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脂肪族双酰基二酰二肼类化合物的EI质谱特征
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作者 范平 董薇 +1 位作者 佟健 唐慧婷 《分析测试学报》 CAS CSCD 北大核心 2002年第2期55-57,共3页
总结和归属了N,N′_二乙酰基丁二酰二肼、N,N′_二乙酰基癸二酰二肼以及4种N,N′_二酰基戊二酰二肼和4种N,N′_二酰基己二酰二肼共10个化合物在电子轰击电离质谱 (EIMS)中的主要裂解方式和特征 ,指明了主要碎片离子的来源和结构 ;这10... 总结和归属了N,N′_二乙酰基丁二酰二肼、N,N′_二乙酰基癸二酰二肼以及4种N,N′_二酰基戊二酰二肼和4种N,N′_二酰基己二酰二肼共10个化合物在电子轰击电离质谱 (EIMS)中的主要裂解方式和特征 ,指明了主要碎片离子的来源和结构 ;这10种化合物质谱图中的主要碎片峰均来自于羰基的α_裂解和重排α_裂解,由其裂解产生的基峰离子H2NNHCO(CH2)nCO+ 以及RCONHNHCO(CH)nCO+ 、RCONHN+ 展开更多
关键词 N N′-二酰基二酰二肼 电子轰击电离 质谱 α-裂解 裂解特征 金属碱活剂
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Fire Extinct Experiments with Water Mist by Adding Additives 被引量:3
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作者 Lijun Yang Jianbo Zhao 《Journal of Thermal Science》 SCIE EI CAS CSCD 2011年第6期563-569,共7页
The effects of fire extinguishment with water mist by adding different additives were studied.Tens of chemical substances (including alkali metal salt,dilution agent and surface active agent) were selected as additive... The effects of fire extinguishment with water mist by adding different additives were studied.Tens of chemical substances (including alkali metal salt,dilution agent and surface active agent) were selected as additives due to their different extinct mechanisms.At first the performance of fire extinguishment with single additive was studied,then the effects of the same kinds of chemical substances under the same mass fraction were compared to study their influences on the fire extinguishment factors,including extinct time,fire temperature and oxygen concentration from which the fire extinct mechanism with additives could be concluded.Based on this the experiments were conducted to study the cooperate effect of the complexity of different additives.It indicated the relations between different firefighting mechanisms and different additives were competitive.From a large number of experiments the extinct mechanism with water mist by adding additives was concluded and an optimal compounding additive was selected. 展开更多
关键词 fire extinguishment ADDITIVES water mist
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