The ZnO quantum dot particles with an average particle size 3 nm and the ZnO nanorods with an average length of 80 nm and width about 14 nm were synthesized by the sol-gel method. The surface photovoltaic properties o...The ZnO quantum dot particles with an average particle size 3 nm and the ZnO nanorods with an average length of 80 nm and width about 14 nm were synthesized by the sol-gel method. The surface photovoltaic properties of ZnO nanoparticles were investigated by means of FISPS technique and the bands in FISPS were identified. The results show that the surface photovoltaic properties of ZnO nanoparticles make a great difference for the structures or sizes due to the quantum confinement effect. The photovoltaic response intensity of ZnO nanorods is two-orders of magnitude stronger than that of quantum dot particles. And it is found that the ZnO quantum dot particles exhibit significant quantum confinement properties of photogenerated charges. The photovoltaic response bands of ZnO nanorods are related to band-band transition and bound exciton transition, respectively.展开更多
文摘The ZnO quantum dot particles with an average particle size 3 nm and the ZnO nanorods with an average length of 80 nm and width about 14 nm were synthesized by the sol-gel method. The surface photovoltaic properties of ZnO nanoparticles were investigated by means of FISPS technique and the bands in FISPS were identified. The results show that the surface photovoltaic properties of ZnO nanoparticles make a great difference for the structures or sizes due to the quantum confinement effect. The photovoltaic response intensity of ZnO nanorods is two-orders of magnitude stronger than that of quantum dot particles. And it is found that the ZnO quantum dot particles exhibit significant quantum confinement properties of photogenerated charges. The photovoltaic response bands of ZnO nanorods are related to band-band transition and bound exciton transition, respectively.
基金supported by the National Basic Research Program of China (2014CB931702)the National Key Research and Development Program of China (2016YFB0401701)+5 种基金the National Natural Science Foundation of China (NSFC 51572128 and 21403109)NSFC-RGC (5151101197)the Natural Science Foundation of Jiangsu Province (BK20160827)China Postdoctoral Science Foundation (2016M590455)the Fundamental Research Funds for the Central Universities (30915012205 and 30916015106)the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
