A new method called mixed Lagrangian and Eulerian method （MILE method） was used to simulate the thermomechanical behavior during continuous casting process of steel YF45MnV. The simulation results are basically in a...A new method called mixed Lagrangian and Eulerian method （MILE method） was used to simulate the thermomechanical behavior during continuous casting process of steel YF45MnV. The simulation results are basically in agreement with the measured data. The delaying period at the beginning of solidification is about 0.1. in square root of solidification time which is agreement with the data in literatures, and shell thickness increases in linear relation to square root of solidification time. The bloom surface temperature decreases gradually as the casting proceeds. The effective stress in the comer is much larger than that in the mid-face. The comer area is the dangerous zone of cracking. The effects of mold flux break temperature on the air gap and hot tearing indicator were also modeled. The model predicts that the bloom surface temperature increases with the increase of the mold flux break temperature, but the heat flux decreases with the increase of the mold flux break temperature. ,The hot tearing indicator is much smaller when the mold flux break temperature is higher.展开更多
The carbon steels dispersed with ultrafine TiC particles were fabricated by conventional casting method. The casting process is more economical than other available routes for metal matrix composite production, and th...The carbon steels dispersed with ultrafine TiC particles were fabricated by conventional casting method. The casting process is more economical than other available routes for metal matrix composite production, and the large sized components to be fabricated in short processing time. However, it is extremely difficult to obtain uniform dispersion of ultrafine ceramic particles in liquid metals due to the poor wettability and the specific gravity difference between the ceramic particle and metal matrix. In order to solve these problems, the mechanical milling (MM) and surface-active processes were introduced. As a result, Cu coated ultrafine TiC powders made by MM process using high energy ball milling machine were mixed with Sn powders as a surfactant to get better wettability by lowering the surface tension of carbon steel melt. The microstructural investigations by OM show that ultrafine TiC particles are distributed uniformly in carbon steel matrix. The grain sizes of the cast matrix with ultrafine TiC particles are much smaller than those without ultrafine TiC particles. This is probably due to the fact that TiC particles act as nucleation sites during solidification. The wear resistance of cast carbon steel composites added with MMed TiC/Cu-Sn powders is improved due to grain size refinement.展开更多
The inhibition of corrosion of steel in molar hydrochloric acid solution by new synthesized DMI （（3-（3,4-dimethoxyphenyl）isoxazole-5-yl） methanol） compound is studied by weight loss and electrochemical polarizat...The inhibition of corrosion of steel in molar hydrochloric acid solution by new synthesized DMI （（3-（3,4-dimethoxyphenyl）isoxazole-5-yl） methanol） compound is studied by weight loss and electrochemical polarization measurements. The two methods give consistent results. The polarization curves indicate that the DMI compound acts as mixed-type inhibitor. This compound is efficient inhibitor. The inhibition efficiency increases with the increase of inhibitor concentration to reach 96% at 10-3 M for DMI. The temperature effect on the corrosion behavior of steel in 1 M HCI with and without the DMI compound at 10-3 M is studied in the temperature range from 298 to 318 K. The adsorption of inhibitor on the steel surface is found to obey the Frumkin adsorption isotherm model. From the adsorption isotherm, some thermodynamic data for the adsorption process （f, K and △Gads） are calculated and discussed.展开更多
A series of functionalized ionic liquids （ILs） containing ester-group were synthesized and their tribological prop- erties as lubricants for steel-steel contact were studied and compared with a non-functionalized io...A series of functionalized ionic liquids （ILs） containing ester-group were synthesized and their tribological prop- erties as lubricants for steel-steel contact were studied and compared with a non-functionalized ionic liquid and perfluo- ropolyethers （PFPE）. The morphology and chemical composition of the worn scars were analyzed by scanning electron mi- croscopy and X-ray photoelectron spectroscopy, respectively, and the possible lubrication mechanism of ILs was discussed. As a result, all ILs demonstrated a better lubricity and a much higher load-carrying capacity than PFPE used as lubricants for the steel-steel tribomates system. The functionalized ILs with ester-group showed slightly worse friction reducing abil- ity than their nonfunctionalized counterparts at relatively lower loads owing to their higher viscosity, but then exhibited better antiwear ability because the ester group they contained had not only physical but also strong chemical reactions with the freshly exposed steel surface and formed chemical adsorption boundary films on the worn surface during friction pro- cess. Under high loads, some triboehemical reactions took place between the active elements, such as fluorine which were released from the ILs, and fresh metal surfaces of rubbing pairs to form the admixture reaction films, which were mainly composed of ferric fluoride mixed with ferric oxide, leading to lower friction coefficients and good wear resistance.展开更多
基金Project(51174020) supported by the National Natural Science Foundation of China
文摘A new method called mixed Lagrangian and Eulerian method （MILE method） was used to simulate the thermomechanical behavior during continuous casting process of steel YF45MnV. The simulation results are basically in agreement with the measured data. The delaying period at the beginning of solidification is about 0.1. in square root of solidification time which is agreement with the data in literatures, and shell thickness increases in linear relation to square root of solidification time. The bloom surface temperature decreases gradually as the casting proceeds. The effective stress in the comer is much larger than that in the mid-face. The comer area is the dangerous zone of cracking. The effects of mold flux break temperature on the air gap and hot tearing indicator were also modeled. The model predicts that the bloom surface temperature increases with the increase of the mold flux break temperature, but the heat flux decreases with the increase of the mold flux break temperature. ,The hot tearing indicator is much smaller when the mold flux break temperature is higher.
基金supported by the Korea Atomic Energy Research Institute (KAERI) R&D Program
文摘The carbon steels dispersed with ultrafine TiC particles were fabricated by conventional casting method. The casting process is more economical than other available routes for metal matrix composite production, and the large sized components to be fabricated in short processing time. However, it is extremely difficult to obtain uniform dispersion of ultrafine ceramic particles in liquid metals due to the poor wettability and the specific gravity difference between the ceramic particle and metal matrix. In order to solve these problems, the mechanical milling (MM) and surface-active processes were introduced. As a result, Cu coated ultrafine TiC powders made by MM process using high energy ball milling machine were mixed with Sn powders as a surfactant to get better wettability by lowering the surface tension of carbon steel melt. The microstructural investigations by OM show that ultrafine TiC particles are distributed uniformly in carbon steel matrix. The grain sizes of the cast matrix with ultrafine TiC particles are much smaller than those without ultrafine TiC particles. This is probably due to the fact that TiC particles act as nucleation sites during solidification. The wear resistance of cast carbon steel composites added with MMed TiC/Cu-Sn powders is improved due to grain size refinement.
文摘The inhibition of corrosion of steel in molar hydrochloric acid solution by new synthesized DMI （（3-（3,4-dimethoxyphenyl）isoxazole-5-yl） methanol） compound is studied by weight loss and electrochemical polarization measurements. The two methods give consistent results. The polarization curves indicate that the DMI compound acts as mixed-type inhibitor. This compound is efficient inhibitor. The inhibition efficiency increases with the increase of inhibitor concentration to reach 96% at 10-3 M for DMI. The temperature effect on the corrosion behavior of steel in 1 M HCI with and without the DMI compound at 10-3 M is studied in the temperature range from 298 to 318 K. The adsorption of inhibitor on the steel surface is found to obey the Frumkin adsorption isotherm model. From the adsorption isotherm, some thermodynamic data for the adsorption process （f, K and △Gads） are calculated and discussed.
基金the Natural Science Foundation Project of CQ CSTC, 2010BB0201
文摘A series of functionalized ionic liquids （ILs） containing ester-group were synthesized and their tribological prop- erties as lubricants for steel-steel contact were studied and compared with a non-functionalized ionic liquid and perfluo- ropolyethers （PFPE）. The morphology and chemical composition of the worn scars were analyzed by scanning electron mi- croscopy and X-ray photoelectron spectroscopy, respectively, and the possible lubrication mechanism of ILs was discussed. As a result, all ILs demonstrated a better lubricity and a much higher load-carrying capacity than PFPE used as lubricants for the steel-steel tribomates system. The functionalized ILs with ester-group showed slightly worse friction reducing abil- ity than their nonfunctionalized counterparts at relatively lower loads owing to their higher viscosity, but then exhibited better antiwear ability because the ester group they contained had not only physical but also strong chemical reactions with the freshly exposed steel surface and formed chemical adsorption boundary films on the worn surface during friction pro- cess. Under high loads, some triboehemical reactions took place between the active elements, such as fluorine which were released from the ILs, and fresh metal surfaces of rubbing pairs to form the admixture reaction films, which were mainly composed of ferric fluoride mixed with ferric oxide, leading to lower friction coefficients and good wear resistance.
