Two Mo/S complexes:K6[Mo2O2S2（C2O4）2（ClPO3）2]·H2O（1）andK6[Mo2O3S（C2O4）2（ClPO3）2]·3H2O（2）containing oxalate ligand were prepared by the reaction of（NH4）2MoS4 and potassiu oxalate with adding a s...Two Mo/S complexes:K6[Mo2O2S2（C2O4）2（ClPO3）2]·H2O（1）andK6[Mo2O3S（C2O4）2（ClPO3）2]·3H2O（2）containing oxalate ligand were prepared by the reaction of（NH4）2MoS4 and potassiu oxalate with adding a small amount of H3PO4 to adjust the value of pH in system of methanol and water under an atmosphere of pure nitrogen at ambient temperature and charcterized by the means of elemental analysis,IR,UV-vis.The analysis results reveal that crystal of the complex 1 is Orthorhombic,space group pbcn,a=4.6370（2）nm,b=0.7549（2）nm,c=1.3888（4）nm,V=4.861（2）nm3,Z=8,Mr=945.49,Dc=2.58g/cm3,μ=2.625cm-1,R=0.063,wR=0.075.In addition,The their spectral properties were also discussed.展开更多
文摘Two Mo/S complexes:K6[Mo2O2S2（C2O4）2（ClPO3）2]·H2O（1）andK6[Mo2O3S（C2O4）2（ClPO3）2]·3H2O（2）containing oxalate ligand were prepared by the reaction of（NH4）2MoS4 and potassiu oxalate with adding a small amount of H3PO4 to adjust the value of pH in system of methanol and water under an atmosphere of pure nitrogen at ambient temperature and charcterized by the means of elemental analysis,IR,UV-vis.The analysis results reveal that crystal of the complex 1 is Orthorhombic,space group pbcn,a=4.6370（2）nm,b=0.7549（2）nm,c=1.3888（4）nm,V=4.861（2）nm3,Z=8,Mr=945.49,Dc=2.58g/cm3,μ=2.625cm-1,R=0.063,wR=0.075.In addition,The their spectral properties were also discussed.
