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电沉积钴硒化合物及其电解水析氢性能的研究
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作者 姬姗姗 王锐 +2 位作者 张惠铃 张丽珍 于淼 《化学工程师》 CAS 2023年第4期1-3,66,共4页
本文以CoCl·6H_(2)O、SeO_(2)为主盐,在铜箔上电沉积CoSe化合物。研究主盐浓度、沉积电势对CoSe化合物电解水析氢性能的影响。扫描电子显微镜测试表明,电沉积的CoSe化合物具有超薄的纳米片形貌;X射线衍射测试表明,CoSe化合物具有... 本文以CoCl·6H_(2)O、SeO_(2)为主盐,在铜箔上电沉积CoSe化合物。研究主盐浓度、沉积电势对CoSe化合物电解水析氢性能的影响。扫描电子显微镜测试表明,电沉积的CoSe化合物具有超薄的纳米片形貌;X射线衍射测试表明,CoSe化合物具有立方体硒钴矿结构。CoSe化合物表现出较优的氢析出活性,在电流密度为10m A·cm^(-2)时,对应的析氢过电势为244m V。 展开更多
关键词 电沉积 电解水 钴硒化合物 析氢反应
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Co0.85Se magnetic nanoparticles supported on carbon nanotubes as catalyst for hydrogen evolution reaction 被引量:5
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作者 Xiaohui Sun Nuzahat Habibul Hong Du 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2021年第1期235-243,共9页
Co0.85Se magnetic nanoparticles supported on carbon nanotubes were prepared by a one‐step hydrothermal method.The saturation magnetization and coercivity of the MWCNTs/Co0.85Se nanocomposites increased due to a decre... Co0.85Se magnetic nanoparticles supported on carbon nanotubes were prepared by a one‐step hydrothermal method.The saturation magnetization and coercivity of the MWCNTs/Co0.85Se nanocomposites increased due to a decrease in the Co0.85Se nanoparticle size in the MWCNTs/Co0.85Se nanocomposites and an increase in the distance between the Co0.85Se nanoparticles,which increased the specific surface area,thereby benefiting the electrocatalytic performance of the catalyst.Moreover,the MWCNTs/Co0.85Se nanocomposites exhibited an excellent hydrogen evolution reaction performance owing to the presence of MWCNTs,which enhanced the mass transport during the electrocatalytic reactions.Furthermore,in an acid solution,the 30 wt%MWCNTs/Co0.85Se composite catalyst exhibited a current density of 10 mA cm^‒2 at a small overpotential of 266 mV vs.RHE,a small Tafel slope of 60.5 mV dec^‐1,and good stability for HER. 展开更多
关键词 Co0.85Se NANOCOMPOSITES MAGNETIC ELECTROCATALYSIS Hydrogen evolution reaction
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