Recently,the spin-orbit coupling and spin current in nanodevice have been investigated extensively.In this paper,we review the recent progresses in this field.We introduce the real space Hamiltonian and the second qua...Recently,the spin-orbit coupling and spin current in nanodevice have been investigated extensively.In this paper,we review the recent progresses in this field.We introduce the real space Hamiltonian and the second quantization Hamiltonian of a typical quantum transport mesoscopic device,metal-QD-metal configuration,containing the spin-orbit interaction,e-e interactions,and magnetic field.Some noteworthy effects(e.g.,the spin-polarized current,spin accumulation,persistent spin current) originated from the spin-orbit interaction are reviewed,and the electric field induced by spin-current is mentioned.Lastly,we introduce some unsolved problems and prospects in this field.展开更多
The rational design and synthesis of hybrid-type electrode nanomaterials are significant for their diverse applications,including their potential usage as high-efficiency nanoarchitectures for supercapacitors(SCs)as a...The rational design and synthesis of hybrid-type electrode nanomaterials are significant for their diverse applications,including their potential usage as high-efficiency nanoarchitectures for supercapacitors(SCs)as a class of promising energy-storage systems for powering next-generation electric vehicles and electronic devices.Here,we reported a facile and controllable synthesis of core-shell Ni_(3)S_(2)@NiWO_(4)nanoarrays to fabricate a freestanding electrode for hybrid SCs.Impressively,the as-prepared freestanding Ni_(3)S_(2)@NiWO_(4)electrode presents an ultrahigh areal capacity of 2032μA h cm^(-2)at 5 mA cm^(-2),and a capacity retention of 63.6%even when the current density increased up to 50 mA cm^(-2).Remarkably,the Ni_(3)S_(2)@NiWO_(4)nanoarraybased hybrid SC delivers a maximum energy density of 1.283 mW h cm^(-2)at 3.128 mW cm^(-2)and a maximum power density of 41.105 mW cm^(-2)at 0.753 mW h cm^(-2).Furthermore,the hybrid SC exhibits a capacity retention of 89.6%even after continuous 10,000 cycles,proving its superior stability.This study provides a facile pathway to rationally design a variety of core-shell metal nanostructures for high-performance energy storage devices.展开更多
基金supported by China National Funds for Distinguished Young Scientists(Grant No.10525418)the National Natural Science Foundation of China(Grant Nos.10734110 and 11121063)the National Basic Research Program of China(Grant No.2012CB921303)
文摘Recently,the spin-orbit coupling and spin current in nanodevice have been investigated extensively.In this paper,we review the recent progresses in this field.We introduce the real space Hamiltonian and the second quantization Hamiltonian of a typical quantum transport mesoscopic device,metal-QD-metal configuration,containing the spin-orbit interaction,e-e interactions,and magnetic field.Some noteworthy effects(e.g.,the spin-polarized current,spin accumulation,persistent spin current) originated from the spin-orbit interaction are reviewed,and the electric field induced by spin-current is mentioned.Lastly,we introduce some unsolved problems and prospects in this field.
基金the National Natural Science Foundation of China(91963113)。
文摘The rational design and synthesis of hybrid-type electrode nanomaterials are significant for their diverse applications,including their potential usage as high-efficiency nanoarchitectures for supercapacitors(SCs)as a class of promising energy-storage systems for powering next-generation electric vehicles and electronic devices.Here,we reported a facile and controllable synthesis of core-shell Ni_(3)S_(2)@NiWO_(4)nanoarrays to fabricate a freestanding electrode for hybrid SCs.Impressively,the as-prepared freestanding Ni_(3)S_(2)@NiWO_(4)electrode presents an ultrahigh areal capacity of 2032μA h cm^(-2)at 5 mA cm^(-2),and a capacity retention of 63.6%even when the current density increased up to 50 mA cm^(-2).Remarkably,the Ni_(3)S_(2)@NiWO_(4)nanoarraybased hybrid SC delivers a maximum energy density of 1.283 mW h cm^(-2)at 3.128 mW cm^(-2)and a maximum power density of 41.105 mW cm^(-2)at 0.753 mW h cm^(-2).Furthermore,the hybrid SC exhibits a capacity retention of 89.6%even after continuous 10,000 cycles,proving its superior stability.This study provides a facile pathway to rationally design a variety of core-shell metal nanostructures for high-performance energy storage devices.
