罗桂祥捐献的瓷器

故宫博物院陶瓷馆第四室的一个展櫃里,陈列着1987年香港羅桂祥先生捐献的十三件清代青花瓷器,这批瓷器以其独特的艺术格吸引着衆多的游人。这十三件瓷器是羅先生从荷蘭首都阿姆斯特丹购买的。 1983年3月,生于英格蘭纽约郡从事海洋沉船打捞的麦克·哈契尔船长来到南中国海,在一处地图上未注明的暗礁旁发现了中国瓷器,有瓷盘、花瓶、壶等及大量碎瓷片。几周后,他带了八十件瓷器来到荷蘭首都阿姆斯特丹,让一位叫佳士德的優秀拍卖商为其鉴定评价,哈契尔原以为祇值几百美圆。

Review on hot spinning for difficult-to-deform lightweight metals

Hot spinning process has attracted significant attention because it can be used to manufacture complex parts, extend the forming limit of materials, decrease forming forces and reduce process chains. In this paper, we review researches on lightweight metals spun at elevated temperatures since they are difficult to deform at room temperature. These metals include light alloys, such as titanium, magnesium and aluminum alloys, and metal composites. Then, the heating methods used in the hot spinning process and the treatment methods employed for the temperature boundary condition in finite element analyses for the process were discussed. Finally, the future development directions for the hot spinning process of lightweight but difficult-to-deform alloys were highlighted.

赞美您年轻的朋友——记优秀花样滑冰运动员许兆晓

在南斯拉夫举行的、有十八个国家参加的第十八届“金旋转”国际花样滑冰邀请赛中,我国19岁的来自黑龙江的选手许兆晓获男子自由滑第三名。时隔不久于匈牙利举行的一九八四年布达佩斯“多脑温泉奖”的国际花样滑冰比赛中,他又战胜了包括英国、西德、澳大利亚、匈牙利在内的十一个国家的许多选手,获男子单人滑第一名,这也是我国运动员在世界大赛中取得的第一个冠军。

Influence of spiral crystal selector on crystal orientation of single crystal superalloy

To increase efficiency and improve performance, reducing cost and emissions, advanced single crystal Ni-based superalloys are required in aerospace propulsion and power generating gas turbines. With the development of alloy, significant improvements in casting techniques have been achieved by introducing the directionally solidified （DS） casting process followed by single crystal （SX） technique. The deviation of preferred orientation of single crystal superalloys is one of the most important defects in casting. In directional solidification equipment with high temperature gradient, single crystal specimens of DZ417G alloy were prepared successfully by the modified Bridgeman method with spiral grain selector. The orientation was investigated by means of X-ray diffraction （XRD） and electron backscattered diffraction （EBSD）.The results show that the crystal selector with a smaller angle can effectively reduce the deviation of preferred orientation.

Finite element simulation of ball spinning of NiTi shape memory alloy tube based on variable temperature field

As a new attempt,ball spinning was used to manufacture the nickel-titanium shape memory alloy（NiTi SMA） tube at elevated temperature.The NiTi bar with a nominal composition of Ni50.9Ti49.1（mole fraction,%） was solution treated and was used as the original tube blank for ball spinning.Based on the variable temperature field and the constitutive equation,rigid-viscoplastic finite element method（FEM） was applied in order to simulate the ball spinning of NiTi SMA tube.The temperature field,the stress field,the strain field and the load prediction were obtained by means of FEM.FEM results reveal that there is a temperature increase of about 160 ℃ in the principal deformation zone of the spun part.It can be found from the stress fields and the strain fields that the outer wall of NiTi SMA tube is easier to meet the plastic yield criterion than the inner wall,and the plastic deformation zone is caused to be in a three-dimensional compressive stress state.The radial strain and the tangential strain are characterized by the compressive strain,while the axial strain belongs to the tensile strain.The variation of spinning loads with the progression of the ball is of great importance in predicting the stable flow of the spun part.

Investigation of GaN Growth Directly on Si (001) by ECR Plasma Enhanced MOCVD

Direct growth of GaN films on Si(001) substrate at low temperatures (620～720℃) by electron cyclotron resonance (ECR) microwave plasma enhanced metalorganic chemical vapor deposition (PEMOCVD).The crystalline phase structures of the films are investigated.The results of high resolution transmission electron microscopy (HRTEM) and X ray diffraction (XRD) indicate that high c axis oriented crystalline wurtzite GaN is grown on Si(001) but there is an amorphous layer formed naturally at GaN/Si interface.Both faces of the amorphous layer are flat and sharp,and the thickness of the layer is 2nm approximately cross the interface.The analysis supports that β GaN phase is not formed owing to the N x Si y amorphous layer induced by the reaction between N and Si during the initial nucleation stage.The results of XRD and atomic force microscopy (AFM) indicate that the conditions of substrate surface cleaned in situ by hydrogen plasma,GaN initial nucleation and subsequent growth are very important for the crystalline quality of GaN films.

Microstructural evolution during hot and cold deformation of Ti-36Nb-2Ta-3Zr-0.35O alloy

The Ti-36Nb-2Ta-3Zr-0.350 （mass fraction, %） （TNTZO） alloy was produced by cold isostatic pressing and sintering from elemental powders, followed by hot and cold deformation. The effects of deformation process on microstructures and mechanical properties were investigated using the SEM, TEM, OM and the universal material testing machine. Results show that the alloy can be easily hot forged and cold swaged due to the fine-grained microstructure. Only after cold swaging by 85%, the alloy shows the typical ＂marble-like＂ structure. And thecold deformation is accompanied by stress-induced a＂ phase transformations. Moreover, both the strength and the ductility of the alloy are significantly improved by hot and cold working.

Effects of Nd and rotary forging on mechanical properties of AZ71 Mg alloys

The effects of Nd addition on the mechanical properties and plastic deformability of AZ71 Mg alloys were investigated.0.5%-2.0%（mass fraction） Nd was added to AZ71 Mg alloys.The grain size and the amount of brittle β-Mg17Al12 phase reduce with increasing the Nd addition,while nanosized AlxNdy precipitates form.In combination with 32% rotary forging and subsequent annealing,the grain size of Nd-added AZ71 Mg alloys reduces greatly from over 350 μm to below 30 μm.Both tensile strength and ductility increase with the Nd addition up to 1.0%.The addition of Nd beyond 1.0% leads to the aggregations of rod-shaped Al11Nd3 and blocky Al2 Nd precipitates,thereby deteriorating both strength and ductility.The 1.0% Nd-added AZ71 Mg alloy shows tensile strength up to 253 MPa and elongation of 10.7%.It is concluded that adding 1.0% Nd to AZ71 Mg alloy yields the optimum toughness,whether under as-cast or rotary forging and annealing conditions.

Effects of directional solidification parameters and crystal selector on microstructure of single crystal of Ni-base superalloys

The single crystal of nickel-base super alloy is widely used for making turbine blades.The microstructure of the alloy,especially the deviation of preferred orientation of single crystal,possesses the most important effects on the mechanical properties of the blades.In this study,the single crystal ingot and blade of DZ417G alloy are prepared by means of the spiral crystal selector as well as the directional solidification method,and the effect of the parameters(i.e.,the shape of samples,the withdrawal rate)and the structure of the spiral crystal selector on the formation of single crystal and the crystal orientation are investigated.This method can prepare not only the single crystal ingot with simple shape but also the single crystal blades with the complex shape,the simple with rod-shape can form the single crystal easily with a relatively fast withdrawal rate,but the blade with complex shape requires much slower withdrawal rate to form single crystal.The length of the crystal selector almost has no effect on the crystal orientation.However,the angle of selector plays an obvious role on the orientation;the selector with a smaller angle can effectively reduce the deviation of preferred orientation;the appropriate angle of selector to obtain optimal orientation is found to be around30°and the deviation of preferred orientation is about30°for this selector.

Deformation behaviour and microstructure evolution of AlMg6Mn alloy during shear spinning

Deformation behavior and microstructure of AlMg6Mn alloy subjected to shear spinning were studied by means of mechanical characterization, optical and SEM＋EDS microscopy. Specimens were shear spun on an industrial spinning machine using different mandrels, providing reductions of wall thickness of 30%, 50% and 68%. The grain structure developed during shear spinning refines gradually. The grains elongate in axial direction with increase of reduction, and also stretches along circumferencial direction. Optimal combination of strength and elongation is observed. This is attributed to grain refinement and dislocation reactions with particles and atoms of Mg and Mn in solid solution.

Structure and properties of nanostructured Cu-13.2Al-5.1Ni shape memory alloy produced by melt spinning

The microstructure and properties of nanostructured Cu-13.2Al-5.1Ni shape memory alloy （SMA） were compared with those of initial coarse structure. The nanostructured Cu-Al-Ni ribbons were produced via rapid solidification using melt spinning technique. The structure and properties of both nanostructured and coarse-grain specimens were then characterized using XRD, SEM, AFM and DSC techniques. According to the obtained results, the nanostructured ribbons show one way shape memory effect. Besides, the formation of nanoparticles of γ2 （Cu9Al4） and the nanograins results in a significant decrease in the martensite-austenite transformation temperature. The produced nanostructure not only leads to a considerable increase in the recovered deformation but also results in the structure stability when it is subjected to deformation-recovery cycles.

Rotating extrusion technique and its effect on quality of aluminum alloy thin-plate weldments

A new technique named rotating extrusion was proposed that uses rotating extrusion action to rectify residual distortion of aluminum alloy thin-plate weldments to improve mechanical properties of welded joints. The basic principle and device of rotating extrusion were introduced. The residual distortion and stresses in rotating extrusion weldments were compared with those in conventional weldments. The differences in microstructure and mechanical properties between conventional welded joints and rotating extrusion welded joints were investigated and analyzed in order to make clear the effect of rotating extrusion on the performance of aluminum alloy weldments. Experimental results show that rotating extrusion can enhance the hardness and tensile strength of aluminum alloy welded joints evidently. This method has also potential effect on extending the life of welded structures.

Alternative flat coil design for electromagnetic forming using FEM

Electromagnetic forming （EMF） is a high velocity forming process that uses impulse magnetic force. Coil is an important component of EMF system which needs to be designed depending on application. Flat spiral coils are generally used for electromagnetic forming of sheet metals. However, with this type of coil the central portion of the workpiece experiences marginal magnetic force. This leads to in-sufficient deformation at this portion and other problems like air entrapment. In this study, a conceptual design of flat coil was proposed for better distribution of magnetic forces over the workpiece. Comparative analysis of distribution of magnetic force, magnetic field and current density using the proposed and the existing coil designs were carried out using FEM. The result indicates that the proposed coil design produces comparatively better magnetic force distribution over the workpiece. Calculation of self-inductance of such coils was also carried out and was compared with FE simulation.

Forward hot extrusion forming process of 4-lobe aluminum alloy helical surface rotor

The 4-lobe aluminum alloy helical surface rotors are widely applied in industry,such as superchargers.Generally,the conventional manufacturing processes of aluminum alloy helical surface are time consuming and costly.To make the manufacturing processes more flexible and economical,the forward hot extrusion process is proposed to form the 4-lobe aluminum alloy helical surface rotors.In this work,we implement both simulations and experiments to the forming process of the helical surface,of which the material is 6063 aluminum alloy.The forward hot extrusion process is simulated with finite element method in DEFORM-3D.Based on the simulation method,the influences of different extrusion parameters,such as extrusion temperature,extrusion speed and extrusion ratio,on the extrusion process are studied.According to the numerical simulation results,the optimal case is chosen to carry out the experiment.Furthermore,the experimental results show that the surface is smooth;the toothed fill is full;the twist angle in the length direction is evenly distributed;the value of twist angle is roughly in line with the design angle,which is mainly due to the modified die structure,having a positive and significant effect on the increment of twist angle.Therefore,the twist angle has an increase of about 76%,which verifies the modified die structure.

Quantitative analysis of orange peel during tension of 6063 alloy spun tubes

Severe surface roughening during plastic deforming of aluminum alloy parts can produce ＂orange peel＂ defects. To analyze ＂orange peel＂ of 6063 aluminum alloy tube quantificationally, the tensile tests of trapezoidal specimens were carried out. The tubes with different grain sizes were obtained by spinning and subsequent annealing heat treatment. The macroscopical behavior of surface roughening was characterized by surface roughness Ra using a laser scanning confocal microscope. The corresponding microscopic behavior was reflected by microstructures of specimens and in-situ observation using electron back-scattered diffraction（EBSD）. The obtained results show that the surface roughness increased firstly with increasing strain and then decreased slightly. There was a critical strain for aluminum alloy tube, below which ＂orange peel＂ defect would not occur. For the tube with a mean grain size of 80, 105, 130 and 175 μm, the critical strains were 10.17%, 5.74%, 3.15% and 1.62%, respectively. Meanwhile, the surface roughening behavior was produced by serious inhomogeneous deformation between grains as strain increased, and was aggravated as the grain size increased due to the larger local deformation in larger grains.

High-pressure torsion deformation process of bronze/niobium composite

The deformation process in the material volume under high-pressure torsion(HPT)was studied.As a model object for the observation of deformation process,we used a composite comprising a bronze matrix and niobium filaments.The arrangements of the niobium filaments in the bronze matrix and their size have regular geometry.This allows us to monitor and measure the displacement of the niobium filaments in the sample volume,which results from HTP.The bronze/niobium composite samples were subjected to HPT at room temperature and 6 GPa,and the number of revolutions N=1/4,1/2,1,2,3 and 5.It was shown that HPT with revolution number of 1 leads to the 360° rotation of entire sample volume without sample slippage.Similar deformational behavior during HPT can be expected for high-ductility metallic materials.The increase in the number of revolutions more than 2 leads to twisting the niobium filaments in the sample volume and the formation of 'vortex' multilayer structure.The mechanisms for the formation of such structures were discussed.

Optimum traveling and rotation speeds in friction stir welding for dissimilar Al alloys

Aluminum alloys are subjected to large deformation and decreased strength due to the high expansion modulus caused by heat effects during friction stir welding （FSW）.The optimum conditions for friction stir welding of 5052-O and 6061-T6 Al alloys were determined.The optimum traveling and rotation speeds were identified to be 61mm/min and 1600r/min using various mechanical characteristic evaluation methods.

Subtransus deformation mechanisms of TC11 titanium alloy with lamellar structure

Isothermal compression tests are applied to study the deformation mechanisms of TCll titanium alloy with lamellar structure under the deformation temperature range of 890-995 ℃ and strain rate range of 0.01-10 s^-1. According to the flow stress data obtained by compression tests, the deformation activations are calculated based on kinetics analysis of high temperature deformation, which are then used for deformation mechanism analysis combined with microstructure investigation. The results show that deformation mechanisms vary with deformation conditions： at low strain rate range, the deformation mechanism is mainly dislocation slip; at low temperature and high strain rate range, twinning is the main mechanism; at high temperature and high strain rate range, the deformation is mainly controlled by diffusion offl phase.

First-Principles Study on Electronic Structure and Half-Metallic Properties of CoNCN and NiNCN

We studied the electronic structure of the two new transition-metal carbodiimides CoNCN and NiNCN using first-principles method, which is based on density-functional theory （DFT）. The density of states （DOS）, the total energy of the cell and the spin magnetic moment of CoNCN and NiNCN were calculated. The calculations reveal that the compound CoNCN and NiNCN have hall-metallic properties in ferromagnetic ground state, and the spin magnetic moment per molecule is about 7.000 μB and 6.000 μB for CoNCN and NiNCN, respectively.

Effect of process parameters on tensile strength of friction stir welded cast A356 aluminium alloy joints

A356 is a high strength aluminium-silicon cast alloy used in food,chemical,marine,electrical and automotive industries.Fusion welding of this cast alloy will lead to many problems such as porosity,micro-fissuring,and hot cracking.However,friction stir welding（FSW） can be used to weld this cast alloy without above mentioned defects.An attempt was made to study the effect of FSW process parameters on the tensile strength of cast A356 aluminium alloy.Joints were made using different combinations of tool rotation speed,welding speed and axial force.The quality of weld zone was analyzed by macrostructure and microstructure analyses.Tensile strengths of the joints were evaluated and correlated with the weld zone hardness and microstructure.The joint fabricated using a rotational speed of 1000 r/min,a welding speed of 75 mm/min and an axial force of 5 kN showed a higher tensile strength compared to the other joints.