用平均原子模型计算钠等离子体的吸收系数

Under local thermodynamic equilibriun conditions(LTE),the density and temperature of Na and Al plasmas are given,its absorption conefficient is calculated by More’s average atom model(AI),in which the photoabsorption coefficients are calcalated in the hydrogenic approximation,and the results for aluminum have a good agreement compared with the experimental results.

Surface plasmon resonance-induced visible-light photocatalytic performance of silver/silver molybdate composites

Novel silver/silver molybdate（Ag/Ag2MoO4） composites with surface plasmon resonance（SPR）-enhanced photocatalytic performance were successfully fabricated via a facile one-pot hydrothermal route with the presence of sodium dodecyl sulfate（SDS） in this study.The as prepared silver/silver molybdate（Ag/Ag2MoO4） composites were systematically characterized by X-ray diffraction（XRD）,scanning electron microscopy（SEM） and ultraviolet-visible diffuse reflectance absorption spectroscopy（DRS） in order to investigate their crystal structure,morphology and optical property as well.The photocatalytic activities of the composites were subsequently evaluated by their ability to degrade rhodamine B（RhB） under visible-light irradiation.Varies of controlled experiments were then carefully operated to gain a deep insight into the assembling of Ag/Ag2MoO4composites.It was found that preparation conditions such as pH,reaction time,and the amount of surfactant played important roles in the formation of composites with octahedral microstructures.And the composite obtained at 160 ℃ using 0.5 g of sodium dodecyl sulfate exhibited the highest photocatalytic performance under visible-light irradiation.Capture experiments were also conducted to clarify the function of different active species generated on the surface of Ag/Ag2MoO4during the photocatalytic process,in which both holes and ·OH radicals were found to play crucial role in photocatalytic removal of RhB under visible light irradiation.A possible photocatalytic mechanism of Ag/Ag2MoO4 was finally proposed on the basis of all the results to explain the higher photocatalytic activity of the octahedral Ag/Ag2MoO4 composites.It was inferred that the photoinduced ＂hot＂ electrons can quickly transfer from the Ag NPs to the conduction band of Ag2MoO4 and react with oxygen and H2O to generate a large quality of active radicals such as ·OH and ·O2^- because of the SPR effects.Besides,this SPR effects of Ag nanoparticles deposited on the surface of Ag2MoO4 can not only dramatically amplify its light absorption,especially in the visible region,but also promote the separation of photoexcited electron-hole pairs and effectively decrease electron-hole recombination.

Wear and corrosion resistant coatings on surface of cast A356 aluminum alloy by plasma electrolytic oxidation in moderately concentrated aluminate electrolytes

Plasma electrolytic oxidation of a cast A356 aluminum alloy was carried out in aluminate electrolytes to develop wear and corrosion resistant coatings. Different concentrations of 2, 16 and 24 g/L NaAlO2 solutions and a silicate electrolyte （for comparison） were employed for the investigation. Wear performance and corrosion resistance of the coatings were evaluated by WC （tungsten carbide） ball-on-flat dry sliding tests and electrochemical methods, respectively. The results show that the coating formed for a short duration of 480 s in 24 g/L NaAlO2 solution generated the best protection. The coating sustained 30 N load for sliding time of 1800 s, showing very low wear rate of -4.5×10^-7 mm3/（N· m）. A low corrosion current density of -8.81×10^-9 A/cm2 was also recorded. Despite low α-Al2O3 content of the coating, the compact and nearly single layer nature of the coating guaranteed the excellent performances.

Effect of sodium citrate plasma on growth and function of hepatocytes

Objective:To observe the effect of sodium citrate plasma (scP) on the growth and function of hepatocytes. Methods: HepG2, fetus and porcine hepatocytes were cultured. The viability, cell cycle and apoptosis, the leakage of LDH, AFP, total protein, glutathione and the changes on morphology of hepatocytes exposured to scP were investigated. Results: (1)Cultured in 10%, 30%, 50%, 100% scP for 24 h, the viability of HepG2 cells was inhibited (F = 40. 108, P = 0. 001). After 48 h, nearly all cells died except 10% scP group. (2)Exposured to scP for 24 h,the percentage of S phase of the cell cycle was significantly increased and apoptosis was also significantly increased compared to control cultures. (3) The leakages of LDH were increased in the HepG2, fetus and porcine hepatocytes following exposure to scP for 5 h. (4) The synthesis of AFP in fetus and porcine hepatocytes were inhibited in medium containing 10% scP for 3 d(t values were 8. 1902, 5. 1034 separately, P<0. 01). Exposure of HepG2 cells to scP within 24 h resulted in a decrease in the total protein synthesis and a increase in the GSH content. (5)Most of HepG2, fetus and porcine hepatocytes died in all except 10% scP groups after 24 h exposed to scP. Conclusion:scP can damage hepatocytes, which results from citric acid and sodium citrate contained in the fluid of blood maintenance.

Effect and mechanism of dolomite with different size fractions on hematite flotation using sodium oleate as collector

The effect of dolomite with different particle size fractions on hematite flotation was studied using sodium oleate as collector at p H of about 9. The effect mechanism of dolomite on hematite flotation was investigated by means of solution chemistry, ultraviolet spectrophotometry(UV), inductively coupled plasma atomic emission spectrometry(ICP-AES) and X-ray photoelectron spectroscopy(XPS). It is observed that dolomite with different size fractions has depressing effect on hematite flotation using sodium oleate as collector, and dolomite could be the "mineral depressant" of hematite using sodium oleate as collector. The reasons for that are concerned with sodium oleate consumption and the adsorption onto hematite of dissolved species of dolomite.

Application of NaHCO_3/ DTPA Extractant-ICP Spectrometry Technique in Soil Test for Availability of Nutrients and Heavy Metals

Soil test for availability of nutrients and heavy metals is extensively served as a means for the evaluations of soil fertility, and environmental effects and phytotoxicity of pollutants in soils, and for the fertilizer recommendation in agricultural and environmental sciences. Therefore, great attention has been paid to the measurement of elemental availability in soil test.

Elevated plasma levels of N-terminal pro-brain natriuretic peptide in patients with chronic hepatitis C during interferon-based antiviral therapy

AIM: To investigate plasma levels of N-terminal pro-brain natriuretic peptide (NT-proBNP), an established marker of cardiac function, in patients with chronic hepatitis C during interferon-based antiviral therapy. METHODS: Using a sandwich immunoassay, plasma levels of NT-proBNP were determined in 48 patients with chronic hepatitis C at baseline, wk 24 and 48 during antiviral therapy and at wk 72 during follow-up.RESULTS: Plasma NT-proBNP concentrations were significantly increased (P < 0.05) at wk 24, 48 and 72 compared to the baseline values. NT-proBNP concentrations at baseline and wk 24 were closely correlated (r = 0.8; P < 0.001). At wk 24, 7 (14.6%) patients had NT-proBNP concentrations above 200 ng/L compared to 1 (2%) patient at baseline (P = 0.059). Six of these 7 patients had been treated with high-dose IFN-α induction therapy. In multiple regression analysis, NT-proBNP was not related to other clinical parameters, biochemical parameters of liver disease or virus load and response to therapy.CONCLUSION: Elevated levels of NT-proBNP during and after interferon-based antiviral therapy of chronic hepatitis C may indicate the presence of cardiac dysfunction, which may contribute to the clinical symptoms observed in patients during therapy. Plasma levels of NT-proBNP may be used as a diagnostic tool and for guiding therapy in patients during interferon-based antiviral therapy.

Carbon coated Au/TiO_2 mesoporous microspheres: a novel selective photocatalyst

Photocatalysts with desirable selectivity to transformation and purification of targeted pollutants are of great importance in water purification. Here, we demonstrate that selective photocatalysis can be realized by the assistance of gold-enhanced selective adsorption onto carbon-coated Au/TiO2 mesoporous microspheres （Au/TiO2@C-MM）, which were prepared via a surfactant-assisted two-step method that involved the assembly of oleic acid-stabilized titania and gold nanoparticles into colloidal spheres in an emulsion using sodium dodecyl sulfate as a surfactant and the conversion of the surfactants into carbon under annealing in Ar. Due to the negatively charged amorphous carbon, the mesoporous structure, and the surface plasmon resonance absorption of the Au components, the Au/TiO2@C-MM shows enhanced charge- and size-selective adsorption prop- erties, which enables the materials to have high selectivity in the photocatalytic process.