The types, composition and physico-chemical conditions of primary fluid inclusions were researched. The results show that the primary fluid inclusions contain vapor and liquid phase type （Type I）, daughter mineral-b...The types, composition and physico-chemical conditions of primary fluid inclusions were researched. The results show that the primary fluid inclusions contain vapor and liquid phase type （Type I）, daughter mineral-bearing type （Type II） and pure liquid phase type （Type III）. The compositions of vapor are mainly H20 and CO2 with a tiny amounts of CH4 and H2; the liquid phase mainly contains Mg2＋, Ca2＋, Na＋, K＋, CI- and SO]-, and w（Na＋）/w（K＋）〉l; the homogenization temperatures of the primary fluid inclusions can be divided into 190-250 ℃, 250-340 ℃ and 360-420 ℃, corresponding to the salinities of 4%-9%, 9%-14%, and 14%-20.43% （NaC1 equivalent mass fraction）, respectively. The mineralization process can be divided into three episodes： the silicatization stage, the quartz-sulfide stage, and the carbonatization stage, and all of them are associated with the ore-forming hydrothermal fluid activity. The origin of the hydrothermal fluid is from magrnatic water mainly, and later it mixes with the groundwater and meteoric water, which lead to the decrease of temperature and salinity. The decrease of salinity, temperature and pressure are the main causes of the metallogenic elements unloading and enriching in the favorable position.展开更多
The Zhuxi ore deposit is a super-large scheelite(copper) polymetallic deposit discovered in recent years. It grew above copper/tungsten-rich Neoproterozoic argilloarenaceous basement rocks and was formed in the contac...The Zhuxi ore deposit is a super-large scheelite(copper) polymetallic deposit discovered in recent years. It grew above copper/tungsten-rich Neoproterozoic argilloarenaceous basement rocks and was formed in the contact zone between Yanshanian granites and Carboniferous-Permian limestone. Granites related to this mineralization mainly include equigranular, middle- to coarse-grained granites and granitic porphyries. There are two mineralization types: skarn scheelite(copper) and granite scheelite mineralization. The former is large scale and has a high content of scheelite, whereas the latter is small scale and has a low content of scheelite. In the Taqian-Fuchun Basin, its NW boundary is a thrust fault, and the SE boundary is an angular unconformity with Proterozoic basement. In Carboniferous-Permian rock assemblages, the tungsten and copper contents in the limestone are both very high. The contents of major elements in granitoids do not differ largely between the periphery and the inside of the Zhuxi ore deposit. In both areas, the values of the aluminum saturation index are A/CNK>1.1, and the rocks are classified as potassium-rich strongly peraluminous granites. In terms of trace elements, compared to granites on the periphery of the Zhuxi ore deposit, the granites inside the Zhuxi ore deposit have smaller d Eu values, exhibit a significantly more negative Eu anomaly, are richer in Rb, U, Ta, Pb and Hf, and are more depleted in Ba, Ce, Sr, La and Ti, which indicates that they are highly differentiated S-type granites with a high degree of evolution. Under the influence of fluids, mineralization of sulfides is evident within massive rock formations inside the Zhuxi ore deposit, and the mean SO_3 content is 0.2%. Compared to peripheral rocks, the d Eu and total rare earth element(REE) content of granites inside the Zhuxi ore deposit are both lower, indicating a certain evolutionary inheritance relationship between the granites on the periphery and the granites inside the Zhuxi ore deposit. For peripheral and ore district plutons, U-Pb zircon dating shows an age range of 152–148 Ma. In situ Lu-Hf isotope analysis of zircon in the granites reveals that the calculated e_(Hf)(t) values are all negative, and the majority range from -6 to -9. The T_(DM2) values are concentrated in the range of 1.50–1.88 Ga(peak at 1.75 Ga), suggesting that the granitic magmas are derived from partial melting of ancient crust. This paper also discusses the metallogenic conditions and ore-controlling conditions of the ore district from the perspectives of mineral contents, hydrothermal alteration, and ore-controlling structures in the strata and the ore-bearing rocks. It is proposed that the Zhuxi ore deposit went through a multistage evolution, including oblique intrusion of granitic magmas, skarn mineralization, cooling and alteration, and precipitation of metal sulfides. The mineralization pattern can be summarized as "copper in the east and tungsten in the west, copper at shallow-middle depths and tungsten at deep depths, tungsten in the early stage and copper in the late stage".展开更多
基金Project(200911007-04) supported by the Special Funds for Scientific Research of Land and Natural Resources, ChinaProject (2007CB411405) supported by the National Basic Research Program of ChinaProject(20109901) supported by the National Crisis Office of China
文摘The types, composition and physico-chemical conditions of primary fluid inclusions were researched. The results show that the primary fluid inclusions contain vapor and liquid phase type （Type I）, daughter mineral-bearing type （Type II） and pure liquid phase type （Type III）. The compositions of vapor are mainly H20 and CO2 with a tiny amounts of CH4 and H2; the liquid phase mainly contains Mg2＋, Ca2＋, Na＋, K＋, CI- and SO]-, and w（Na＋）/w（K＋）〉l; the homogenization temperatures of the primary fluid inclusions can be divided into 190-250 ℃, 250-340 ℃ and 360-420 ℃, corresponding to the salinities of 4%-9%, 9%-14%, and 14%-20.43% （NaC1 equivalent mass fraction）, respectively. The mineralization process can be divided into three episodes： the silicatization stage, the quartz-sulfide stage, and the carbonatization stage, and all of them are associated with the ore-forming hydrothermal fluid activity. The origin of the hydrothermal fluid is from magrnatic water mainly, and later it mixes with the groundwater and meteoric water, which lead to the decrease of temperature and salinity. The decrease of salinity, temperature and pressure are the main causes of the metallogenic elements unloading and enriching in the favorable position.
基金supported by the National Basic Research Program of China(Grant No.2012CB416701)National Natural Science Foundation of China(Grant Nos.41330208+3 种基金41572200)National Science and Technology Support Program(Grant No.2011BAB04B02)the Jiangxi Geological Exploration Fund(Grant No.20100112)Jiangxi Science and Technology Project(Grant No.20122BBG70068)
文摘The Zhuxi ore deposit is a super-large scheelite(copper) polymetallic deposit discovered in recent years. It grew above copper/tungsten-rich Neoproterozoic argilloarenaceous basement rocks and was formed in the contact zone between Yanshanian granites and Carboniferous-Permian limestone. Granites related to this mineralization mainly include equigranular, middle- to coarse-grained granites and granitic porphyries. There are two mineralization types: skarn scheelite(copper) and granite scheelite mineralization. The former is large scale and has a high content of scheelite, whereas the latter is small scale and has a low content of scheelite. In the Taqian-Fuchun Basin, its NW boundary is a thrust fault, and the SE boundary is an angular unconformity with Proterozoic basement. In Carboniferous-Permian rock assemblages, the tungsten and copper contents in the limestone are both very high. The contents of major elements in granitoids do not differ largely between the periphery and the inside of the Zhuxi ore deposit. In both areas, the values of the aluminum saturation index are A/CNK>1.1, and the rocks are classified as potassium-rich strongly peraluminous granites. In terms of trace elements, compared to granites on the periphery of the Zhuxi ore deposit, the granites inside the Zhuxi ore deposit have smaller d Eu values, exhibit a significantly more negative Eu anomaly, are richer in Rb, U, Ta, Pb and Hf, and are more depleted in Ba, Ce, Sr, La and Ti, which indicates that they are highly differentiated S-type granites with a high degree of evolution. Under the influence of fluids, mineralization of sulfides is evident within massive rock formations inside the Zhuxi ore deposit, and the mean SO_3 content is 0.2%. Compared to peripheral rocks, the d Eu and total rare earth element(REE) content of granites inside the Zhuxi ore deposit are both lower, indicating a certain evolutionary inheritance relationship between the granites on the periphery and the granites inside the Zhuxi ore deposit. For peripheral and ore district plutons, U-Pb zircon dating shows an age range of 152–148 Ma. In situ Lu-Hf isotope analysis of zircon in the granites reveals that the calculated e_(Hf)(t) values are all negative, and the majority range from -6 to -9. The T_(DM2) values are concentrated in the range of 1.50–1.88 Ga(peak at 1.75 Ga), suggesting that the granitic magmas are derived from partial melting of ancient crust. This paper also discusses the metallogenic conditions and ore-controlling conditions of the ore district from the perspectives of mineral contents, hydrothermal alteration, and ore-controlling structures in the strata and the ore-bearing rocks. It is proposed that the Zhuxi ore deposit went through a multistage evolution, including oblique intrusion of granitic magmas, skarn mineralization, cooling and alteration, and precipitation of metal sulfides. The mineralization pattern can be summarized as "copper in the east and tungsten in the west, copper at shallow-middle depths and tungsten at deep depths, tungsten in the early stage and copper in the late stage".
