This study presents the first documentation work on recent benthic foraminifers of Oman coasts, especially of the northern part of Sultanate at Sawadi and the southern part at Janoof Tidal Creek near Taqah-Salalah bea...This study presents the first documentation work on recent benthic foraminifers of Oman coasts, especially of the northern part of Sultanate at Sawadi and the southern part at Janoof Tidal Creek near Taqah-Salalah beach. Eleven samples were collected from both localities. Twenty-nine species of benthonic Foraminifera belonging to 20 genera are retrieved, identified and illustrated herein. The study areas show the interaction in land and sea. Lagoons with normal marine hypersaline inhabited with sea grass and Mangrove-swamps. Mainly calcareous porcellaneous and hyaline walled foraminifers are abundant. Environmentally, the Janoof Tidal Creek shows better condition than Sawadi Tidal Creek as reflected by the more diverse and high abundance of foraminiferal taxa at the former locality. Both water bodies are free of toxic-heavy elements as evidenced by the lack of any abnormal foraminiferal test.展开更多
This paper presents a study on the effects of phase transitions on the mantle convection of Venus in a three-dimensional （3D） spherical shell domain. Our model includes strong depth- and temperature-dependent viscos...This paper presents a study on the effects of phase transitions on the mantle convection of Venus in a three-dimensional （3D） spherical shell domain. Our model includes strong depth- and temperature-dependent viscosity and exothermic phase change from olivine to spinel as well as endothermic phase change from spinel to perovskite. From extensive numerical simulations of the effects of Rayleigh number （Ra）, and the Clapeyron slopes and depths of phase changes, we found the following： （1） The endothermic phase change prevents mass flow through the interface. Increasing the absolute value of the Clapeyron slopes decreases radial mass flux and normalized radial mass flux at the endotbermic phase boundary, and decreases the number of mantle plumes. In other words, mass flow through the phase boundary decreases. The inhibition influence of phase changes increases, as do convective wavelengths. （2） Increasing Ra also increases the convective wavelength and decreases the number of mantle plumes, but it has less influence on the mass exchange. As Ra increases, the convective vigor increases along with the radial mass flux and the mass flow through the phase boundary; however, the normalized mass flux through the phase boundary varies little with Ra, which is different from the conclusion that increasing Ra will greatly increase the inhibition of mass flow through the phase boundary based on two-dimensional （2D） modeling. （3） Increasing the depth of endothermic phase change will slightly decrease the number of mantle plumes, but has little effect on the mass flow through the phase boundary. Consistent with previous studies, our results show that the phase change from spinel to perovskite could inhibit the mass flow through the phase boundary, but they also show that the buildup of hot materials under the endothermic phase boundary in the 3D model could not be so large as to cause strong episodic overturns of mantle materials, which is quite different from previous 2D studies. Our results suggest that it is difficult for phase changes to cause significant magmatism on Venus; in other words, phase changes may not be the primary cause of catastrophic resurfacing on Venus.展开更多
Co_(2)VO_(4) with Co tetrahedrons and octahedrons of transition metal oxides has achieved progress in electrocatalysts and batteries.However,high metal-metal interactions make it challenging to maintain high reactivit...Co_(2)VO_(4) with Co tetrahedrons and octahedrons of transition metal oxides has achieved progress in electrocatalysts and batteries.However,high metal-metal interactions make it challenging to maintain high reactivity as well as increase the conductivity and stability of supercapacitors.In this work,spinel-structured CoZn_(0.5)V_(1.5)O_(4) with a high specific surface area was synthesized through an ion-exchange process from the metal-organic frameworks of zinc-cobalt.Density functional theory calculations indicate that the replacement of transition metal by Zn can decrease the interaction between the transition metals,leading to a downshift in the π^(∗)-orbitals(V-O)and half-filled a_(1g) orbitals near the Fermi level,thus increasing the conductivity and stability of CoZn_(0.5)V_(1.5)O_(4).As a supercapacitor electrode,CoZn_(0.5)V_(1.5)O_(4) exhibits high cycling durability(99.4% capacitance retention after 18,000 cycles)and specific capacitance(1100mFcm^(-2) at 1mAcm^(-2)).This work provides the possibility of designing octahedral and tetrahedral sites in transition metal oxides to improve their electrochemical performance.展开更多
文摘This study presents the first documentation work on recent benthic foraminifers of Oman coasts, especially of the northern part of Sultanate at Sawadi and the southern part at Janoof Tidal Creek near Taqah-Salalah beach. Eleven samples were collected from both localities. Twenty-nine species of benthonic Foraminifera belonging to 20 genera are retrieved, identified and illustrated herein. The study areas show the interaction in land and sea. Lagoons with normal marine hypersaline inhabited with sea grass and Mangrove-swamps. Mainly calcareous porcellaneous and hyaline walled foraminifers are abundant. Environmentally, the Janoof Tidal Creek shows better condition than Sawadi Tidal Creek as reflected by the more diverse and high abundance of foraminiferal taxa at the former locality. Both water bodies are free of toxic-heavy elements as evidenced by the lack of any abnormal foraminiferal test.
基金supported by National Natural Science Foundation of China(Grant Nos.41474082,91014005)Knowledge Innovation Program of the Chinese Academy of Sciences(Grant No.KZCX2-YW-QN507)t
文摘This paper presents a study on the effects of phase transitions on the mantle convection of Venus in a three-dimensional （3D） spherical shell domain. Our model includes strong depth- and temperature-dependent viscosity and exothermic phase change from olivine to spinel as well as endothermic phase change from spinel to perovskite. From extensive numerical simulations of the effects of Rayleigh number （Ra）, and the Clapeyron slopes and depths of phase changes, we found the following： （1） The endothermic phase change prevents mass flow through the interface. Increasing the absolute value of the Clapeyron slopes decreases radial mass flux and normalized radial mass flux at the endotbermic phase boundary, and decreases the number of mantle plumes. In other words, mass flow through the phase boundary decreases. The inhibition influence of phase changes increases, as do convective wavelengths. （2） Increasing Ra also increases the convective wavelength and decreases the number of mantle plumes, but it has less influence on the mass exchange. As Ra increases, the convective vigor increases along with the radial mass flux and the mass flow through the phase boundary; however, the normalized mass flux through the phase boundary varies little with Ra, which is different from the conclusion that increasing Ra will greatly increase the inhibition of mass flow through the phase boundary based on two-dimensional （2D） modeling. （3） Increasing the depth of endothermic phase change will slightly decrease the number of mantle plumes, but has little effect on the mass flow through the phase boundary. Consistent with previous studies, our results show that the phase change from spinel to perovskite could inhibit the mass flow through the phase boundary, but they also show that the buildup of hot materials under the endothermic phase boundary in the 3D model could not be so large as to cause strong episodic overturns of mantle materials, which is quite different from previous 2D studies. Our results suggest that it is difficult for phase changes to cause significant magmatism on Venus; in other words, phase changes may not be the primary cause of catastrophic resurfacing on Venus.
基金supported by the National Natural Science Foundation of China(51872204,52072261 and 22011540379)the National Key Research and Development Program of China(2017YFA0204600)+1 种基金Shanghai Social Development Science and Technology Project(20dz1201800)Shanghai Sailing Program(21YF1430900).
文摘Co_(2)VO_(4) with Co tetrahedrons and octahedrons of transition metal oxides has achieved progress in electrocatalysts and batteries.However,high metal-metal interactions make it challenging to maintain high reactivity as well as increase the conductivity and stability of supercapacitors.In this work,spinel-structured CoZn_(0.5)V_(1.5)O_(4) with a high specific surface area was synthesized through an ion-exchange process from the metal-organic frameworks of zinc-cobalt.Density functional theory calculations indicate that the replacement of transition metal by Zn can decrease the interaction between the transition metals,leading to a downshift in the π^(∗)-orbitals(V-O)and half-filled a_(1g) orbitals near the Fermi level,thus increasing the conductivity and stability of CoZn_(0.5)V_(1.5)O_(4).As a supercapacitor electrode,CoZn_(0.5)V_(1.5)O_(4) exhibits high cycling durability(99.4% capacitance retention after 18,000 cycles)and specific capacitance(1100mFcm^(-2) at 1mAcm^(-2)).This work provides the possibility of designing octahedral and tetrahedral sites in transition metal oxides to improve their electrochemical performance.
