A systematic experiment relating to the electrochemistry of oxygen ion transport in slag has been studied in lab. An equivalent circuit has been used to describe ion transfer between metal and slag in this paper and a...A systematic experiment relating to the electrochemistry of oxygen ion transport in slag has been studied in lab. An equivalent circuit has been used to describe ion transfer between metal and slag in this paper and a kinetic model with electrochemical characteristic representing oxygen ion immigration has been worked out. The different experimental phenomena can be explained generally by this model. It can be seen that the theoretical results are in good agreement with experiments. The comparison of experimental data with model calculation proved that the electrochemical model is right.展开更多
Na_(2)S,Na_(2)CO_(3),FeO,FeS and carbon were used to regulate the properties of slag or metal fractions,and their effects on metal growth and metal–slag separation behavior were investigated.The growth of ferronickel...Na_(2)S,Na_(2)CO_(3),FeO,FeS and carbon were used to regulate the properties of slag or metal fractions,and their effects on metal growth and metal–slag separation behavior were investigated.The growth of ferronickel grains can be enhanced by adding these additives,and Na_(2)S was the most effective.Na_(2)S,Na_(2)CO_(3) and FeO mainly affected the properties of slag,while carbon and FeS affected the metal fraction.The onset temperature of metal–slag separation was 1297℃ for the sample without additive,which was decreased to 1123 and 1101℃ after adding 3.30 wt.%Na_(2)S and 4.47 wt.%Na_(2)CO_(3),respectively.The onset temperature of metal–slag separation was mainly controlled by the slag fraction.The average apparent activation energy of metal grain growth was 125.32 kJ/mol without additive,and it decreased obviously after adding different additives.Na_(2)S also had the most remarkable effect on the decrease in activation energy.展开更多
The results to develop a complex technology of co-extraction of germanium and gallium from the ash-and-slag wastes of coal combustion in Ukraine were presented. Based on the study of phase changes occurring in initial...The results to develop a complex technology of co-extraction of germanium and gallium from the ash-and-slag wastes of coal combustion in Ukraine were presented. Based on the study of phase changes occurring in initial raw materials as a result of its processing, it was proposed to carry out a preliminary enrichment of the raw materials in order to produce secondary sublimates. Their further processing involves a combination of leaching soluble material with distillation of germanium in the form of tetrachloride. The resulting acidic solutions are trended to the gallium extraction. Optimum conditions of carrying out of processes are recommended.The chemical and phase composition of the resulting dump products and solutions have been defined. On the basis of it ways of their processing for the purpose of reception of alumina and building materials are recommended.展开更多
文摘A systematic experiment relating to the electrochemistry of oxygen ion transport in slag has been studied in lab. An equivalent circuit has been used to describe ion transfer between metal and slag in this paper and a kinetic model with electrochemical characteristic representing oxygen ion immigration has been worked out. The different experimental phenomena can be explained generally by this model. It can be seen that the theoretical results are in good agreement with experiments. The comparison of experimental data with model calculation proved that the electrochemical model is right.
基金support from the National Natural Science Foundation of China(No.51904047)the Fundamental and Frontier Research Project of Chongqing,China(No.cstc2020jcyj-msxmX0515)the State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization,China.
文摘Na_(2)S,Na_(2)CO_(3),FeO,FeS and carbon were used to regulate the properties of slag or metal fractions,and their effects on metal growth and metal–slag separation behavior were investigated.The growth of ferronickel grains can be enhanced by adding these additives,and Na_(2)S was the most effective.Na_(2)S,Na_(2)CO_(3) and FeO mainly affected the properties of slag,while carbon and FeS affected the metal fraction.The onset temperature of metal–slag separation was 1297℃ for the sample without additive,which was decreased to 1123 and 1101℃ after adding 3.30 wt.%Na_(2)S and 4.47 wt.%Na_(2)CO_(3),respectively.The onset temperature of metal–slag separation was mainly controlled by the slag fraction.The average apparent activation energy of metal grain growth was 125.32 kJ/mol without additive,and it decreased obviously after adding different additives.Na_(2)S also had the most remarkable effect on the decrease in activation energy.
文摘The results to develop a complex technology of co-extraction of germanium and gallium from the ash-and-slag wastes of coal combustion in Ukraine were presented. Based on the study of phase changes occurring in initial raw materials as a result of its processing, it was proposed to carry out a preliminary enrichment of the raw materials in order to produce secondary sublimates. Their further processing involves a combination of leaching soluble material with distillation of germanium in the form of tetrachloride. The resulting acidic solutions are trended to the gallium extraction. Optimum conditions of carrying out of processes are recommended.The chemical and phase composition of the resulting dump products and solutions have been defined. On the basis of it ways of their processing for the purpose of reception of alumina and building materials are recommended.
