Co, Ni, Cr and V in 25 typical soils of China were fractionated into exchangeable, carbonate bound (calcareous soils), Mn oxide bound, organically bound, amorphous Fe oxide bound, crystalline Fe oxide bound and residu...Co, Ni, Cr and V in 25 typical soils of China were fractionated into exchangeable, carbonate bound (calcareous soils), Mn oxide bound, organically bound, amorphous Fe oxide bound, crystalline Fe oxide bound and residual forms using a seven-step sequential extraction procedure, so as to study the distribution of chemical forms of these metals as well as the effects of soil properties on the distribution. The results showed that most of soil Co, Ni, Cr and V were present in residual forms, and the distribution ratio averaged 48.2% for Co, 53.0% for Ni, 81.5% for Cr and 68.7% for V. The speciation of heavy metals was greatly influenced by soil physico-chemical properties and the chemistry of elements. The results also indicated that the recovery of metal elements by the sequential extraction procedure was satisfactory, with the relative difference between the sum of seven forms and the total content in soils averaging 9.5% for Co, 12.8% for Ni, 6.6% for Cr and 7.2% for V.展开更多
During the reaction between calcium sorbents and SO2, calcium sorbents are first calcined and converted into CaO. CaO can be obtained by calcining Ca(OH)2or CaCO3. The porosity of the sorbent is increased because of c...During the reaction between calcium sorbents and SO2, calcium sorbents are first calcined and converted into CaO. CaO can be obtained by calcining Ca(OH)2or CaCO3. The porosity of the sorbent is increased because of calcination and is decreased because of sulfurization. In the calcination process H2O or CO2 is escaped from the particles and pores are formed in particles. The reaction or convert rate of CaO is influenced strongly by the pore structure characters. From Ca(OH)2 to CaO the escape velocity of H2O or its mass transfer is one of the key factors influencing the pore forming. During calcination process different healing velocity, different heating time and temperature were suggested. The temperature rising rate and calcining temperature play important role to the pore structure. The convert rates of CaO obtained through different calcining conditions were investigated experimentally. Some interesting results were showed that the calcium utilization of CaO particles is determined not only by the special surface area and total pore volume, but also by pore-size distribution. The main factor influencing the sulfation is the pore diameter distribution at lower sulfation temperature. For higher reaction temperature specific volume is the important reason. But pore-size distribution is strongly influenced by heat flux and temperature in the calcining process.展开更多
文摘Co, Ni, Cr and V in 25 typical soils of China were fractionated into exchangeable, carbonate bound (calcareous soils), Mn oxide bound, organically bound, amorphous Fe oxide bound, crystalline Fe oxide bound and residual forms using a seven-step sequential extraction procedure, so as to study the distribution of chemical forms of these metals as well as the effects of soil properties on the distribution. The results showed that most of soil Co, Ni, Cr and V were present in residual forms, and the distribution ratio averaged 48.2% for Co, 53.0% for Ni, 81.5% for Cr and 68.7% for V. The speciation of heavy metals was greatly influenced by soil physico-chemical properties and the chemistry of elements. The results also indicated that the recovery of metal elements by the sequential extraction procedure was satisfactory, with the relative difference between the sum of seven forms and the total content in soils averaging 9.5% for Co, 12.8% for Ni, 6.6% for Cr and 7.2% for V.
文摘During the reaction between calcium sorbents and SO2, calcium sorbents are first calcined and converted into CaO. CaO can be obtained by calcining Ca(OH)2or CaCO3. The porosity of the sorbent is increased because of calcination and is decreased because of sulfurization. In the calcination process H2O or CO2 is escaped from the particles and pores are formed in particles. The reaction or convert rate of CaO is influenced strongly by the pore structure characters. From Ca(OH)2 to CaO the escape velocity of H2O or its mass transfer is one of the key factors influencing the pore forming. During calcination process different healing velocity, different heating time and temperature were suggested. The temperature rising rate and calcining temperature play important role to the pore structure. The convert rates of CaO obtained through different calcining conditions were investigated experimentally. Some interesting results were showed that the calcium utilization of CaO particles is determined not only by the special surface area and total pore volume, but also by pore-size distribution. The main factor influencing the sulfation is the pore diameter distribution at lower sulfation temperature. For higher reaction temperature specific volume is the important reason. But pore-size distribution is strongly influenced by heat flux and temperature in the calcining process.