Effects of reflowing temperature and time on the alloy layer of tinplate and its electrochemical behavior in 3.5%NaCl solution were investigated by electrochemical measurements and surface characterization.It is found...Effects of reflowing temperature and time on the alloy layer of tinplate and its electrochemical behavior in 3.5%NaCl solution were investigated by electrochemical measurements and surface characterization.It is found that the amount of alloy layer increases with the increase of reflowing temperature and time.Then the corrosion potential of detinned tinplate shifts positively and the corrosion rate decreases.After being coupled with tin,the detinned tinplate acts as cathode and tin acts as anode initially.However,after being exposed for some time,the potential shifts of both detinned tinplate and tin reverse the polarity of the coupling system.The galvanic current density decreases with the increase of reflowing temperature and time.展开更多
Ni-Cr alloys with mass fraction of 1.4%23.9%Cr, 76.1%98.6%Ni, and hardness of 70.5 80.5HR were electrodeposited on aluminium substrate from the trivalent chromium sulphate-chloride solution using citric acid as comple...Ni-Cr alloys with mass fraction of 1.4%23.9%Cr, 76.1%98.6%Ni, and hardness of 70.5 80.5HR were electrodeposited on aluminium substrate from the trivalent chromium sulphate-chloride solution using citric acid as complexing agent. The aluminium was pretreated by means of degreasing and eroding, polishing and twice chemical immersion of zinc. The effects of electrodeposition parameters such as current density, temperature, pH value and bath concentration on the composition and hardness of deposits were investigated. The results show that the Cr content increases with the increase of current density and the decrease of temperature, and that it increases with the increase of pH value to a maximum and then decreases. The increase of Cr content leads to the increase of hardness of the Ni-Cr layers. The deposits with high Cr content are of good corrosion resistance. Good adherence of Ni-Cr deposits to aluminium substrate is obtained. The Ni-Cr alloys are the Ni-Cr solid solution with fcc crystalline structure. The Ni-Cr alloy deposits are fine, bright and smooth and compact.展开更多
The fatigue behavior of press hardened Al-Si coated high strength steel has been investigated,and the fatigue strength turns out to be about 1 000 MPa.Surface morphology of fractured and non-fractured specimen has bee...The fatigue behavior of press hardened Al-Si coated high strength steel has been investigated,and the fatigue strength turns out to be about 1 000 MPa.Surface morphology of fractured and non-fractured specimen has been observed,and the coating shows significant influence on the fatigue behavior.The difference of elastic modulus between coating and substrate led to the main cracks perpendicular to the loading direction.The coating close to fracture exfoliated thinly,while the coating far away from the fracture kept integrated.Though the specimen was polished to obtain high surface quality,3 types of cracks occurred during the fatigue test.What’s more,inclusion particles were proved to play a crucial role in causing these cracks.展开更多
基金Projects (50771092,21073162) supported by the National Natural Science Foundation of China
文摘Effects of reflowing temperature and time on the alloy layer of tinplate and its electrochemical behavior in 3.5%NaCl solution were investigated by electrochemical measurements and surface characterization.It is found that the amount of alloy layer increases with the increase of reflowing temperature and time.Then the corrosion potential of detinned tinplate shifts positively and the corrosion rate decreases.After being coupled with tin,the detinned tinplate acts as cathode and tin acts as anode initially.However,after being exposed for some time,the potential shifts of both detinned tinplate and tin reverse the polarity of the coupling system.The galvanic current density decreases with the increase of reflowing temperature and time.
基金Project (59674025) supported by the National Natural Science Foundation of China
文摘Ni-Cr alloys with mass fraction of 1.4%23.9%Cr, 76.1%98.6%Ni, and hardness of 70.5 80.5HR were electrodeposited on aluminium substrate from the trivalent chromium sulphate-chloride solution using citric acid as complexing agent. The aluminium was pretreated by means of degreasing and eroding, polishing and twice chemical immersion of zinc. The effects of electrodeposition parameters such as current density, temperature, pH value and bath concentration on the composition and hardness of deposits were investigated. The results show that the Cr content increases with the increase of current density and the decrease of temperature, and that it increases with the increase of pH value to a maximum and then decreases. The increase of Cr content leads to the increase of hardness of the Ni-Cr layers. The deposits with high Cr content are of good corrosion resistance. Good adherence of Ni-Cr deposits to aluminium substrate is obtained. The Ni-Cr alloys are the Ni-Cr solid solution with fcc crystalline structure. The Ni-Cr alloy deposits are fine, bright and smooth and compact.
基金National Natural Science Foundation of China (No. 51275185, No. 51405171) National Basic Research Program of China (No. 2010CB630802-3)+1 种基金 Graduate Innovation and Entrepreneurship Fund of Huazhong University of Science and Technology (No. 0109070112) Fundamental Research Funds for the Central Universities (No. 0118110621)
文摘The fatigue behavior of press hardened Al-Si coated high strength steel has been investigated,and the fatigue strength turns out to be about 1 000 MPa.Surface morphology of fractured and non-fractured specimen has been observed,and the coating shows significant influence on the fatigue behavior.The difference of elastic modulus between coating and substrate led to the main cracks perpendicular to the loading direction.The coating close to fracture exfoliated thinly,while the coating far away from the fracture kept integrated.Though the specimen was polished to obtain high surface quality,3 types of cracks occurred during the fatigue test.What’s more,inclusion particles were proved to play a crucial role in causing these cracks.