ox-GQDs can achieve uniform dispersion on the surface/inner channels of PCNO,as well as intimate contact with PCNO through hydrogen bonding,π-π,and chemical bonding interactions.In contrast with PCNO,the ox-GQDs/PCNO composite photocatalysts possessed improved light-harvesting ability,higher charge-transfer efficiency,enhanced photooxidation capacity,and increased amounts of reactive species due to the upconversion properties,strong electron capturing ability,and peroxidase-like activity of the ox-GQDs.Therefore,the visible-light photocatalytic degradation and disinfection performances of the ox-GQDs/PCNO composite were significantly enhanced.Remarkably,the composite with a 0.2 wt.% deposited amount of ox-GQDs(ox-GQDs-0.2%/PCNO)exhibited optimum amaranth photodegradation activity,with a corresponding rate about 3.1 times as high as that of PCNO.In addition,ox-GQDs-0.2%/PCNO could inactivate about 99.6%of Escherichia coli(E.coli)cells after 4 h of visible light irradiation,whereas only^31.9% of E.coli cells were killed by PCNO.Furthermore,h+,·O2-,and·OH were determined to be the reactive species generated in the photocatalytic process of the ox-GQDs/PCNO system;these species can thoroughly mineralize azo dyes and effectively inactivate pathogenic bacteria.
基金supported by President Foundation of Chinese Academy of Sciences and National Natural Science Foundation of China under Grant Nos. 10775097 and 10874174
文摘By introducing a fictitious mode to be a counterpart mode of the system mode under review we introduce the entangled state representation （η｜, which can arrange master equations of density operators p（t） in quantum statistics as state-vector evolution equations due to the elegant properties of （η｜. In this way many master equations （respectively describing damping oscillator, laser, phase sensitive, and phase diffusion processes with different initial density operators） can be concisely solved. Specially, for a damping process characteristic of the decay constant k we find that the matrix element of p（t） at time t in 〈η｜ representation is proportional to that of the initial po in the decayed entangled state （ηe^-kt｜ representation, accompanying with a Gaussian damping factor. Thus we have a new insight about the nature of the dissipative process. We also set up the so-called thermo-entangled state representation of density operators, ρ = f（d^2η/π）（η｜ρ〉D（η）, which is different from all the previous known representations.
基金supported by the National Natural Science Foundation of China under Grant No. 60433050the Science Foundation of Xuzhou Normal University under Grant No. 06XLA05
文摘We investigate the realization of 2-qutrit logic gate in a bipartite 3-level system with qusi-Ising interaction. On the basis of Caftan decomposition of matrices, the unitary matrices of 2-qutrit are factorized into products of a series of realizable matrices. It is equivalent to exerting a certain control field on the system, and the control goal is usually gained by a sequence of control pulses. The general discussion on the realization of 2-qutrit logic gate is made first, and then the realization of the ternary SWAP gate and the ternary √SWAP gate are discussed specifically, and the sequences of control pulses and drift processes implementing these gates are given.
基金The project supported by the Natural Science Foundation of Education Committee of Anhui Province of China under Grant No. 2004kj186
文摘The interaction of a single three-level trapped ion with two laser beams has been studied theoretically. With application of two successive unitary transformations, an analytical solution to this quantum system has been obtained.
基金This work was supported by the National Natural Science Foundation of China （No.21273232 and No.21327901） and the Key Research Program of the Chinese Academy of Science （No.KGZD-EW-T05）. Ling Jiang acknowledges Hundred Talents Program of Chinese Academy of Sciences and Collaborative Innovation Center of Chemistry for Energy and Materials.
文摘The effect of solvation on the conformation of acetylene has been studied by adding one water molecule at a time. Quantum chemical calculations of the n＋ （C2H2）（H2O）n （n=1-5） clusters indicate that the H2O molecules prefer to form the OH...Tr interaction rather than the CH...O interaction. This solvation motif is different from that of neutral （C2H2）（H2O）n （n=1-4） clusters, in which the H2O molecules prefer to form the CH...O and OH...C Hbonds. For the H＋（C2H2）（H2O）n cationic clusters, the first solvation shell consists of one ring structure with two OH...Tr H-bonds and three water molecules, which is completed at n=4. Simulated infrared spectra reveal that vibrational frequencies of OH... H-bonded O-H stretching afford a sensitive probe for exploring the solvation of acetylene by protonated water molecules. Infrared spectra of the H＋ （C2H2）（H2O）n （n=1-5） clusters could be readily measured by the infrared photodissociation technique and thus provide useful information for the understanding of solvation processes.
