Veratraldehyde was tested as a corrosion inhibitor for mild steel in I M HCI and 0.5 M H2SO4 separately using mass loss and electrochemical studies. The inhibition efficiencies were evaluated at different concentratio...Veratraldehyde was tested as a corrosion inhibitor for mild steel in I M HCI and 0.5 M H2SO4 separately using mass loss and electrochemical studies. The inhibition efficiencies were evaluated at different concentrations of the inhibitor at different temperatures. The inhibition efficiency increased with increase in inhibitor concentration and decreased with increase in temperature in both the acid solutions. Electrochemical studies showed that the inhibitor is of mixed type with a slight predominance of anodic character. The inhibitor was more active in HCI than in H2SO4. The maximum inhibition efficiency approached at 1000 ppm in both the acid medium. The inhibitor was found to adsorb on the mild steel surface according to the Langmuir adsorption isotherm. The surface morphology of mild steel in the presence and absence of inhibitor was studied by using scanning electron microscopic (SEM) images.展开更多
A6×19 point-contact hoisting cable was used as our research object to examine the progress of corrosion of steel wires in a laboratory,simulating the actual working conditions in a coalmine.An electrochemical met...A6×19 point-contact hoisting cable was used as our research object to examine the progress of corrosion of steel wires in a laboratory,simulating the actual working conditions in a coalmine.An electrochemical method was used to investigate the corrosion behavior of steel wires with different surface treatments of a corrosive acid solution.The results show that anode activation of steel wire mainly occurs during pre-corrosion,where the anode activation process of bare steel wires is the fastest as is their corresponding corrosion speed,while the anode activation process of oil coated steel wires and their corresponding corrosion speed are the lowest.During the intermediate and late immersion periods, a passive film is generated on the surface of steel wires,which are gradually damaged with the passage of time.Local pitting corrosion occurs easily on the surface of steel wires with a high-polarization potential. Suitable equivalent circuits were chosen to fit the electrochemical impedance spectroscopy(EIS)of steel wires over various corrosive times and different surface treatments,which indicate good fitting results. The double electrical layer charge-transfer resistance increases in the sequence:bare steel wire, untreated steel wire and oil coated steel wire and their corrosion resistance decreases in turn,which is consistent with their polarization curves.The oil layer provides a certain protective effect on untreated steel wires,but its effect is not entirely clear.展开更多
The iron and steel industry generally features the characteristics of large volume of energy consumption, multiple sorts of energy medium, complex secondary conversion, more recyclable extra energy, and the energy man...The iron and steel industry generally features the characteristics of large volume of energy consumption, multiple sorts of energy medium, complex secondary conversion, more recyclable extra energy, and the energy management of the field may involve the entire personnel, process and system, covering all links from designing, purchasing, energy storage, processing and conversion, distribution, energy use and extra energy recycling. The implementation guidelines summarizes the energy management experience and results and provide a systematic approach for the implementation of GB/T 23331-2012 and GB/T 29456-2012, sharing svstematic instructions and suggestions for the implementing paths and methods of creating, implementing, maintaining and improving the energy management system (EnMS) at the enterprise level.展开更多
Corrosion is a costly and complicated problem facing mild of Vitex doniana as a corrosion inhibitor for mild steel in HCI medium steel utility. This study investigated the use of ethanol extract Experimental methods u...Corrosion is a costly and complicated problem facing mild of Vitex doniana as a corrosion inhibitor for mild steel in HCI medium steel utility. This study investigated the use of ethanol extract Experimental methods used are gravimetric and thermometric The results showed that corrosion rate decreased as the concentration of ethanol extract of Vitex doniana increased and with decrease in temperature. Vitex doniana extract obeyed Langmuir and Tempkin adsorption isotherm. Physical adsorption was proposed from △G° and Ea. Inhibition efficiency (1%) and the degree of surface coverage (0) were calculated and all indicated that Vitex doniana was a good corrosion inhibitor.展开更多
In order to estimate the cavitation incubation period of duplex stainless steel(DSS)under ultrasonic cavitation erosion(CE),this paper analyzed the loading process of material during ultrasonic CE.Local strain theory,...In order to estimate the cavitation incubation period of duplex stainless steel(DSS)under ultrasonic cavitation erosion(CE),this paper analyzed the loading process of material during ultrasonic CE.Local strain theory,cumulative damage theory,and Bernoulli probability model were used to derive the minimum number of cavitation impacts required for the initiation of fatigue cracks,and the predictive equation of the material cavitation incubation period was given.DSS was obtained by tungsten inert gas welding(TIG)powder surfacing method.Tensile test and ultrasonic CE test were performed,and the tensile test data were used to calculate the cavitation incubation period by using the predictive equation.Due to the possible presence of precipitates and micro-cracks in the sample,there was an error between the calculated and the test results.The results showed that the max error between the calculated results and the test results was 8.1%,and the errors of the remaining two groups were within 3.5%.展开更多
文摘Veratraldehyde was tested as a corrosion inhibitor for mild steel in I M HCI and 0.5 M H2SO4 separately using mass loss and electrochemical studies. The inhibition efficiencies were evaluated at different concentrations of the inhibitor at different temperatures. The inhibition efficiency increased with increase in inhibitor concentration and decreased with increase in temperature in both the acid solutions. Electrochemical studies showed that the inhibitor is of mixed type with a slight predominance of anodic character. The inhibitor was more active in HCI than in H2SO4. The maximum inhibition efficiency approached at 1000 ppm in both the acid medium. The inhibitor was found to adsorb on the mild steel surface according to the Langmuir adsorption isotherm. The surface morphology of mild steel in the presence and absence of inhibitor was studied by using scanning electron microscopic (SEM) images.
基金supported by the National Natural Science Foundation of China(No.50875252)the Program for New Century Excellent Talents in University(No.NCET-06-0479).
文摘A6×19 point-contact hoisting cable was used as our research object to examine the progress of corrosion of steel wires in a laboratory,simulating the actual working conditions in a coalmine.An electrochemical method was used to investigate the corrosion behavior of steel wires with different surface treatments of a corrosive acid solution.The results show that anode activation of steel wire mainly occurs during pre-corrosion,where the anode activation process of bare steel wires is the fastest as is their corresponding corrosion speed,while the anode activation process of oil coated steel wires and their corresponding corrosion speed are the lowest.During the intermediate and late immersion periods, a passive film is generated on the surface of steel wires,which are gradually damaged with the passage of time.Local pitting corrosion occurs easily on the surface of steel wires with a high-polarization potential. Suitable equivalent circuits were chosen to fit the electrochemical impedance spectroscopy(EIS)of steel wires over various corrosive times and different surface treatments,which indicate good fitting results. The double electrical layer charge-transfer resistance increases in the sequence:bare steel wire, untreated steel wire and oil coated steel wire and their corrosion resistance decreases in turn,which is consistent with their polarization curves.The oil layer provides a certain protective effect on untreated steel wires,but its effect is not entirely clear.
文摘The iron and steel industry generally features the characteristics of large volume of energy consumption, multiple sorts of energy medium, complex secondary conversion, more recyclable extra energy, and the energy management of the field may involve the entire personnel, process and system, covering all links from designing, purchasing, energy storage, processing and conversion, distribution, energy use and extra energy recycling. The implementation guidelines summarizes the energy management experience and results and provide a systematic approach for the implementation of GB/T 23331-2012 and GB/T 29456-2012, sharing svstematic instructions and suggestions for the implementing paths and methods of creating, implementing, maintaining and improving the energy management system (EnMS) at the enterprise level.
文摘Corrosion is a costly and complicated problem facing mild of Vitex doniana as a corrosion inhibitor for mild steel in HCI medium steel utility. This study investigated the use of ethanol extract Experimental methods used are gravimetric and thermometric The results showed that corrosion rate decreased as the concentration of ethanol extract of Vitex doniana increased and with decrease in temperature. Vitex doniana extract obeyed Langmuir and Tempkin adsorption isotherm. Physical adsorption was proposed from △G° and Ea. Inhibition efficiency (1%) and the degree of surface coverage (0) were calculated and all indicated that Vitex doniana was a good corrosion inhibitor.
基金This work was supported by the National Natural Science Foundation of China(Grant No.51879089).
文摘In order to estimate the cavitation incubation period of duplex stainless steel(DSS)under ultrasonic cavitation erosion(CE),this paper analyzed the loading process of material during ultrasonic CE.Local strain theory,cumulative damage theory,and Bernoulli probability model were used to derive the minimum number of cavitation impacts required for the initiation of fatigue cracks,and the predictive equation of the material cavitation incubation period was given.DSS was obtained by tungsten inert gas welding(TIG)powder surfacing method.Tensile test and ultrasonic CE test were performed,and the tensile test data were used to calculate the cavitation incubation period by using the predictive equation.Due to the possible presence of precipitates and micro-cracks in the sample,there was an error between the calculated and the test results.The results showed that the max error between the calculated results and the test results was 8.1%,and the errors of the remaining two groups were within 3.5%.