内蒙古某高硫金矿石嵌布粒度微细,金品位2.21 g/t,金以包裹金为主,并可综合回收硫。为合理利用该金矿资源,对其进行选矿试验。结果表明,原矿粗磨至-0.074 mm 65%后进行1粗1精2扫金硫混合浮选,混合精矿再磨至-0.045 mm 85%进行1粗2精1扫...内蒙古某高硫金矿石嵌布粒度微细,金品位2.21 g/t,金以包裹金为主,并可综合回收硫。为合理利用该金矿资源,对其进行选矿试验。结果表明,原矿粗磨至-0.074 mm 65%后进行1粗1精2扫金硫混合浮选,混合精矿再磨至-0.045 mm 85%进行1粗2精1扫金硫分离浮选,最终可获得金品位48.58 g/t、回收率86.16%的金精矿和硫品位55.26%、回收率58.57%的硫精矿,实现了该难选金矿的高效回收利用,可供其开发利用参考。展开更多
The presence of a limited amount of H2S in H2-rich feed adversely affects the Pd-Cu membrane permeation performance due to the sulphidization of the membrane surface. A theoretical model was proposed to predict the S-...The presence of a limited amount of H2S in H2-rich feed adversely affects the Pd-Cu membrane permeation performance due to the sulphidization of the membrane surface. A theoretical model was proposed to predict the S-tolerant performance of the Pd-Cu membranes in presence of H2S under the industrial water-gas-shift(WGS) reaction conditions. The ideas of surface coverage and competitive adsorption thermodynamics of H2S and H2 on Pd-Cu surface were introduced in the model. The surface sulphidization of the Pd-Cu membranes mainly depended on the pressure ratio of H2S to H2, temperature and S-adsorbed surface coverage, i.e., the occurrence of sulphidization on the surface was not directly related with the bulk compositions and structures [body centered cubic and face centered cubic(bcc or fcc)] of Pd-Cu alloy membranes because of the surface segregation phenomena. The resulting equilibrium equations for the H2S adsorption/sulphidization reactions were solved to calculate the pressure ratio of H2S to H2 over a wide range of temperatures. A validation of the model was performed through a comparison between lots of literature data and the model calculations over a rather broad range of operating conditions. An extremely good agreement was obtained in the different cases, and thus, the model can serve to guide the development of S-resistant Pd alloy membrane materials for hydrogen separation.展开更多
The presented results are related to the leaching of Pb-Zn-Cu-Fe sulphide concentrate, obtained from barite-sulphide ores, under the elevated temperatures and pressures in an autoclave. The leaching process was perfor...The presented results are related to the leaching of Pb-Zn-Cu-Fe sulphide concentrate, obtained from barite-sulphide ores, under the elevated temperatures and pressures in an autoclave. The leaching process was performed using the sulphur acid solution with the oxygen addition for the separation of the targeted metals from the polymetallic concentrate. In this process influences of various parameters were discussed and then correlated to the leached metals, zinc, copper and iron. Zinc, copper and iron were dissolved in a solution, while lead remained as insoluble in the leach residue. The best leaching results were determined under the temperature of 210 ℃ during the 240 min. Obtained leaching degrees were 98% zinc, 95% copper and 96% iron.展开更多
An ion-selective electrode(ISE)-based immunoassay has been innovatively designed for the sensitive detection of liver cancer biomarker(alpha-fetoprotein,AFP),using metal sulfide quantum dot(QD)-based nano labels.Cd S ...An ion-selective electrode(ISE)-based immunoassay has been innovatively designed for the sensitive detection of liver cancer biomarker(alpha-fetoprotein,AFP),using metal sulfide quantum dot(QD)-based nano labels.Cd S QDs-aggregated PAMAM dendrimer(QD-DE)was first synthesized and functionalized with polyclonal rabbit anti-human AFP antibodies.Thereafter,a sandwich immunoreaction was implemented on monoclonal mouse anti-human AFP antibody-coated microplate by using antibody-functionalized QD-DE as the secondary antibody.Accompanying the immunocomplex,subsequent potentiometric detection of cadmium ion dissolved from the QD-DE under acidic condition was conducted on a portable cadmium ion-selective electrode(Cd-ISE).Results revealed that the electrode potential of the Cd-ISE increased with the increment of AFP concentration from 0.1 to 100 ng m L^(-1)at a detection limit(LOD)of 68 pg m L^(-1).The relative standard deviations(RSD)were below9.09%and 10.54%for the intra-and inter-assay,respectively.Additionally,six human serum specimens were determined on CdISE-based immunosensor by using commercial human AFP ELISA kit as the reference,and gave good relationship between two methods.Importantly,Cd-ISE-based immunoassay offers the promise for simple and cost-effective screening of disease-related biomarkers.展开更多
文摘内蒙古某高硫金矿石嵌布粒度微细,金品位2.21 g/t,金以包裹金为主,并可综合回收硫。为合理利用该金矿资源,对其进行选矿试验。结果表明,原矿粗磨至-0.074 mm 65%后进行1粗1精2扫金硫混合浮选,混合精矿再磨至-0.045 mm 85%进行1粗2精1扫金硫分离浮选,最终可获得金品位48.58 g/t、回收率86.16%的金精矿和硫品位55.26%、回收率58.57%的硫精矿,实现了该难选金矿的高效回收利用,可供其开发利用参考。
基金Supported by the National Natural Science Foundation of China(50972038)the National Natural Science Foundation of Hebei Province(B2009000739,B2014209258)Science and Technology Support Program of Hebei Province(09215142D)
文摘The presence of a limited amount of H2S in H2-rich feed adversely affects the Pd-Cu membrane permeation performance due to the sulphidization of the membrane surface. A theoretical model was proposed to predict the S-tolerant performance of the Pd-Cu membranes in presence of H2S under the industrial water-gas-shift(WGS) reaction conditions. The ideas of surface coverage and competitive adsorption thermodynamics of H2S and H2 on Pd-Cu surface were introduced in the model. The surface sulphidization of the Pd-Cu membranes mainly depended on the pressure ratio of H2S to H2, temperature and S-adsorbed surface coverage, i.e., the occurrence of sulphidization on the surface was not directly related with the bulk compositions and structures [body centered cubic and face centered cubic(bcc or fcc)] of Pd-Cu alloy membranes because of the surface segregation phenomena. The resulting equilibrium equations for the H2S adsorption/sulphidization reactions were solved to calculate the pressure ratio of H2S to H2 over a wide range of temperatures. A validation of the model was performed through a comparison between lots of literature data and the model calculations over a rather broad range of operating conditions. An extremely good agreement was obtained in the different cases, and thus, the model can serve to guide the development of S-resistant Pd alloy membrane materials for hydrogen separation.
文摘The presented results are related to the leaching of Pb-Zn-Cu-Fe sulphide concentrate, obtained from barite-sulphide ores, under the elevated temperatures and pressures in an autoclave. The leaching process was performed using the sulphur acid solution with the oxygen addition for the separation of the targeted metals from the polymetallic concentrate. In this process influences of various parameters were discussed and then correlated to the leached metals, zinc, copper and iron. Zinc, copper and iron were dissolved in a solution, while lead remained as insoluble in the leach residue. The best leaching results were determined under the temperature of 210 ℃ during the 240 min. Obtained leaching degrees were 98% zinc, 95% copper and 96% iron.
基金supported by the National Natural Science Foundation of China (21675029, 21665009, 21475025)the Key Joint Project for Health Education of Fujian Province (WKJ2016-2-15)the Program for Changjiang Scholars and Innovative Research Team in University (IRT15R11)
文摘An ion-selective electrode(ISE)-based immunoassay has been innovatively designed for the sensitive detection of liver cancer biomarker(alpha-fetoprotein,AFP),using metal sulfide quantum dot(QD)-based nano labels.Cd S QDs-aggregated PAMAM dendrimer(QD-DE)was first synthesized and functionalized with polyclonal rabbit anti-human AFP antibodies.Thereafter,a sandwich immunoreaction was implemented on monoclonal mouse anti-human AFP antibody-coated microplate by using antibody-functionalized QD-DE as the secondary antibody.Accompanying the immunocomplex,subsequent potentiometric detection of cadmium ion dissolved from the QD-DE under acidic condition was conducted on a portable cadmium ion-selective electrode(Cd-ISE).Results revealed that the electrode potential of the Cd-ISE increased with the increment of AFP concentration from 0.1 to 100 ng m L^(-1)at a detection limit(LOD)of 68 pg m L^(-1).The relative standard deviations(RSD)were below9.09%and 10.54%for the intra-and inter-assay,respectively.Additionally,six human serum specimens were determined on CdISE-based immunosensor by using commercial human AFP ELISA kit as the reference,and gave good relationship between two methods.Importantly,Cd-ISE-based immunoassay offers the promise for simple and cost-effective screening of disease-related biomarkers.
