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摩擦点火Ti-V-Cr阻燃钛合金燃烧产物的组织特征 被引量:20
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作者 弭光宝 黄旭 +2 位作者 曹京霞 王宝 曹春晓 《物理学报》 SCIE EI CAS CSCD 北大核心 2016年第5期217-226,共10页
采用摩擦氧浓度实验方法,结合原位观察、扫描电镜、能谱仪和X一射线衍射分析,系统研究Ti-V-Cr阻燃钛合金燃烧产物的微观组织形貌、燃烧反应过程的合金元素分布规律及微观机理.结果表明:Ti-V-Cr阻燃钛合金燃烧过程发出闪亮耀眼的白光,具... 采用摩擦氧浓度实验方法,结合原位观察、扫描电镜、能谱仪和X一射线衍射分析,系统研究Ti-V-Cr阻燃钛合金燃烧产物的微观组织形貌、燃烧反应过程的合金元素分布规律及微观机理.结果表明:Ti-V-Cr阻燃钛合金燃烧过程发出闪亮耀眼的白光,具有典型金属燃烧的火焰特征.燃烧产物主要有TiO_2,V_2O_5和Cr_2O_3三种氧化物,该混合氧化物以分散颗粒和致密连续体存在.分散颗粒为规则的球形;致密连续燃烧产物的微观组织具有分区特征,从合金基体至燃烧表面依次为过渡区、热影响区、熔凝区和燃烧区.其中,过渡区存在一些微小的颗粒状凸起,且有一定方向性;热影响区中形成大量V基固溶体相和少量的Ti基固溶体相,V基固溶体相上存在Ti的含量远高于基体的针状析出物;熔凝区中,大量的Ti基固溶体中存在少量的V基固溶体;燃烧区主要为Ti,V和Cr的氧化物混合物.热影响区的V基固溶体相降低了Ti元素向熔凝区的迁移速率,减慢了燃烧区Ti与O的优先反应;燃烧区形成的TiO_2,V_2O_5和Cr_2O_3混合氧化物和熔凝区O在Ti中大量固溶共同终止了O向合金基体的继续扩散,从而使Ti-V-Cr阻燃钛合金表现出优异的阻燃功能性. 展开更多
关键词 阻燃合金 燃烧产物 微观组织 钛火机理
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Frictional ignition of Ti40 fireproof titanium alloys for aero-engine in oxygen-containing media 被引量:8
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作者 弭光宝 黄旭 +2 位作者 曹京霞 曹春晓 黄秀松 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第8期2270-2275,共6页
The effect of friction pressure p and oxygen concentration xo on the fireproof performance of Ti40 titanium alloy was studied by frictional ignition test, the U--Xo relationship quantitatively describing the fireproof... The effect of friction pressure p and oxygen concentration xo on the fireproof performance of Ti40 titanium alloy was studied by frictional ignition test, the U--Xo relationship quantitatively describing the fireproof performance of Ti40 was established and the fireproof mechanism of Ti40 was analyzed by SEM, XRD and EDS. The results show that the p--xo relationship of Ti40 obeys parabolic rule. The varying range of xo is about 25% while p varies within 0.1-0.25 MPa. When Xo is 〉70%, Ti40 is ignited immediately at room temperature and develops into continual and steady burning, and the duration of burning is more than 10 s. The fireproof performance of Ti40 is better than TC4 while xo of Ti40 is at least 40% higher than TC4. When Xo is low, the fireproof performance of Ti40 is more sensitive to p; when Xo increases, it is more sensitive to Xo. The forming of fused oxides of V205, TiO2 and Cr203 with strong inner interaction during friction is the basic reason of high fireproof performance of Ti40. 展开更多
关键词 Ti40 fireproof titanium alloys fireproof performance fused oxides fireproof mechanism titanium fire
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