700型气需量分析仪在煤气净化中的故障分析及处理

700型气需量分析仪是一种专用仪器,用来控制煤气净化分厂的克劳斯硫回收系统中助燃气体与酸气的比率。本文介绍了该分析仪工作原理及其作用,详细分析了分析仪目前的现状,对发生的故障作了认真地统计,通过近半年的检查、分析、实验、调整和必要地改造,使各主要部位的故障问题得到了基本解决。通过此次技术改造,使我们对全套分析仪有了更清楚地认识,为今后分析仪的正常运转打下了坚实的基础。

一种延长700型气需量分析仪紫外灯工作寿命的方法

介绍克劳斯法硫回收装置用德国皮尔 70 0型气需量分析仪 ,提出一种延长其紫外灯工作寿命的方法。

Prediction and Analysis of O_3 based on the ARIMA Model

The research conducted prediction on changes of atmosphere pollution during July 9, 2014-July 22, 2014 with SPSS based on monitored data of O3 in 13 successive weeks from 6 sites in Baoding City and demonstrated prediction effect of ARIMA model is good by Ljung-Box Q-test and R2, and the model can be used for prediction on future atmosphere pollutant changes.

Efficient Separation of Ar and Kr from Environmental Samples for Trace Radioactive Noble Gas Detection

Radioactive noble-gas isotopes, SSKr （half-life tl/2=10.8 y）, 39Ar （tl/2=269 y）, and SlKr （t1/2-229,000 y）, are ideal tracers and can be detected by atom trap trace analysis （ATTA）, a laser-based technique, from environmental samples like air and groundwater. Prior to ATTA measurements, it is necessary to efficiently extract krypton and argon gases from samples. Using a combination of cryogenic distillation, titanium chemical reaction and gas chromatography, we demonstrate that we can recover both krypton and argon gases from 1-10 L ＂air-like＂ samples with yields in excess of 90% and 98%, respectively, which meet well the requirements for ATTA measurements. A group of testing samples are analyzed to verify the performance of the system, including two groundwater samples obtained from north China plain.

The Curl of Q Vector: A New Diagnostic Parameter Associated with Heavy Rainfall

As a powerful tool to diagnose vertical motion, frontogenesis, and secondary circulation, the Q vector and its divergence are widely used. However, little attention has been given to the curl of Q vector. In this paper, a new set of analyses combining the divergence of the Q vector （DQ） with the vertical component of the curl of the Q vector （VQ） is applied to a Northeastern cold vortex rainfall case. From the derivation, it was found that the expressions of the Q vectors and their divergences in saturated moist flow （DQm） differ from those of dry and unsaturated moist atmosphere （DQ）, while the VQs of various background flows are exactly the same, which largely simplified the analyses. This case study showed that, compared with the DQ, not only can the DQm diagnose precipitation more effectively, but the VQ may also be indicative of precipitation （especially for heavy rainfall and strong convection） because of its direct, close relationship with ageostrophic motion. Thus, the VQ may be computed and analyzed with ease, and may serve as a useful tool for analyses of precipitation and strong convective svstems.

Surface Modification of Polyethylene Terephthalate(PET) Fiber by Roll-to-Roll Treatment in Atmospheric Ar/O_2 Dielectric Barrier Discharge(DBD) Plasma

In this work,polyethylene terephthalate(PET) fibers were continuously treated by atmospheric dielectric barrier discharge(DBD) in Ar mixed O2 plasma,and the discharge was characterized by electrical function and optical diagnostics.It is found that the interfacial adhesion strength between treated PET fiber and resorcinol formaldehyde latex(RFL)(little)-rubber was improved(about 50%) by the measurement of interfacial shear strength(IFSS) and peel test.The wettability was improved rapidly in the initial treatment time.It is considered that oxidation chemical reaction as the major role of PET fiber surface modification is ahead of the physical etching effect.The high density of atomic oxygen in the plasma by optical emission spectroscopy supports the purpose.According to the scanning electron micrograph(SEM) image in the work,the longer treatment time obviously caused physical etching effect,which shall be less responsible for the improvement of the wettability.

Factor Analysis on Air Quality of Key Environmental Protection Cities

Statistical analysis was performed on 678 data of 6 key indices on air pollution in 113 key cities on basis of China Statistical Yearbook in 2015.Besides,factor analysis was then performed with SPSS17.0 to make overall assessment on air quality in different cities.The results showed that air pollution is quite severe in varying degrees in different cities and the research is expected to provide references for air pollution control in key environment protection cities.

Biogas upgrading technologies: Energetic analysis and environmental impact assessment

Biogas upgrading for removing CO2 and other trace components from raw biogas is a necessary step before the biogas to be used as a vehicle fuel or supplied to the natural gas grid. In this work, three technologies for biogas upgrading, i.e., pressured water scrubbing(PWS), monoethanolamine aqueous scrubbing(MAS) and ionic liquid scrubbing(ILS), are studied and assessed in terms of their energy consumption and environmental impacts with the process simulation and green degree method. A non-random-two-liquid and Henry's law property method for a CO2 separation system with ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide([bmim][Tf2N]) is established and verified with experimental data. The assessment results indicate that the specific energy consumption of ILS and PWS is almost the same and much less than that of MAS. High purity CO2 product can be obtained by MAS and ILS methods, whereas no pure CO2 is recovered with the PWS. For the environmental aspect, ILS has the highest green degree production value, while MAS and PWS produce serious environmental impacts.

Interdecadal Variability of Spring Precipitation over South China and Its Associated Atmospheric Water Vapor Transport

The characteristics of spring precipitation and water vapor transport in South China were analyzed by using observational data and the National Centers for Environmental Prediction (NCEP) reanalysis data. The results show that, during the spring, each component of the water cycle (precipitation, wind field, specific humidity, water vapor transport, etc.) in South China exhibits a notable interdecadal variability. An abrupt increase in spring precipitation occurred in the early 1970s. During the dry period from 1958 to 1971, a water vapor flux divergence (positive divQ) existed in South China, which may have led to the deficiency in rainfall. However, during the wet period from 1973 to 1989, there was a remarkable water vapor flux convergence (negative divQ) in South China, which may have resulted in the higher rainfall. The interdecadal variability of water vapor transport is closely related to the interdecadal variability of wind fields, although the interdecadal variability of specific humidity also plays a role to some extent, and the interdecadal variability of the zonal water vapor transport contributes much more to the interdecadal variability of spring precipitation than the meridional water vapor transport.

Combustion characteristics of Methanol-base fuel （MBF） made by coal

Profound experimental research was made on Methanol-base fuel （MBF） mainly consisting of methanol, and the results were compared with that of diesel oil. Their respective combustion characteristics of caloric value, combustion efficiency and components of smoke were synthetically analyzed by employing the electronic weighing devices, the rotor flow-meter, intelligent flue gas analyzer, advanced bomb calorimeter, etc., referring to the feasibility of taking it as a fuel for general use. Experiment results show that Methanol-base fuel not only has superiorities on combustion characteristics but also bears energy saving and environmental protection advantages.

Energetic analysis of gasification of biomass by partial oxidation in supercritical water

Partial oxidation gasification in supercritical water could produce fuel gases(such as H2, CO and CH4) and significantly reduce the energy consumption. In this work, an energetic model was developed to analyze the partial oxidative gasification of biomass(glucose and lignin) in supercritical water and the related key factors on which gasification under autothermal condition depended upon. The results indicated that the oxidant equivalent ratio(ER) should be over 0.3 as the concern about energy balance but less than 0.6 as the concern about fuel gas production. Feedstocks such as glucose and lignin also had different energy recovery efficiency. For materials which can be efficiently gasified, the partial oxidation might be a way for energy based on the combustion of fuel gases. Aromatic materials such as lignin and coal are more potential since partial oxidation could produce similar amount of fuel gases as direct gasification and offer additional energy. Energy recovered pays a key role to achieve an autothermal process. Keeping heat exchanger efficiency above 80% and heat transfer coefficient below15 k J·s-1is necessary to maintain the autothermal status. The results also indicated that the biomass loading should be above 15% but under 20% for an autothermal gasification, since the increase of biomass loading could improve the energy supplied but decrease the efficiency of gasification and gaseous yields. In general,some specific conditions exist among different materials.

Judgment of Aroma Types of Middle and Upper Flue-cured Tobacco Leaves Based on Stepwise Discriminant Analysis

[Objective] The aim of this study was to establish mathematical models for judging the aroma types of middle and upper flue-cured tobacco leaves according to the contents and proportions of aroma compositions. [Method] The aroma types of tobacco leaves were judged based on stepwise discriminant analysis, using 63 C3F and 65 B2F tobacco leaf samples from 13 tobacco producing regions in 11 provinces of China （Huili in Sichuan, Baokang in Hubei, Wulong in Chongqing, Lu- oyang in Henan, Zhucheng in Shandong, Wuyi Mountain in Fujian, Malong in Yun- nan, Chuxiong in Yunnan, Bijie in Guizhou, Liuyang in Hunan, Suiyang in Guizhou, Kaiyuan in Liaoning, Nanxiong in Guangdong） as calibration samples, and 67 aroma components as indices. And the Fisher discriminant functions were verified using 21 C3F and 19 B2F tobacco leaf samples. [Result] Variation coefficients of the propor- tions were lower than that of contents of most aroma components in middle and upper leaves of the samples, indicating that the proportions were more stable than contents of aroma components. The proportions of benzyl alcohol, solanone, β-dam- ascone, neophytadiene, farnesylacetone A, palmitic acid, thunbergol, methyl linole- nate and cembratriene-diol were all over 1% in both middle and upper leaves, al- though the dominant aroma components of the same aroma type varied between middle and upper leaves. Moreover, 11, 18, 7 and 11 aroma components were re- spectively introduced into the Fisher discriminant functions established based on the contents and proportions of middle and upper flue-cured tobacco leaves, which ex- hibited accuracy rates of 91.7%, 100%, 91.7% and 91.7% in the judgments of other tobacco leaf samples. The results revealed that the components those determined aroma types in middle leaves were obviously more than in upper leaves. In middle leaves, the accuracy rates of aroma type judgment could be improved by using the proportions rather than the contents of aroma components as indices. However, the functions based on the proportions and the contents of aroma components in upper leaves gave close accuracy rates. [Conclusion] The results of the study will provide references for identifying aroma types of flue-cured tobacco leaves in future work.

Transformation of Flue-Gas-Desulfurization Gypsum to α-Hemihydrated Gypsum in Salt Solution at Atmospheric Pressure

Direct phase transformation of flue gas desulfurization gypsum in hot salt solution at atmospheric pres-sure was investigated.The effects of temperature,salt species,salt concentration,solids content,pH and modifier were examined.The crystals obtained under different conditions and solubility of calcium sulfate in contact with solid gypsum were also determined.α-Calcium sulfate hemihydrate crystals of stubby columnar shape and regular pentahedral sides were obtained under the following conditions：salt concentration 20%-30%,operation tempera-ture 95-100 °C,solids mass content in the slurry 10%-30% and neutral pH.Thermodynamic analysis revealed that phase transformation of calcium sulfate dihydrate to α-calcium sulfate hemihydrate occurs because of the difference in solubilities between the two solid gypsum phases in this system.

Study of Rotor Spun Basofil/Cotton Blended Yarn Quality Characteristics during Optimisation of Processing Parameters

Yarn quality characteristics are affected by processing parameters. A 36 tex rotor spun yarn of 50/50 Basofil/ cotton （B/C） blended yarn was spun, and the spinning process optimised for rotor speed, opening roller speed and twist factor. Selected yarn characteristics were studied during the optimization process. During the optimizations process yarn elongation and hairiness reduced with increase in rotor speed. Tenacity increased with increase of rotor speed. The increase in TF caused tenacity and CV of count to increase up to a peak and then started to decrease with further increase of TF.While TF caused an increase in yarn hairiness, elongation decreased to a minimum level and then started to increase with further increase of TF. CV of count and hairiness increased with increase in opening roller speed, but tenacity and elongation decreased with increase in opening roller speed. The optimization process yielded the optimum levels for rotor speed, opening roller speed and twist factor （TF） as 45,000 rpm, 6,500 rpm and 450 respectively. As per uster Standards the optimum yam showed good results for CV of count, CV of tenacity and thin places/km.

Characterization of Specific Spoilage Bacteria and Volatile Flavor Compounds of Flavored Crayfish

It is a common issue in the processing industry of crayfish that flavored crayfish stored at room temperature is perishable.In order to establish an effective putrid prediction mechanism,high-throughput sequencing and solid phase microextraction gas chromatography-mass spectrometry(SPME-GCMS)were used to analyse the microbial community structure and volatile flavor compounds of normal and putrid crayfish.The results showed that Aeromonas(57%),Macrococcus(7.7%),Vibrio sp.(6.6%),Acinetobacter(5%),Citrobacter(4.9%)and Enterobacter(1.49%)were the main bacterial genus in the refrigerated fresh crayfish(HNA).And Staphylococcus(17.04%),Aeromonas(4.46%),Xanthomonas(4.16%),Streptococcus(4.62%)and Enterococcus(2.77%)were the main bacterial genus in the marinated and refrigerated crayfish(HND).With the spoilage of samples(HNE and HNC),the diversity of bacteria decreased,and the specific spoilage bacteria grew rapidly,mainly Enterococcus,Bacillus,Lactobacillus,Leuconostoc,Weissella.Meanwhile,the volatile compounds in non-spoilage sample(HNA and HND)were mainly alkane compounds,aldehydes compound and esters compounds;and the volatile compounds in spoilage samples were mainly alcohols,acids,benzene compounds,terpenoids,N-containing compounds,S-containing compounds and ethers.This indicated that the contents and types of volatile compounds changed with the sample spoilage and deterioration.Correlation analysis results showed that Enterococcus,Lactobacillus and Bacillus were significantly positively correlated with alcohols,acids,benzene,terpenoids,N-containing compounds,S-containing compounds and ether compounds,while Aeromonas,Megasphaera,Acinetobacter,Citrobacter and Vibrio were significantly positively correlated with alkane compounds and esters compounds,and Leuconostoc were significantly positively correlated with alcohol compounds.These results can provide a theoretical guidance for the storage of cooked flavor crayfish at room temperature.

Monitoring Ambient Air Quality in the Carpathian Region of Ukraine

Ivano-Frankivsk oblast is located in the south-western part of Ukraine, close to the geographical center of Europe at the junction of the two major geographic units, the East European Plain and the Eastern Carpathians （the Carpathian region of Ukraine）. Between September 2013 and September 2015, the expert group of the Department of Organic and Analytical Chemistry of Vasyl Stefanyk Precarpathian National University conducted the mobile monitoring of air cleanliness in Ivano-Frankivsk region; the authors monitored the level of air contamination with seven gases： carbon monoxide and dioxide, sulfur dioxide, nitrogen dioxide, hydrogen sulfide, ammonia, formaldehyde, beta-particles, and gamma radiation. For this purpose, there were used six automatic analyzers ＂Dozor-C-P＂, the formaldehyde Gas Analyzer ＂MIC-98170＂, and the radiometer ＂TERRA＂. The monitoring resulted in the making of three maps of Ivano-Frankivsk region, on which the average levels of concentration of three particular gases （CO2, SO2, and CH20） throughout all the districts of the oblast were marked. There was registered the excess of CH20 limits--the consequences of the presence of the chipboard and wood-fiber production, for which formaldehyde is used as a raw material. Also there was observed the excess of SO2 in the air caused by gas fumes from vehicles and thermal power stations.

Experimental study on gas explosion suppression based on ferrocene

In order to study the gas explosion suppression performance based on ferrocene, the self-constructed experimental facility was used to accomplish the experiment of gas explosion suppression. By means of thermogravimetric analysis, the thermal characteristics of ferrocene have been gotten and the gas explosion suppression mechanism of ferrocene has been analyzed. The results show that ferrocene had good effects on gas explosion suppression, and the explosion pressure and flame propagation speed declined obviously. When ferrocene concentration is 0.08 g/L and methane volume concentration is 9.5%, the maximum explosion overpressure and maximum flame propagation speed of methane-air respectively decreased by about 59.5% and 19.6%, respectively. TG and DSC curves showed that the mass loss of ferrocene consists of two processes, which are sublimation and lattice fracture. The temperature of mass loss ranged from 128 ℃ to 230 ℃. The results showed profoundly theoretical significance to gas explosion suppression by ferrocene in coal mines.

Characteristics and Cause Analysis of Heavy Haze in Changchun City in Northeast China

Northeast China has been reported as having serious air pollution in China with increasing occurrences of severe haze epi- sodes. Changchun City, as the center of Northeast China, has longstanding industry and is an important agricultural base. Additionally, Changchun City has a long winter requiring heating of buildings emitting pollution into the air. These factors contribute to the complex- ity of haze pollution in this area. In order to analyze the causes of heavy haze, surface air quality has been monitored from 2013 to 2015. By using satellite and meteorological data, atmospheric pollution status, spatio-temporal variations and formation have been analyzed. Results indicated that the air quality in 88.9% of days exceeding air quality index （AQI） level-1 standard （AQI 〉50） according to the National Ambient Air Quality Standard （NAAQS） of China. Conversely, 33.7% of the days showed a higher level with AQI 〉 100. Ex- treme haze events （AQI 〉 300） occurred frequently during agricultural harvesting period （from October 10 to November 10）, intensive winter heating period （from Late-December to February） and period of spring windblown dust （April and May）. Most daily concentra- tions of gaseous pollutants, i.e., NO2 （43.8 gg/m3）, CO （0.9 mg/m3）, SO2 （37.9 gg/m3）, and 03 （74.9 gg/m3） were evaluated within level-1 concentration limits of NAAQS standards. However, particulate matter （PM2.5 and PMI0） concentrations （67.3 ~tg/m3and 115.2 ~g/m3, respectively） were significantly higher than their level-1 limits. Severe haze in spring was caused by offsite transported dust and windblown surface soil. Heavy haze periods during fall and winter were mainly formed by intensive emissions of atmospheric pollutants and steady weather conditions （i.e., low wind speed and inversion layer）. The overlay emissions of widespread straw burning and coal combustion for heating were the dominant factors contributing to haze in autumn, while intensive coal burning during the coldest time was the primary component of total emissions. In addition, general emissions including automobile exhaust, road and construction dust, residential and industrial activities, have significantly increased in recent years, making heavy haze a more frequent occurrence. There- fore, both improved technological strategies and optimized pollution management on a regional scale are necessary to minimize emis- sions in specified seasons in Changchun City, as well as comprehensive control measures in Northeast China.

Regression Analysis of Nutrient Elements between Soil and Tobacco Leaves and Their Influences on Aroma Quality of Flue-cured Tobacco

This study aimed to analyze the relationship between nutrient elements K, Ca, Mg, Cu, Mn, Zn and Fe in tobacco-planting soils and tobacco leaves from six main tobacco-producing areas, and to investigate the influences of these elements on chemical composition and aroma components in tobacco leaves. Results showed that there were certain relationship between contents of nutrient elements in tobacco-planting soils and contents of corresponding elements in tobacco leaves; various elements exhibited different influences on the aroma quality of flue-cured tobacco. Based on the actual situation of nutrient contents in soils from different tobaccoproducing areas, contents of various elements in tobacco leaves should be regulated by soil fertilization and foliar spraying, thereby improving the aroma quality of flue-cured tobacco.