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室温固相反应合成钼磷酸铵、钨磷酸铵纳米微粒 被引量:8
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作者 石晓波 万屏南 +1 位作者 李春根 汪德先 《合成化学》 CAS CSCD 2003年第4期334-337,共4页
采用室温固相反应法合成了钼磷酸铵、钨磷酸铵两种多金属氧酸盐纳米微粒 ,用元素分析确定了其分子组成。它们的结构、性质、颗粒大小、表面形状分别用 IR,X-射线粉末衍射、透射电镜和热分析等手段进行了研究。结果表明 :两种多金属氧酸... 采用室温固相反应法合成了钼磷酸铵、钨磷酸铵两种多金属氧酸盐纳米微粒 ,用元素分析确定了其分子组成。它们的结构、性质、颗粒大小、表面形状分别用 IR,X-射线粉末衍射、透射电镜和热分析等手段进行了研究。结果表明 :两种多金属氧酸盐都为 Keggin结构 ,晶粒分别为 3 4nm和 3 2 nm左右 。 展开更多
关键词 室温固相反应合成 磷酸铵 钨磷酸铵 纳米微粒 多金属氧酸盐 KEGGIN结构 催化剂
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STUDIES ON SYNTHESIS AND CHARACTER OF INORGANIC ION EXCHANGER TITANIUM PHOSPHATE-AMMONIUM TUNGSTOPHOSPHATE
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作者 Yu Xintian Sun Zhaoxiang(Chemistry Department of Beijing Normal University, Beijing 100875) 《Chinese Journal of Reactive Polymers》 1998年第1期25-31,共7页
In this paper, a new complex inorganic ion exchanger Titanium Phosphate - Ammonium Tungstophosphate (abbreviated as TiP - AWP) was synthesized, whose exchange character and chemical structure were studied, Thiscompoun... In this paper, a new complex inorganic ion exchanger Titanium Phosphate - Ammonium Tungstophosphate (abbreviated as TiP - AWP) was synthesized, whose exchange character and chemical structure were studied, Thiscompound exhibits high exchange capacity and selectivity for Cs+, its exchangecapacity attains 0. 95 mmol/g in the medium of 0. 1 mol/L HNO3, andwhich almost doesn’ t change in the 1 AW imitated waste solution. There areno change in exchange capacity and structure after several times of exchanging,eluting, regenerating, which is of great importance to the separation and uptaking of radio - nuclides. Further more, this exchanger has good thermal andradioactive stability. 展开更多
关键词 合成 无机离子交换磷酸 低价钨磷酸铵
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