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新型钛基银电极上硼氢化钠的电化学氧化 被引量:1
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作者 易清风 李磊 《化工学报》 EI CAS CSCD 北大核心 2009年第2期455-459,共5页
A novel titanium-supported silver catalyst(Ag/Ti)with a 3D network structure was prepared by the hydrothermal process using polyethylene glycol as a reduction agent.Electrocatalytic activity of the Ag/Ti electrode tow... A novel titanium-supported silver catalyst(Ag/Ti)with a 3D network structure was prepared by the hydrothermal process using polyethylene glycol as a reduction agent.Electrocatalytic activity of the Ag/Ti electrode towards borohydride oxidation was evaluated by cyclic voltammograms(CVs).A direct oxidation process of borohydride on the Ag/Ti electrode was observed.The results showed that the Ag/Ti electrode presented a high anodic current density for borohydride oxidation,and the onset potential for borohydride oxidation was ca-0.64 V vs SCE at BH-4 concentration of 0.1 mol·L-1.This indicated that the Ag/Ti electrode exhibited high electrocatalytic activity for borohydride oxidation and it would be a promising anode used in direct borohydride fuel cells. 展开更多
关键词 钛基银 直接硼氢化物燃料电池 电催化剂 硼氢化物氧化
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