The solidification microstructures and hardness of Mg-2%Zn (mass fraction) based alloys with addition of 0.4%Ce, 0.4%Gd, 0.4%Y or 0.4%Nd (mass fraction) were investigated, and the effects of the rare earth elements on...The solidification microstructures and hardness of Mg-2%Zn (mass fraction) based alloys with addition of 0.4%Ce, 0.4%Gd, 0.4%Y or 0.4%Nd (mass fraction) were investigated, and the effects of the rare earth elements on the microstructures and mechanical properties of these alloys extruded at 310℃ were also compared. The results indicate that the trace rare earth Ce, Gd, Y or Nd in the Mg-2%Zn alloy has obviously different grain refinement effects on its solidification microstructures, and the as-cast and hot-extruded alloy with 0.4%Ce has the smallest average grain size and the highest strength. However, the extruded alloys containing 0.4%Nd or 0.4%Y with the elongation of 26.6% and 30%, respectively, show higher plasticity in spite of lower strength as compared with the alloy containing 0.4%Ce.展开更多
The solution-treated Mg-4Y-4Sm-0.5Zr alloy was extruded at temperatures from 325℃ to 500℃.Dynamic recrystallization(DRX) completely occurs when the alloy is extruded at 350℃and above.The grains of the extruded allo...The solution-treated Mg-4Y-4Sm-0.5Zr alloy was extruded at temperatures from 325℃ to 500℃.Dynamic recrystallization(DRX) completely occurs when the alloy is extruded at 350℃and above.The grains of the extruded alloy are obviously refined by the occurrence of DRX.The average grain size of the extruded alloy increases with increasing the extrusion temperature,leading to a slight decrease of the ultimate tensile strength(UTS) and the yield strength(YS) .On the contrary,the UTS and YS of the extruded and aged alloy increase with increasing the extrusion temperature.Values of UTS of 400 MPa,YS larger than 300 MPa and elongation(EL) of 7%are achieved after extrusion at 400℃ and ageing at 200℃ for 16 h.Both grain refinement and precipitation are efficient strengthening mechanisms for the Mg-4Y-4Sm-0.5Zr alloy.展开更多
Simultaneous equilibrium was applied to the thermodynamic analysis and calculation of Bi(Ⅲ)-X(Cl-, NO-3)-H2O systems, based on which the diagrams of the logarithm of equilibrium concentration of Bi(Ⅲ) of serie...Simultaneous equilibrium was applied to the thermodynamic analysis and calculation of Bi(Ⅲ)-X(Cl-, NO-3)-H2O systems, based on which the diagrams of the logarithm of equilibrium concentration of Bi(Ⅲ) of series precipitation vs pH value of these two systems at 25 ℃ were obtained, and the pH ranges of the stable zones of various precipitations were analyzed and determined. In Bi(Ⅲ)-Cl--H2O system, the variations of c0(Bi3+) and (c0(Cl-)) have little effect on the equilibria of Bi(OH)3-solution and BiOOH-solution, but has great influence on the (equilibrium) of BiOCl-solution. However, in Bi(Ⅲ)-NO-3-H2O system, the variations of c0(Bi3+) and c0(NO-3) have little effect on equilibria of Bi(OH)3-solution, BiOOH-solution and Bi2O3-solution. When pH value is high, Bi2O3 is the thermodynamic stable phase, its stable zone is the widest, almost including the stable zones of BiOCl or (BiONO3,) (Bi(OH)3) and BiOOH. Bi(OH)3 cannot be obtained from Bi(Ⅲ)-Cl--H2O system, even strong alkaline media. Bi2O3 can be obtained from the solution directly, and highly pure BiOCl or BiONO3 can also be obtained through strictly controlling pH value.展开更多
The Ce/Cr coating was homogenously deposited onto the reticulated open-cell Ni?Cr?Fe alloy foam by the pack cementation process.The mechanical properties of the Ce/Cr coated alloy foams were investigated by the quasi-...The Ce/Cr coating was homogenously deposited onto the reticulated open-cell Ni?Cr?Fe alloy foam by the pack cementation process.The mechanical properties of the Ce/Cr coated alloy foams were investigated by the quasi-static compression test.Simultaneously,the deformation and failure mechanisms of Ce/Cr coated alloy foams were discussed.The results show that the adding amount of CeO2powders influences the mechanical properties of the Ce/Cr coated alloy foams.Despite an increase in density as compared to the uncoated foams,the Ce/Cr coated foams exhibit improvement in both yield strength and energy-absorption performance.Especially,the energy-absorption performance of2%Ce/Cr(mass fraction)coated alloy foam is averagely1.9times as high as that of the bare Ni?Cr?Fe alloy foam.In addition,the mechanical properties of the Ce/Cr coated alloy foams increase with the increase of strain rate.The distortion and cracking are mainly the deformation behavior of the Ce/Cr coated alloy foam,confirmed by SEM images.展开更多
The microstructure,mechanical properties and damping capacity of ZK60-xY(x=0,1.5%,2.5%,4.0%,mass fraction) magnesium alloys were investigated by using the optical microscope(OM),X-ray diffractometer(XRD),universal ten...The microstructure,mechanical properties and damping capacity of ZK60-xY(x=0,1.5%,2.5%,4.0%,mass fraction) magnesium alloys were investigated by using the optical microscope(OM),X-ray diffractometer(XRD),universal tensile testing machine and dynamic mechanical analyzer(DMA).The mechanisms for damping capacity of referred alloys were discussed by Granato-Lücke theory.The results show that Y additions remarkably reduce grain size(the average grain size is 21.6,13.0,8.6 and 4.0μm,respectively),and the tensile properties are enhanced with grain refining(the yield tensile strength increases to 292 MPa from 210 MPa and ultimate tensile strength increases to 330 MPa from 315 MPa).For the ZK60-xY(x=0,1.5%,4.0%)alloys,the damping capacity decreases with the increase of Y content.However,for the ZK60-xY(x=2.5%)alloy,the damping capacity improves abnormally,which is possibly related to the formation of Mg3Y2Zn3(W)FCC phase in this alloy.展开更多
The current crisis has revealed the weaknesses of the global financial in general and its banking system in particular and puts forward a requirement for assessing the effectiveness and stability of the banking sector...The current crisis has revealed the weaknesses of the global financial in general and its banking system in particular and puts forward a requirement for assessing the effectiveness and stability of the banking sectors across countries. Based on available data from 64 countries over the world, the author tried to evaluate the effectiveness of the banking sectors in those countries through the view point of the data envelopment analysis approach to define how the global banking systems is under the effect of the current crisis. Findings from the research showed that banking systems in advanced economies are still more effective than in developing countries. Moreover, it explained the effect of the current financial crisis, the role of public finance (and the government), and the development of the (privately) commercial banks to the effectiveness of the banking sectors. The research also explained some determinants that can affect the effectiveness of the banking system, including inflation, bank concentration, and level of economic development.展开更多
Constitutive behavior of nickel-titanium shape memory alloy (Ni-Ti SMA) under hot deformation was investigated by means of the compression tests and the linear fitting method. Based on the true stres-strain curves o...Constitutive behavior of nickel-titanium shape memory alloy (Ni-Ti SMA) under hot deformation was investigated by means of the compression tests and the linear fitting method. Based on the true stres-strain curves of Ni-Ti SMA under compression at the strain rates of 0.001-1 s land at the temperatures ranging from 600 to 1 000 ℃, the constitutive equation of Ni-Ti SMA with respect to the Zener-Hollomon parameter was established according to the high stress level and the low stress level at various temperatures so as to more accurately describe the deformation behavior of Ni-Ti SMA during hot working. Dynamic recovery and dynamic recrystallization of Ni-Ti SMA occur under hot compression, which lays the theoretical foundation for understanding the constitutive behavior of Ni-Ti SMA.展开更多
Tidal currents are a resource of great potentiality and not yet fully explored. Several efforts have been made to exploit these resources, but the costs associated to the deployment of tidal plants in marine environme...Tidal currents are a resource of great potentiality and not yet fully explored. Several efforts have been made to exploit these resources, but the costs associated to the deployment of tidal plants in marine environments are usually too high. The aim of this work is to present a system able to handle with the above mentioned problems, through the development of a particular hydrokinetic turbine design. In previous works, the authors described a basic turbine configuration achieving interesting performances, although some operational inconveniences were detected. Those problems have been existing so the solution should be optimized and redesigned. As a result, a new design of the turbine is proposed, consisting of a double rotor spinning in opposite directions in order to balance the induced mechanical torque. From preliminary evaluations related to the Messina Strait tidal cycles (Punta Pezzo site, RC, Italy), a single 12 m diameter turbine can supply a power of about 500 kW with a peak current speed of 3 m/s and deliver up to 450 MWh/year.展开更多
The equilibrium of the solid-liquid interface in pressurized solidification process of binary alloys was studied using the Gibbs theory, and the stability of the solid-liquid interface was discussed based on the consi...The equilibrium of the solid-liquid interface in pressurized solidification process of binary alloys was studied using the Gibbs theory, and the stability of the solid-liquid interface was discussed based on the consideration of the effects of pressure on the diffusion coefficient, the interface growth rate and tile equilibrium liquid composition. A mathematical description of the equi- librium status, the relationship of temperature, pressure, composition and interfacial tension was obtained, and further, a mathematical representation of the curvature radius of solid-liquid interface was developed, which facilitates a thorough understanding of the controlled variables of the interfacial stability.展开更多
基金Projects(2007CB613701 2007CB613702) supported by the National Basic Research Program of China+2 种基金Project(NCET-08-0098) supported by the Program for New Century Excellent Talents in UniversityProject(50974037) supported by the National Natural Science Foundation of ChinaProject(90209002) supported by the Special Fund for Basic Scientific Research of Central Colleges in China
文摘The solidification microstructures and hardness of Mg-2%Zn (mass fraction) based alloys with addition of 0.4%Ce, 0.4%Gd, 0.4%Y or 0.4%Nd (mass fraction) were investigated, and the effects of the rare earth elements on the microstructures and mechanical properties of these alloys extruded at 310℃ were also compared. The results indicate that the trace rare earth Ce, Gd, Y or Nd in the Mg-2%Zn alloy has obviously different grain refinement effects on its solidification microstructures, and the as-cast and hot-extruded alloy with 0.4%Ce has the smallest average grain size and the highest strength. However, the extruded alloys containing 0.4%Nd or 0.4%Y with the elongation of 26.6% and 30%, respectively, show higher plasticity in spite of lower strength as compared with the alloy containing 0.4%Ce.
基金Project(2009AA033501)supported by the National Hi-tech Research and Development Program of ChinaProject(2006BAE04B01-2)supported by the National Key Technology Research&Development Program of ChinaProject(06SR07104)supported by theInternational Cooperation Fund of Shanghai Science and Technology Committee,Shanghai/Rhone-Alpes Science and Technology
文摘The solution-treated Mg-4Y-4Sm-0.5Zr alloy was extruded at temperatures from 325℃ to 500℃.Dynamic recrystallization(DRX) completely occurs when the alloy is extruded at 350℃and above.The grains of the extruded alloy are obviously refined by the occurrence of DRX.The average grain size of the extruded alloy increases with increasing the extrusion temperature,leading to a slight decrease of the ultimate tensile strength(UTS) and the yield strength(YS) .On the contrary,the UTS and YS of the extruded and aged alloy increase with increasing the extrusion temperature.Values of UTS of 400 MPa,YS larger than 300 MPa and elongation(EL) of 7%are achieved after extrusion at 400℃ and ageing at 200℃ for 16 h.Both grain refinement and precipitation are efficient strengthening mechanisms for the Mg-4Y-4Sm-0.5Zr alloy.
文摘Simultaneous equilibrium was applied to the thermodynamic analysis and calculation of Bi(Ⅲ)-X(Cl-, NO-3)-H2O systems, based on which the diagrams of the logarithm of equilibrium concentration of Bi(Ⅲ) of series precipitation vs pH value of these two systems at 25 ℃ were obtained, and the pH ranges of the stable zones of various precipitations were analyzed and determined. In Bi(Ⅲ)-Cl--H2O system, the variations of c0(Bi3+) and (c0(Cl-)) have little effect on the equilibria of Bi(OH)3-solution and BiOOH-solution, but has great influence on the (equilibrium) of BiOCl-solution. However, in Bi(Ⅲ)-NO-3-H2O system, the variations of c0(Bi3+) and c0(NO-3) have little effect on equilibria of Bi(OH)3-solution, BiOOH-solution and Bi2O3-solution. When pH value is high, Bi2O3 is the thermodynamic stable phase, its stable zone is the widest, almost including the stable zones of BiOCl or (BiONO3,) (Bi(OH)3) and BiOOH. Bi(OH)3 cannot be obtained from Bi(Ⅲ)-Cl--H2O system, even strong alkaline media. Bi2O3 can be obtained from the solution directly, and highly pure BiOCl or BiONO3 can also be obtained through strictly controlling pH value.
基金Project(51501133)supported by the National Natural Science Foundation of ChinaProject(T201629)supported by the Universities of Hubei Province Outstanding Young Scientific and Technological Innovation Team Plans,ChinaProject(AWJ-M16-11)supported by the State Key Laboratory of Advanced Welding and Joining,Harbin Institute of Technology,China
文摘The Ce/Cr coating was homogenously deposited onto the reticulated open-cell Ni?Cr?Fe alloy foam by the pack cementation process.The mechanical properties of the Ce/Cr coated alloy foams were investigated by the quasi-static compression test.Simultaneously,the deformation and failure mechanisms of Ce/Cr coated alloy foams were discussed.The results show that the adding amount of CeO2powders influences the mechanical properties of the Ce/Cr coated alloy foams.Despite an increase in density as compared to the uncoated foams,the Ce/Cr coated foams exhibit improvement in both yield strength and energy-absorption performance.Especially,the energy-absorption performance of2%Ce/Cr(mass fraction)coated alloy foam is averagely1.9times as high as that of the bare Ni?Cr?Fe alloy foam.In addition,the mechanical properties of the Ce/Cr coated alloy foams increase with the increase of strain rate.The distortion and cracking are mainly the deformation behavior of the Ce/Cr coated alloy foam,confirmed by SEM images.
基金Project(10876045)supported by the National Natural Science Foundation Commission of China and China Academy of Engineering PhysicsProject(50725413)supported by the National Natural Science Foundation of China+1 种基金Project(2007CB613704)supported by the National Basic Research Program of ChinaProject(CSTS2008AB4114)supported by Chongqing Science and Technology Commission(CQ CSTC)
文摘The microstructure,mechanical properties and damping capacity of ZK60-xY(x=0,1.5%,2.5%,4.0%,mass fraction) magnesium alloys were investigated by using the optical microscope(OM),X-ray diffractometer(XRD),universal tensile testing machine and dynamic mechanical analyzer(DMA).The mechanisms for damping capacity of referred alloys were discussed by Granato-Lücke theory.The results show that Y additions remarkably reduce grain size(the average grain size is 21.6,13.0,8.6 and 4.0μm,respectively),and the tensile properties are enhanced with grain refining(the yield tensile strength increases to 292 MPa from 210 MPa and ultimate tensile strength increases to 330 MPa from 315 MPa).For the ZK60-xY(x=0,1.5%,4.0%)alloys,the damping capacity decreases with the increase of Y content.However,for the ZK60-xY(x=2.5%)alloy,the damping capacity improves abnormally,which is possibly related to the formation of Mg3Y2Zn3(W)FCC phase in this alloy.
文摘The current crisis has revealed the weaknesses of the global financial in general and its banking system in particular and puts forward a requirement for assessing the effectiveness and stability of the banking sectors across countries. Based on available data from 64 countries over the world, the author tried to evaluate the effectiveness of the banking sectors in those countries through the view point of the data envelopment analysis approach to define how the global banking systems is under the effect of the current crisis. Findings from the research showed that banking systems in advanced economies are still more effective than in developing countries. Moreover, it explained the effect of the current financial crisis, the role of public finance (and the government), and the development of the (privately) commercial banks to the effectiveness of the banking sectors. The research also explained some determinants that can affect the effectiveness of the banking system, including inflation, bank concentration, and level of economic development.
基金Project(51071056) supported by the National Natural Science Foundation of ChinaProjects(HEUCFR1132, HEUCF121712)supported by the Fundamental Research Funds for the Central Universities of China
文摘Constitutive behavior of nickel-titanium shape memory alloy (Ni-Ti SMA) under hot deformation was investigated by means of the compression tests and the linear fitting method. Based on the true stres-strain curves of Ni-Ti SMA under compression at the strain rates of 0.001-1 s land at the temperatures ranging from 600 to 1 000 ℃, the constitutive equation of Ni-Ti SMA with respect to the Zener-Hollomon parameter was established according to the high stress level and the low stress level at various temperatures so as to more accurately describe the deformation behavior of Ni-Ti SMA during hot working. Dynamic recovery and dynamic recrystallization of Ni-Ti SMA occur under hot compression, which lays the theoretical foundation for understanding the constitutive behavior of Ni-Ti SMA.
文摘Tidal currents are a resource of great potentiality and not yet fully explored. Several efforts have been made to exploit these resources, but the costs associated to the deployment of tidal plants in marine environments are usually too high. The aim of this work is to present a system able to handle with the above mentioned problems, through the development of a particular hydrokinetic turbine design. In previous works, the authors described a basic turbine configuration achieving interesting performances, although some operational inconveniences were detected. Those problems have been existing so the solution should be optimized and redesigned. As a result, a new design of the turbine is proposed, consisting of a double rotor spinning in opposite directions in order to balance the induced mechanical torque. From preliminary evaluations related to the Messina Strait tidal cycles (Punta Pezzo site, RC, Italy), a single 12 m diameter turbine can supply a power of about 500 kW with a peak current speed of 3 m/s and deliver up to 450 MWh/year.
基金supported by the National Natural Science Foundation of China(Grant Nos.50875143 and 50675113)the support of the Scientific Research Foundation for the Returned Overseas Chinese Scholars,Ministry of Education of Chinathe support of State Key Laboratory of Materials Processing and Die & Mould Technology,Huazhong University of Science and Technology
文摘The equilibrium of the solid-liquid interface in pressurized solidification process of binary alloys was studied using the Gibbs theory, and the stability of the solid-liquid interface was discussed based on the consideration of the effects of pressure on the diffusion coefficient, the interface growth rate and tile equilibrium liquid composition. A mathematical description of the equi- librium status, the relationship of temperature, pressure, composition and interfacial tension was obtained, and further, a mathematical representation of the curvature radius of solid-liquid interface was developed, which facilitates a thorough understanding of the controlled variables of the interfacial stability.