对某钴厂黄金工段沉金工艺的改进

沉金是将金粒（含金化合物或单质金）从含金溶液（金浸液）中沉淀出来的工艺。沉金是提炼黄金的重要工序，金泥（含金固体混合物）品位太低，不仅增加了黄金精炼难度，也影响黄金的回收率，为此，某钴厂沉金工序规定了几项主要技术指标，见表１。表１沉金工序主要技术指标...

Security Risk Analysis on the Nutrients and Heavy Metals of Biogas Slurry in Agricultural Application

[Objective] This study was to provide scientific basis for the security application of biogas slurry in agriculture through the analysis on the security risk of nu- trients and heavy metals of biogas slurry in agricultural application. [Method] The components of the slurry produced by the anaerobic digestion of straws and manures were systematically analyzed. Different types of biogas slurry with different concentrations were used to conduct the germination test. [Result] The types and proportions of raw materials, and alkali pretreatment affected the compositions and nature of the biogas slurry. Alkali pretreatment could reduce the contents of heavy metals and improved the contents of nitrogen, phosphorous, organic matter and available components. The contents of heavy metals in the biogas slurry were as follows： Cd of 8.76 μg/kg, Cr of 52μg/kg, Pb of 210 μg/kg, Hg of 0.512 μg/kg, As of 140μg/kg, and the contents of Cu and Zn were the highest among the heavy metals, respectively, 279 and 680 μg/kg. All the contents were under the limit standards of the urban wastes for agricultural use. The germination tests of the seeds verified that the slurry with the concentration of lower than 5% could accelerate the germination, while the salt stress could inhibit the growth of seedlings in the slurry. [Conclusion] When the dung are uses as the raw materials for fermentation, appropriate control should be conducted on the feeding proportion or the heavy metals should be pre-removed; when the slurry is used as the liquid fertilizer to apply in the farmland, the dilution or desalting treatment should be conducted at first.

Surface pretreatment of Mg alloys prior to Al electroplating in TMPAC-AlCl_3 ionic liquids

It is difficult to directly electroplate Al on Mg alloys. The effects of pretreatment parameters on the corrosion resistance of films obtained on AZ31 Mg alloy surface were studied by using potentiodynamic polarization curves, to produce a compact interfacial layer as zinc-immersion deposition. After the substrate was pretreated under optimized conditions, aluminum was electrodeposited on AZ31 from TMPAC-AlCl3 room temperature ionic liquids. The depositions were characterized by scanning electron microscope equipped with energy dispersion X-ray. The results show that the traditional pretreatment of Mg alloys was successfully used for the Al-electroplating process from TMPAC-AlCl3 ionic liquids. The entire procedure includes alkaline cleaning, chemical pickling, surface activation （400 mL/L HF acid, 10 min）, zinc-immersion （20 min） and anhydrous treatment. A relatively compact zinc-immersion film was prepared on the substrate surface. A silvery-colored satin aluminum deposition was obtained on AZ31 from TMPAC-AlCl3 using direct current plating.

Corrosion and leaching behaviors of Sn-based alloy in simulated soil solutions

The corrosion and leaching behaviors of Sn-0.75Cu solders and joints in NaCl-Na2SO4 and NaCl-Na2SO4-Na2CO3 simulated soil solutions were investigated compared with those in NaCl solution, aiming to assess the potential risk from the electronic-waste disposed in soil. The leaching kinetics of Sn reveals that the leaching amount of Sn increases with increasing the time. The amount of Sn leached from the joint is the largest in NaCl solution.SO4^2- and CO3^2- inhibit the leaching of Sn from the joints, but accelerate that from the solders. Meanwhile, the corrosion layer of the joint in NaCl solution is more porous, and those immersed in NaCl-Na2SO4 and NaCl-Na2SO4-Na2CO3 solutions are compact. The XRD results indicate that the main corrosion products on the solders and joints surfaces are comprised of tin oxide, tin chloride and tin chloride hydroxide. The potentiodynamic polarization measurements for the solders were discussed in the simulated soil solutions.

Removal of Pb^(2+) and Cd^(2+) by adsorption on clay-solidified grouting curtain for waste landfills

Pb2+ and Cd2+ in leachate were adsorbed on clay-solidified grouting curtain for waste landfills with equilibrium experiment. The cation exchange capacity was determined with ammonium acetate. And the concentration of heavy metal cations in leachate was determined with atomic absorption spectrophotometer. Their equilibrium isotherms were measured, and the experimental isotherm data were analyzed by using Freundlich and Langmuir models. The results show that the adsorption capacities of the heavy metal cations are closely related to the compositions of clay-solidified grouting curtain, and the maximum adsorption appears at the ratio of cement to clay of 2∶4 in the experimental conditions. At their maximum adsorption and pH 5.0, the adsorption capacities of Pb 2+ and Cd 2+ are 16.19mg/g and 1.21mg/g. The competitive adsorption coefficients indicate that the adsorption of clay-solidified grouting curtain for Pb2+ is stronger than that for Cd 2+ . The adsorption process conforms to Freundlich’s model with related coefficient higher than 0.996.

Retention of clay-solidified grouting curtain to Cd^(2+), Pb^(2+) and Hg^(2+) in landfill of municipal solid waste

The effects of components and their ratio of grouts on anti-seepage capability of clay-solidified grouting curtain and its permeability of heavy metal cations were investigated by permeating experiments, using reactive solute transport model to study the permeation of heavy metals (Cd2+, Pb2+ and Hg2+). The study of permeating for different mixture ratios of cement and clay indicates that hydraulic conductivity of clay-solidified grouting curtain with different ratios of solid to liquid or with the same ratio of solid to liquid but with different ratios of cement to clay is changed. The laboratory simulation test results also show that precipitates produced in heavy metal cation migration process in curtain block up water flowing passage which makes the hydraulic conductivity of the solution-permeated curtain decrease with the leakage time. The permeation velocities for different heavy metal cations vary with ionic concentration, exchange capacity and ion radius etc. The test results indicate that the permeation rapidity order of heavy metals cations in clay-solidified grouting curtain is Hg2+>Pb2+ in the same experimental circumstance. In addition, permeability for different mixture ratios and antisepsis capabilities of clay-solidified grouting curtain were studied in tests.

Design of the Metal Precursors Molecular Structures in Impregnating Solutions for Preparation of Efficient Ni Mo/Al_2O_3 Hydrodesulfurization Catalysts

The molecular structures of metal precursors in the impregnating solution were designed so as to prepare efficient Ni Mo/Al_2O_3 hydrodesulfurization(HDS) catalysts. At first, five typical impregnating solutions were designed; the existing metal precursors, such as [Mo4(citrate)2O11]^(4-)-like, [P2Mo18O62]^(6-)-like and [P2Mo5O23]^(6-)-like species in the solutions were confirmed by laser Raman spectroscopy(LRS). The UV-Vis spectra results indicated that the solutions containing both phosphoric acid and citric acid could change the existing form of nickel species. Five corresponding Ni Mo/Al_2O_3 catalysts were prepared by the incipient wetness impregnation method. The LRS analysis results of dried catalysts showed that the above metal precursors could be partly retained on alumina support after impregnation and drying, although the interface reaction between different metal precursors and alumina support unavoidably took place. Then the catalysts were sulfided and characterized by N2 physisorption, TEM and XPS analyses. The results showed that different metal precursors in impregnating solution could mainly result in the difference in both the morphology of(Ni)Mo S2 slabs and the promoting effect of Ni species. The catalyst prepared mainly with [P2Mo5O23]^(6-)-like species used as precursors exhibited worse dispersion of(Ni)Mo S2 slabs and lower ratio of Ni–Mo–S active phases than the one with [Mo4(citrate)2O11]^(4-)-like species. Promisingly, the catalyst prepared with co-existing [Mo4(citrate)2O11]^(4-)-like, [P2Mo18O62]^(6-)-like and [P2Mo5O23]^(6-)-like species showed better hydrodesulfurization activity for 4,6-DMDBT thanks to its more well-dispersed Ni–Mo–S active phases.