In this work, an equilibrium-dispersion model was successfully established to describe the breakthrough performance of Ca（Ⅱ） imprinted chitosan （Ca（Ⅱ）-CS） microspheres packed column for metal adsorption, and t...In this work, an equilibrium-dispersion model was successfully established to describe the breakthrough performance of Ca（Ⅱ） imprinted chitosan （Ca（Ⅱ）-CS） microspheres packed column for metal adsorption, and the assumptions of Langmuir isotherms and axial dispersion controlled mass transfer process were confirmed. The axial dispersion coefficient in Ca（Ⅱ）-CS microspheres packed column was found to be almost proportional to the linear velocity and fit for prediction through single breakthrough test. Sensitivity analysis for breakthrough curve indicated the axial dispersion coefficient as well as Langmuir coefficient was sensitive variable for deep removal requirement. The retrieval of the adsorption isotherms of Ca（Ⅱ）-CS microspheres from breakthrough curve was fulfilled by modelling calibration. A strategy based on the correlation between adsorption isotherms and breakthrough performance was further proposed to simplify the column adsorption design using absorbents with small/uniform size and fast adsorption kinetics like Ca（Ⅱ）-CS microspheres to cut down the gap between lab and industry.展开更多
Uniaxial tensile tests and scanning electron microscopy(SEM)experiments were carried out on the porous FeAl intermetallics(porosities of 41.1%,44.2%and 49.3%,pore size of 15−30μm)prepared by our research group to stu...Uniaxial tensile tests and scanning electron microscopy(SEM)experiments were carried out on the porous FeAl intermetallics(porosities of 41.1%,44.2%and 49.3%,pore size of 15−30μm)prepared by our research group to study the macroscopic mechanical properties and microscopic failure mechanism.The results show that the tensileσ−εcurves of the porous FeAl with different porosities can be divided into four stages:elasticity,yielding,strengthening and failure,without necking phenomenon.The elastic modulus,ultimate strength and elongation decrease with the increase of porosity and the elongation is much lower than 5%.A macroscopic brittle fracture appears,and the microscopic fracture mechanism is mainly intergranular fracture,depending on the Al content in the dense FeAl intermetallics.In addition,the stochastic porous model(SPM)with random pore structure size and distribution is established by designing a self-compiling generation program in FORTRAN language.Combined with the secondary development platform of finite element software ANSYS,the effective elastic moduli of the porous FeAl can be determined by elastic analysis of SPM and they are close to the experimental values,which can verify the validity of the established SPM for analyzing the elastic properties of the porous material.展开更多
We carried out first-principles calculations to investigate the electronic properties of the monolayer blue phosphorene(BlueP)decorated by the group-IVB transition-metal adatoms(Cr,Mo and W),and found that the Cr-deco...We carried out first-principles calculations to investigate the electronic properties of the monolayer blue phosphorene(BlueP)decorated by the group-IVB transition-metal adatoms(Cr,Mo and W),and found that the Cr-decorated BlueP is a magnetic half metal,while the Mo-and W-decorated BlueP are semiconductors with band gaps smaller than 0.2 eV.Compressive biaxial strains make the band gaps close and reopen,and band inversions occur during this process,which induces topological transitions in the Mo-decorated BlueP(with strain of-5.75%)and W-decorated BlueP(with strain of-4.25%)from normal insulators to topological insulators(TIs).The TI gap is 94 meV for the Mo-decorated BlueP and218 me V for the W-decorated BlueP.Such large TI gaps demonstrate the possibility to engineer topological phases in the monolayer BlueP with transition-metal adatoms at high temperature.展开更多
In this paper,an elasto-viscoplastic three-dimension(3D) finite element model is developed to simulate the processing of bimetal tube with rotary swaging. Through simulation,the effects of high-frequency pulse strokin...In this paper,an elasto-viscoplastic three-dimension(3D) finite element model is developed to simulate the processing of bimetal tube with rotary swaging. Through simulation,the effects of high-frequency pulse stroking on the distribution and histories of stress,stain and loading are clarified. The stress in inner tube is compressive and higher than the minimum bonding force. Meanwhile,the stiffness of inner tube impacts outer tube extension in length.展开更多
The distribution and characteristics of nonmetallic micro-inclusions of GCr15 bearing steel were explored through metallographic area method in virtue of tracer method and electronic microscope.The results show that t...The distribution and characteristics of nonmetallic micro-inclusions of GCr15 bearing steel were explored through metallographic area method in virtue of tracer method and electronic microscope.The results show that the micro-inclusions,of which the average value is 0.032%,are mainly the compounds formed via the adsorption/aggregation of multielement deoxidized compounds and secondarily deoxidized products on tundish liquid level.The micro-inclusions of diameters from 0 to 5 μm are 92.5% in total,which basically determines the characteristics of inclusions distribution in casting slab.The inclusions of diameters more than 10 μm only account for less than 1% in total,which have little influence on steel quality.The relationship between equilibrium compositions of the first deoxidation products and molten steel compositions was also calculated based on thermodynamic theory.展开更多
To reduce defects caused by non-homogeneous metal flow in conventional extrusion,a die with guiding angle was designed to improve the metal flow behavior. The characteristic quantities such as the second invariant of ...To reduce defects caused by non-homogeneous metal flow in conventional extrusion,a die with guiding angle was designed to improve the metal flow behavior. The characteristic quantities such as the second invariant of the deviator stress J2 and Lode's coefficient μ were employed for the division of deformation area. The results show that when the metal is extruded with the guiding angle,no metal flow interface forms at the container's bottom,the dead zone completely disappears,the deformation types of the metal in the plastic deformation area change from three types to one type of tension,and the homogeneity of the deformation as well as metal flow are greatly improved. The non-homogeneous metal flow at the final stage of extrusion is improved,reducing the shrinkage hole at the axis end. The radial stress of the furthest point from the axis is transformed from tensile stress to compressive stress and the axial stress,and decreased from 70.8 to 34.8 MPa. Therefore,the surface cracks caused by additional stress are greatly reduced.展开更多
基金the National Natural Science Foundation of China(2117613621422603)the National Science and Technology Support Program of China(2011BAC06B01)
文摘In this work, an equilibrium-dispersion model was successfully established to describe the breakthrough performance of Ca（Ⅱ） imprinted chitosan （Ca（Ⅱ）-CS） microspheres packed column for metal adsorption, and the assumptions of Langmuir isotherms and axial dispersion controlled mass transfer process were confirmed. The axial dispersion coefficient in Ca（Ⅱ）-CS microspheres packed column was found to be almost proportional to the linear velocity and fit for prediction through single breakthrough test. Sensitivity analysis for breakthrough curve indicated the axial dispersion coefficient as well as Langmuir coefficient was sensitive variable for deep removal requirement. The retrieval of the adsorption isotherms of Ca（Ⅱ）-CS microspheres from breakthrough curve was fulfilled by modelling calibration. A strategy based on the correlation between adsorption isotherms and breakthrough performance was further proposed to simplify the column adsorption design using absorbents with small/uniform size and fast adsorption kinetics like Ca（Ⅱ）-CS microspheres to cut down the gap between lab and industry.
基金Project(11502307)supported by the National Natural Science Foundation of ChinaProject(2016JJ3187)supported by the Natural Science Foundation of Hunan Province,ChinaProject(50825102)supported by the National Natural Science Funds for Distinguished Young Scholar of China。
文摘Uniaxial tensile tests and scanning electron microscopy(SEM)experiments were carried out on the porous FeAl intermetallics(porosities of 41.1%,44.2%and 49.3%,pore size of 15−30μm)prepared by our research group to study the macroscopic mechanical properties and microscopic failure mechanism.The results show that the tensileσ−εcurves of the porous FeAl with different porosities can be divided into four stages:elasticity,yielding,strengthening and failure,without necking phenomenon.The elastic modulus,ultimate strength and elongation decrease with the increase of porosity and the elongation is much lower than 5%.A macroscopic brittle fracture appears,and the microscopic fracture mechanism is mainly intergranular fracture,depending on the Al content in the dense FeAl intermetallics.In addition,the stochastic porous model(SPM)with random pore structure size and distribution is established by designing a self-compiling generation program in FORTRAN language.Combined with the secondary development platform of finite element software ANSYS,the effective elastic moduli of the porous FeAl can be determined by elastic analysis of SPM and they are close to the experimental values,which can verify the validity of the established SPM for analyzing the elastic properties of the porous material.
基金the National Natural Science Foundation of China(No.11574223)the Natural Science Foundation of Jiangsu Province(BK20150303)the Six Talent Peaks Project of Jiangsu Province(2019-XCL-081)。
文摘We carried out first-principles calculations to investigate the electronic properties of the monolayer blue phosphorene(BlueP)decorated by the group-IVB transition-metal adatoms(Cr,Mo and W),and found that the Cr-decorated BlueP is a magnetic half metal,while the Mo-and W-decorated BlueP are semiconductors with band gaps smaller than 0.2 eV.Compressive biaxial strains make the band gaps close and reopen,and band inversions occur during this process,which induces topological transitions in the Mo-decorated BlueP(with strain of-5.75%)and W-decorated BlueP(with strain of-4.25%)from normal insulators to topological insulators(TIs).The TI gap is 94 meV for the Mo-decorated BlueP and218 me V for the W-decorated BlueP.Such large TI gaps demonstrate the possibility to engineer topological phases in the monolayer BlueP with transition-metal adatoms at high temperature.
基金National Natural Science Foundation of China(No.51175413)
文摘In this paper,an elasto-viscoplastic three-dimension(3D) finite element model is developed to simulate the processing of bimetal tube with rotary swaging. Through simulation,the effects of high-frequency pulse stroking on the distribution and histories of stress,stain and loading are clarified. The stress in inner tube is compressive and higher than the minimum bonding force. Meanwhile,the stiffness of inner tube impacts outer tube extension in length.
基金Supported by Natural Science Foundation of Hebei Province (No.502265)
文摘The distribution and characteristics of nonmetallic micro-inclusions of GCr15 bearing steel were explored through metallographic area method in virtue of tracer method and electronic microscope.The results show that the micro-inclusions,of which the average value is 0.032%,are mainly the compounds formed via the adsorption/aggregation of multielement deoxidized compounds and secondarily deoxidized products on tundish liquid level.The micro-inclusions of diameters from 0 to 5 μm are 92.5% in total,which basically determines the characteristics of inclusions distribution in casting slab.The inclusions of diameters more than 10 μm only account for less than 1% in total,which have little influence on steel quality.The relationship between equilibrium compositions of the first deoxidation products and molten steel compositions was also calculated based on thermodynamic theory.
基金Project(RC2010QN017008) supported by the Excellent Young Teachers Program of Harbin City, China
文摘To reduce defects caused by non-homogeneous metal flow in conventional extrusion,a die with guiding angle was designed to improve the metal flow behavior. The characteristic quantities such as the second invariant of the deviator stress J2 and Lode's coefficient μ were employed for the division of deformation area. The results show that when the metal is extruded with the guiding angle,no metal flow interface forms at the container's bottom,the dead zone completely disappears,the deformation types of the metal in the plastic deformation area change from three types to one type of tension,and the homogeneity of the deformation as well as metal flow are greatly improved. The non-homogeneous metal flow at the final stage of extrusion is improved,reducing the shrinkage hole at the axis end. The radial stress of the furthest point from the axis is transformed from tensile stress to compressive stress and the axial stress,and decreased from 70.8 to 34.8 MPa. Therefore,the surface cracks caused by additional stress are greatly reduced.
